scholarly journals Highly Efficient and Practical N-Heterocyclic Carbene Organocatalyzed Chemoselective N1/C3-Functionalization of Isatins with Green Chemistry Principles

ACS Omega ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 17646-17655
Author(s):  
Chandrashekar Mudithanapelli ◽  
Chandra Sekhar Vasam ◽  
Ravinder Vadde ◽  
Mi-hyun Kim
2013 ◽  
Vol 62 (2) ◽  
pp. 438-440 ◽  
Author(s):  
N. K. Gusarova ◽  
N. A. Chernysheva ◽  
S. V. Yas’ko ◽  
B. A. Trofimov

Author(s):  
Jyoti Prajapati ◽  
Mangalshree Dulawat ◽  
Prakash Prajapat ◽  
Renu Rathore ◽  
Shiv S. Dulawat

<div><p><em>Green chemistry uses highly efficient and environmental benign synthetic procedures to synthesize various bioactive heterocyclic frameworks which are the useful synthons for the synthesis of medicines, plastics, petrochemicals, agrochemicals, cosmetics and many more hence the green chemistry is the need of the day. In this methodology pyrazolines have been synthesized under microwave irradiation<sup>1</sup> using ethanol /alumina. The structures of these compounds were established by elemental analysis and spectral data. The method has several advantages in comparison with conventional synthesis including clean reaction procedure, easy workup, and short reaction time giving excellent yields of product.</em></p></div>


2017 ◽  
Vol 41 (8) ◽  
pp. 448-451 ◽  
Author(s):  
Maryam Salari ◽  
Mohammad H. Mosslemin ◽  
Alireza Hassanabadi

A green and highly efficient synthesis of 12 novel trans-2-(4-chlorobenzoyl)-3-aryl-2,3-dihydronaphtho[2,3- b]furan-4,9-diones has been achieved via a three-component, one-pot condensation of 2-[2-(4-chlorophenyl)-2-oxoethyl)]isoquinolinium bromide with 2-hydroxy-1,4-naphthoquinone and an aromatic aldehyde in the presence of catalytic amounts of choline hydroxide in water under reflux conditions. The advantages of this method are a short reaction time, high yields and the avoidance of any hazardous organic solvent. Therefore, this procedure can be classified as green chemistry.


2021 ◽  
Author(s):  
Sarune Daskeviciute‐Geguziene ◽  
Yi Zhang ◽  
Kasparas Rakstys ◽  
Gediminas Kreiza ◽  
Sher Bahadar Khan ◽  
...  

2016 ◽  
Vol 18 (10) ◽  
pp. 3082-3088 ◽  
Author(s):  
Jianpeng Shang ◽  
Xiaoguang Guo ◽  
Zuopeng Li ◽  
Youquan Deng

An effective route for the syntheses of hydroxyl carbamates from CO2, epoxides and amines over Au/Fe2O3 was developed. Such a process could fulfill the optimum utilization of CO2, which is of significance from the standpoint of green chemistry and sustainable development.


RSC Advances ◽  
2020 ◽  
Vol 10 (23) ◽  
pp. 13866-13871
Author(s):  
Shanta Raj Lakshmi ◽  
Vipin Singh ◽  
L. Raju Chowhan

Tandem conjugate addition, decarboxylation and esterification/amidation of coumarin 3-carboxylic acid derivatives with pyrazolones have been developed.


2013 ◽  
Vol 03 (02) ◽  
pp. 9-18 ◽  
Author(s):  
Eligeti Rajanarendar ◽  
Kammari Thirupathaiah ◽  
Saini Rama Krishna ◽  
Baireddy Kishore

2014 ◽  
Vol 16 (8) ◽  
pp. 3680-3704 ◽  
Author(s):  
Luigi Vaccaro ◽  
Daniela Lanari ◽  
Assunta Marrocchi ◽  
Giacomo Strappaveccia

Green chemistry and flow chemistry are ideal partners for accessing novel chemical spaces and define highly efficient synthetic tools.


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Long Kuai ◽  
Zheng Chen ◽  
Shoujie Liu ◽  
Erjie Kan ◽  
Nan Yu ◽  
...  

AbstractSelective reduction of ketone/aldehydes to alcohols is of great importance in green chemistry and chemical engineering. Highly efficient catalysts are still demanded to work under mild conditions, especially at room temperature. Here we present a synergistic function of single-atom palladium (Pd1) and nanoparticles (PdNPs) on TiO2 for highly efficient ketone/aldehydes hydrogenation to alcohols at room temperature. Compared to simple but inferior Pd1/TiO2 and PdNPs/TiO2 catalysts, more than twice activity enhancement is achieved with the Pd1+NPs/TiO2 catalyst that integrates both Pd1 and Pd NPs on mesoporous TiO2 supports, obtained by a simple but large-scaled spray pyrolysis route. The synergistic function of Pd1 and PdNPs is assigned so that the partial Pd1 dispersion contributes enough sites for the activation of C=O group while PdNPs site boosts the dissociation of H2 molecules to H atoms. This work not only contributes a superior catalyst for ketone/aldehydes hydrogenation, but also deepens the knowledge on their hydrogenation mechanism and guides people to engineer the catalytic behaviors as needed.


ChemInform ◽  
2014 ◽  
Vol 45 (24) ◽  
pp. no-no
Author(s):  
N. K. Gusarova ◽  
N. A. Chernysheva ◽  
S. V. Yas'ko ◽  
B. A. Trofimov

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