scholarly journals Silver(I)-Promoted Cascade Reaction of Propargylic Alcohols, Carbon Dioxide, and Vicinal Diols: Thermodynamically Favorable Route to Cyclic Carbonates

ACS Omega ◽  
2017 ◽  
Vol 2 (1) ◽  
pp. 337-345 ◽  
Author(s):  
Zhi-Hua Zhou ◽  
Qing-Wen Song ◽  
Liang-Nian He
Keyword(s):  
Carbon Dioxide ◽  
Cascade Reaction ◽  
Cyclic Carbonates ◽  
Propargylic Alcohols ◽  
Vicinal Diols

Carboxylative cyclization of propargylic alcohols with carbon dioxide: A facile and Green route to α-methylene cyclic carbonates

2020 ◽  
Vol 38 ◽  
pp. 220-231 ◽  
Author(s):  
Mingli Li ◽  
Shahrzad Abdolmohammadi ◽  
Mir Saleh Hoseininezhad-Namin ◽  
Farnaz Behmagham ◽  
Esmail Vessally
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Propargylic Alcohols ◽  
Green Route

Phosphine catalysed synthesis of unsaturated cyclic carbonates from carbon dioxide and propargylic alcohols

1989 ◽  
Vol 30 (30) ◽  
pp. 3981-3982 ◽  
Author(s):  
Jean Fournier ◽  
Christian Bruneau ◽  
Pierre H Dixneuf
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Propargylic Alcohols

A recyclable AgI/OAc− catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

2017 ◽  
Vol 19 (13) ◽  
pp. 2936-2940 ◽  
Author(s):  
Ye Yuan ◽  
Yu Xie ◽  
Cheng Zeng ◽  
Dandan Song ◽  
Somboon Chaemchuen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic System ◽  
Atmospheric Pressure ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Carbon Dioxide Conversion ◽  
Propargylic Alcohols

The cyclization of CO2 and propargylic alcohols were catalyzed by a green and recyclable (20 cycles) AgI/OAc− system under atmospheric pressure.

Zinc(ii)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature

2016 ◽  
Vol 18 (2) ◽  
pp. 382-385 ◽  
Author(s):  
Jiayin Hu ◽  
Jun Ma ◽  
Qinggong Zhu ◽  
Qingli Qian ◽  
Hongling Han ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Room Temperature ◽  
Solvent Free ◽  
Cyclic Carbonates ◽  
Propargylic Alcohols ◽  
Solvent Free Conditions ◽  
Catalyzed Reactions

ZnI2/NEt3 can catalyze the reactions of CO2 and propargylic alcohols to form α-alkylidene cyclic carbonates effectively at room temperature under solvent-free conditions, and the yields of the desired products can reach 99%.

scholarly journals Tandem Reactions Based on the Cyclization of Carbon Dioxide and Propargylic Alcohols: Derivative Applications of α-Alkylidene Carbonates

Catalysts ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 73
Author(s):  
Bowen Jiang ◽  
Xiangyu Yan ◽  
Yong Xu ◽  
Natalya Likhanova ◽  
Heriberto Díaz Velázquez ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Sustainable Chemistry ◽  
Tandem Reactions ◽  
Cyclic Carbonates ◽  
Co2 Utilization ◽  
Propargylic Alcohols ◽  
The Past ◽  
Energy Environment ◽  
Potential Methods ◽  
Carbon Dioxide Co2

As a well-known greenhouse gas, carbon dioxide (CO2) has attracted increasing levels of attention in areas of energy, environment, climate, etc. Notably, CO2 is an abundant, nonflammable, and renewable C1 feedstock in view of chemistry. Therefore, the transformation of CO2 into organic compounds is an extremely attractive research topic in modern green and sustainable chemistry. Among the numerous CO2 utilization methods, carboxylative cycloaddition of CO2 into propargylic alcohols is an ideal route due to the corresponding products, α-alkylidene cyclic carbonates, which are a series of highly functionalized compounds that supply numerous potential methods for the construction of various synthetically and biologically valuable agents. This cyclization reaction has been intensively studied and systematically summarized, in the past years. Therefore, attention has been gradually transferred to produce more derivative compounds. Herein, the tandem reactions of this cyclization with hydration, amination, alcoholysis, and isomerization to synthesize α-hydroxyl ketones, oxazolidinones, carbamates, unsymmetrical carbonates, tetronic acids, ethylene carbonates, etc. were systematically reviewed.

Boosting the Catalytic Performance of Organic Salts for the Fast and Selective Synthesis of α-Alkylidene Cyclic Carbonates from Carbon Dioxide and Propargylic Alcohols

ChemCatChem ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 2584-2592 ◽  
Author(s):  
Bruno Grignard ◽  
Charlène Ngassamtounzoua ◽  
Sandro Gennen ◽  
Bernard Gilbert ◽  
Raphaël Méreau ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Performance ◽  
Selective Synthesis ◽  
Cyclic Carbonates ◽  
Organic Salts ◽  
Propargylic Alcohols

Insights into the Solubility of Carbon Dioxide in Grafted Mesoporous Silica for the Catalytic Synthesis of Cyclic Carbonates by Nanoconfinement

2021 ◽  
Author(s):  
Shahab Boroun ◽  
Abolfazl Alizadeh Sahraei ◽  
Abdol Hadi Mokarizadeh ◽  
Houshang Alamdari ◽  
Frédéric-Georges Fontaine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Catalytic Synthesis ◽  
Cyclic Carbonates
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