scholarly journals Photophysical Properties of an Azine-Linked Pyrene–Cinnamaldehyde Hybrid: Evidence of Solvent-Dependent Charge-Transfer-Coupled Excimer Emission

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 2178-2187 ◽  
Author(s):  
Arghyadeep Bhattacharyya ◽  
Subhash Chandra Makhal ◽  
Nikhil Guchhait
RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 83709-83709
Author(s):  
V. Thanikachalam ◽  
A. Arunpandiyan ◽  
J. Jayabharathi ◽  
P. Ramanathan

Correction for ‘Photophysical properties of the intramolecular excited charge-transfer states of π-expanded styryl phenanthrimidazoles – effect of solvent polarity’ by V. Thanikachalam et al., RSC Adv., 2014, 4, 6790–6806.


2011 ◽  
Vol 239-242 ◽  
pp. 2612-2615
Author(s):  
Jie Xiu Wang ◽  
Feng Zhao

Two related tricarbonyl rhenium complexes with the formula of [Re(CO)3(L)Cl], where L=4,5-diazafluoren-9-one (Dafo-Re) and 9-(phenylamino)-4,5-diazafluoren (PADF-Re) were successfully synthesized with the aim to explore the effect of the geometry of Dafo on Rhenium(I) coordination, and characterized by1H NMR. Photophysical behaviors are investigated by UV–vis absorption and Fluorescence spectra. The two complexes Dafo-Re and PADF-Re show metal-to-ligand charge transfer absorptions at ca.391nm, ca.394 nm and emissions at ca.492nm, ca.470nm, respectively.


2019 ◽  
Vol 233 (7) ◽  
pp. 895-911 ◽  
Author(s):  
Abdullah G. Al-Sehemi ◽  
Ahmad Irfan ◽  
Mehboobali Pannipara ◽  
Mohammed A. Assiri ◽  
Abul Kalam

Abstract A novel aggregation induced emission (AIE) active anthracene based dihydroquinazolinone derivative (probe 1) has been synthesized and characterized by means of spectroscopic methods. The photophysical properties of this probe have been investigated in solvents of different polarity display that fluorescence states are of intramolecular charge transfer (ICT) character. Probe 1 show clear AIE behavior in water/THF mixture on reaching water fraction 95%. The AIE behavior of probe 1 have been exploited for the detection of metal ions in aqueous solution which reveals high selectivity and sensitivity towards Cu2+ ions by colorimetrically and function as a chemosensor in a remarkable turn-off fluorescence manner. Further, the experimental results were investigated by computational means by optimizing the ground state geometries of probe 1 and probe 1-Cu complex using density functional theory (DFT) at B3LYP/6-31G∗∗ and B3LYP/6-31G∗∗(LANL2DZ) levels of theory. Intra-molecular charge transfer was observed in probe 1 while ligand to metal charge transfer (LMCT) for probe 1-Cu complex.


2017 ◽  
Vol 16 (4) ◽  
pp. 539-546 ◽  
Author(s):  
C. Rémy ◽  
C. Allain ◽  
I. Leray

A series of π conjugated naphthalimide derivatives were prepared. Compounds display efficient photoinduced charge transfer in solution which was rationalized by time-resolved spectroscopy and modelled by TD-DFT calculations.


2015 ◽  
Vol 17 (3) ◽  
pp. 2094-2103 ◽  
Author(s):  
R. F. Jin ◽  
Y. F. Chang

Theoretical investigations show that star-shaped molecules are expected to be promising candidates for charge transfer and donor materials for OSCs.


2016 ◽  
Vol 52 (89) ◽  
pp. 13136-13139 ◽  
Author(s):  
Papri Sutar ◽  
Tapas Kumar Maji

Solvent-dependent, bimodal self-assembly of a flexible, amphiphilic LMWG results in a charge-transfer hydrogel and an organogel with different nano-morphologies and the hydrogel is used as a nanocatalyst for Knoevenagel condensation reaction.


2019 ◽  
Vol 55 (63) ◽  
pp. 9351-9354 ◽  
Author(s):  
Michael Hailmann ◽  
Benjamin Hupp ◽  
Alexander Himmelspach ◽  
Fabian Keppner ◽  
Philipp T. Hennig ◽  
...  

Homo- and heterometallic gold(i) and silver(i) complexes with the carba-closo-dodecaboranylethynyl ligand were obtained and the participation of the boron cluster to the photophysical properties was proven.


2015 ◽  
Vol 39 (5) ◽  
pp. 4100-4108 ◽  
Author(s):  
Soumyajit Dey ◽  
Pritam Mondal ◽  
Sankar Prasad Rath

An anthracene–porphyrin donor–acceptor triad has been synthesized and its photophysical properties along with excimer behavior are investigated.


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