scholarly journals Intumescent Phosphorus and Triazole-Based Flame-Retardant Polyurethane Foams from Castor Oil

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 1086-1094 ◽  
Author(s):  
Kesavarao Sykam ◽  
Kiran Kumar Reddy Meka ◽  
Shailaja Donempudi
Keyword(s):  
Flame Retardant ◽  
Castor Oil ◽  
Polyurethane Foams

Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols

2014 ◽  
Vol 52 ◽  
pp. 380-388 ◽  
Author(s):  
Liqiang Zhang ◽  
Meng Zhang ◽  
Lihong Hu ◽  
Yonghong Zhou
Keyword(s):  
Flame Retardant ◽  
Castor Oil ◽  
Polyurethane Foams ◽  
Rigid Polyurethane Foams

Preparation and Characterization of Soybean Oil-based Flame Retardant Rigid Polyurethane Foams Containing Phosphaphenanthrene Groups

2020 ◽  
Vol 17 (10) ◽  
pp. 760-771
Author(s):  
Qirui Gong ◽  
Niangui Wang ◽  
Kaibo Zhang ◽  
Shizhao Huang ◽  
Yuhan Wang
Keyword(s):  
Soybean Oil ◽  
Flame Retardant ◽  
Chemical Structure ◽  
Cell Structure ◽  
Polyurethane Foams ◽  
Limiting Oxygen Index ◽  
Rigid Polyurethane Foams ◽  
Degradation Activation Energy ◽  
Ft Ir

A phosphaphenanthrene groups containing soybean oil based polyol (DSBP) was synthesized by epoxidized soybean oil (ESO) and 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide (DOPO). Soybean oil based polyol (HSBP) was synthesized by ESO and H2O. The chemical structure of DSBP and HSBP were characterized with FT-IR and 1H NMR. The corresponding rigid polyurethane foams (RPUFs) were prepared by mixing DSBP with HSBP. The results revealed apparent density and compression strength of RPUFs decreased with increasing the DSBP content. The cell structure of RPUFs was examined by scanning electron microscope (SEM) which displayed the cells as spherical or polyhedral. The thermal degradation and flame retardancy of RPUFs were investigated by thermogravimetric analysis, limiting oxygen index (LOI), and UL 94 vertical burning test. The degradation activation energy (Ea) of first degradation stage reduced from 80.05 kJ/mol to 37.84 kJ/mol with 80 wt% DSBP. The RUPF with 80 wt% DSBP achieved UL94 V-0 rating and LOI 28.3. The results showed that the flame retardant effect was mainly in both gas phase and condensed phase.

scholarly journals Mechanically Sustainable Starch-Based Flame-Retardant Coatings on Polyurethane Foams

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1286
Author(s):  
Kyung-Who Choi ◽  
Jun-Woo Kim ◽  
Tae-Soon Kwon ◽  
Seok-Won Kang ◽  
Jung-Il Song ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Coating Layer ◽  
Real Life ◽  
Polyurethane Foams ◽  
Layer By Layer ◽  
Toxic Substances ◽  
Cone Calorimetry ◽  
Coating Agent ◽  
Cone Calorimeter Test

The use of halogen-based materials has been regulated since toxic substances are released during combustion. In this study, polyurethane foam was coated with cationic starch (CS) and montmorillonite (MMT) nano-clay using a spray-assisted layer-by-layer (LbL) assembly to develop an eco-friendly, high-performance flame-retardant coating agent. The thickness of the CS/MMT coating layer was confirmed to have increased uniformly as the layers were stacked. Likewise, a cone calorimetry test confirmed that the heat release rate and total heat release of the coated foam decreased by about 1/2, and a flame test showed improved fire retardancy based on the analysis of combustion speed, flame size, and residues of the LbL-coated foam. More importantly, an additional cone calorimeter test was performed after conducting more than 1000 compressions to assess the durability of the flame-retardant coating layer when applied in real life, confirming the durability of the LbL coating by the lasting flame retardancy.

Effects of a novel phosphorus–nitrogen flame retardant on rosin-based rigid polyurethane foams

2015 ◽  
Vol 120 ◽  
pp. 427-434 ◽  
Author(s):  
Meng Zhang ◽  
Zhenyang Luo ◽  
Jinwen Zhang ◽  
Shuigen Chen ◽  
Yonghong Zhou
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foams ◽  
Rigid Polyurethane Foams

New biocomposites based on castor oil polyurethane foams and ionic liquids for CO 2 capture

2017 ◽  
Vol 452 ◽  
pp. 103-112 ◽  
Author(s):  
Marisol Fernández Rojas ◽  
Liliana Pacheco Miranda ◽  
Andrea Martinez Ramirez ◽  
Karina Pradilla Quintero ◽  
Franciele Bernard ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Castor Oil ◽  
Polyurethane Foams

A facile strategy to fabricate microencapsulated expandable graphite as a flame-retardant for rigid polyurethane foams

2015 ◽  
Vol 132 (31) ◽  
pp. n/a-n/a ◽  
Author(s):  
Xiao-Liang Zhang ◽  
Hong-Ji Duan ◽  
Ding-Xiang Yan ◽  
Li-Quan Kang ◽  
Wei-Qin Zhang ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foams ◽  
Expandable Graphite ◽  
Rigid Polyurethane Foams
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