scholarly journals Effect of Dicumyl Peroxide on a Poly(lactic acid) (PLA)/Poly(butylene succinate) (PBS)/Functionalized Chitosan-Based Nanobiocomposite for Packaging: A Reactive Extrusion Study

ACS Omega ◽  
2018 ◽  
Vol 3 (10) ◽  
pp. 13298-13312 ◽  
Author(s):  
Monika ◽  
Akhilesh Kumar Pal ◽  
Siddharth Mohan Bhasney ◽  
Purabi Bhagabati ◽  
Vimal Katiyar
Keyword(s):  
Lactic Acid ◽  
Reactive Extrusion ◽  
Poly Lactic Acid ◽  
Dicumyl Peroxide ◽  
Butylene Succinate

scholarly journals A Facile Fabrication of High Toughness Poly(lactic Acid) via Reactive Extrusion with Poly(butylene Succinate) and Ethylene-Methyl Acrylate-Glycidyl Methacrylate

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1401 ◽  
Author(s):  
Bin Xue ◽  
Hezhi He ◽  
Zhiwen Zhu ◽  
Jiqian Li ◽  
Zhaoxia Huang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Methyl Acrylate ◽  
Glycidyl Methacrylate ◽  
Epoxy Group ◽  
Reactive Extrusion ◽  
Poly Lactic Acid ◽  
Hydroxyl Groups ◽  
Butylene Succinate ◽  
Interfacial Compatibility ◽  
Ethylene Methyl Acrylate

As is an excellent bio-based polymer material, poly(lactic acid) (PLA)’s brittle nature greatly restricts its extensive applications. Herein, poly(butylene succinate) (PBS) was introduced to toughening PLA by melt blending using a self-made triple screw extruder through in situ reactive with ethylene-methyl acrylate-glycidyl methacrylate (EGMA). The effect of EGMA concentrations on the mechanical properties, morphology, interfacial compatibility of PLA/PBS blends were studied. Fourier transform infrared (FT-IR) results demonstrated that the epoxy group of EGMA reacts with the hydroxyl groups of PLA and PBS, which proved the occurrence of interfacial reactions among the tri-component. The significantly improved compatibility between PLA and PBS after EGMA incorporation was made evident by scanning electron microscope (SEM) characterization results. Meanwhile, the contact angle test predicted that the EGMA was selectively localized at the interface between PLA and PBS, and the result was verified by morphological analysis of cryofracture and etched samples. The EGMA improves the compatibility of PLA/PBS blends, and consequently leads to a significantly increased toughness with the elongation at break occurring 83 times more when 10 wt % EGMA was introduced than neat PLA, while impact strength also enhanced by twentyfold. Ultimately, the toughening mechanism of PLA based polymers was established based on the above analysis, exploring a new way for the extensive application for degradable material.

scholarly journals Poly(Lactic Acid)–Poly(Butylene Succinate)–Sugar Beet Pulp Composites; Part I: Mechanics of Composites with Fine and Coarse Sugar Beet Pulp Particles

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2531
Author(s):  
Rodion Kopitzky
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Sugar Beet ◽  
Cell Structure ◽  
Sugar Beet Pulp ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Fracture Patterns ◽  
Beet Pulp ◽  
The Impact

Sugar beet pulp (SBP) is a residue available in large quantities from the sugar industry, and can serve as a cost-effective bio-based and biodegradable filler for fully bio-based compounds based on bio-based polyesters. The heterogeneous cell structure of sugar beet suggests that the processing of SBP can affect the properties of the composite. An “Ultra-Rotor” type air turbulence mill was used to produce SBP particles of different sizes. These particles were processed in a twin-screw extruder with poly(lactic acid) (PLA) and poly(butylene succinate) (PBS) and fillers to granules for possible marketable formulations. Different screw designs, compatibilizers and the use of glycerol as a thermoplasticization agent for SBP were also tested. The spherical, cubic, or ellipsoidal-like shaped particles of SBP are not suitable for usage as a fiber-like reinforcement. In addition, the fineness of ground SBP affects the mechanical properties because (i) a high proportion of polar surfaces leads to poor compatibility, and (ii) due to the inner structure of the particulate matter, the strength of the composite is limited to the cohesive strength of compressed sugar-cell compartments of the SBP. The compatibilization of the polymer–matrix–particle interface can be achieved by using compatibilizers of different types. Scanning electron microscopy (SEM) fracture patterns show that the compatibilization can lead to both well-bonded particles and cohesive fracture patterns in the matrix. Nevertheless, the mechanical properties are limited by the impact and elongation behavior. Therefore, the applications of SBP-based composites must be well considered.

The effect of poly(ethylene glycol) as plasticizer in blends of poly(lactic acid) and poly(butylene succinate)

2015 ◽  
Vol 133 (8) ◽  
pp. n/a-n/a ◽  
Author(s):  
Weraporn Pivsa-Art ◽  
Kazunori Fujii ◽  
Keiichiro Nomura ◽  
Yuji Aso ◽  
Hitomi Ohara ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Ethylene Glycol ◽  
Poly Lactic Acid ◽  
Poly Ethylene Glycol ◽  
Butylene Succinate ◽  
Poly Ethylene

scholarly journals Modification of poly(lactic) acid by reactive extrusion and its melt blending with acrylonitrile–butadiene–styrene

2020 ◽  
Vol 69 (9) ◽  
pp. 794-803
Author(s):  
Tobias Abt ◽  
Mohammad Reza Kamrani ◽  
Jonathan Cailloux ◽  
Orlando Santana ◽  
Miguel Sánchez‐Soto
Keyword(s):  
Lactic Acid ◽  
Acrylonitrile Butadiene Styrene ◽  
Reactive Extrusion ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Butadiene Styrene

Poly(lactic acid)/poly(butylene-succinate-co-adipate) (PLA/PBSA) blend films containing thymol as alternative to synthetic preservatives for active packaging of bread

2020 ◽  
Vol 25 ◽  
pp. 100515 ◽  
Author(s):  
Panitee Suwanamornlert ◽  
Noppadon Kerddonfag ◽  
Amporn Sane ◽  
Wannee Chinsirikul ◽  
Weibiao Zhou ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Active Packaging ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Blend Films
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