scholarly journals Effects of Treatment Conditions on Pd Speciation in CHA and Beta Zeolites for Passive NOx Adsorption

ACS Omega ◽  
2021 ◽  
Author(s):  
Robert B. Pace ◽  
Trevor M. Lardinois ◽  
Yaying Ji ◽  
Rajamani Gounder ◽  
Olivier Heintz ◽  
...  
Keyword(s):  
Treatment Conditions ◽  
Beta Zeolites ◽  
Nox Adsorption

Bang for Your Buck: A Single-Case Experimental Design Study of Practice Amount and Distribution in Treatment for Childhood Apraxia of Speech

2019 ◽  
Vol 62 (9) ◽  
pp. 3160-3182 ◽  
Author(s):  
Edwin Maas ◽  
Christina Gildersleeve-Neumann ◽  
Kathy Jakielski ◽  
Nicolette Kovacs ◽  
Ruth Stoeckel ◽  
...  
Keyword(s):  
Single Case ◽  
Evidence Base ◽  
Distributed Practice ◽  
Single Subject ◽  
Single Subject Design ◽  
Apraxia Of Speech ◽  
Childhood Apraxia Of Speech ◽  
Opposite Pattern ◽  
Massed Practice ◽  
Treatment Conditions

Purpose The aim of this study was to examine 2 aspects of treatment intensity in treatment for childhood apraxia of speech (CAS): practice amount and practice distribution. Method Using an alternating-treatments single-subject design with multiple baselines, we compared high versus low amount of practice, and massed versus distributed practice, in 6 children with CAS. Conditions were manipulated in the context of integral stimulation treatment. Changes in perceptual accuracy, scored by blinded analysts, were quantified with effect sizes. Results Four children showed an advantage for high amount of practice, 1 showed an opposite effect, and 1 showed no condition difference. For distribution, 4 children showed a clear advantage for massed over distributed practice post treatment; 1 showed an opposite pattern, and 1 showed no clear difference. Follow-up revealed a similar pattern. All children demonstrated treatment effects (larger gains for treated than untreated items). Conclusions High practice amount and massed practice were associated with more robust speech motor learning in most children with CAS, compared to low amount and distributed practice, respectively. Variation in effects across children warrants further research to determine factors that predict optimal treatment conditions. Finally, this study adds to the evidence base supporting the efficacy of integral stimulation treatment for CAS. Supplemental Material https://doi.org/10.23641/asha.9630599

Optimal Experimental Design With Nesting of Persons in Organizations

2013 ◽  
Vol 221 (3) ◽  
pp. 145-159 ◽  
Author(s):  
Gerard J. P. van Breukelen
Keyword(s):  
Repeated Measures ◽  
Optimal Number ◽  
Health Centers ◽  
Randomized Experiments ◽  
Optimal Sample ◽  
Treatment Conditions ◽  
Sampling Cost ◽  
Nested Designs ◽  
Simple Equations ◽  
Number Of Individuals

This paper introduces optimal design of randomized experiments where individuals are nested within organizations, such as schools, health centers, or companies. The focus is on nested designs with two levels (organization, individual) and two treatment conditions (treated, control), with treatment assignment to organizations, or to individuals within organizations. For each type of assignment, a multilevel model is first presented for the analysis of a quantitative dependent variable or outcome. Simple equations are then given for the optimal sample size per level (number of organizations, number of individuals) as a function of the sampling cost and outcome variance at each level, with realistic examples. Next, it is explained how the equations can be applied if the dependent variable is dichotomous, or if there are covariates in the model, or if the effects of two treatment factors are studied in a factorial nested design, or if the dependent variable is repeatedly measured. Designs with three levels of nesting and the optimal number of repeated measures are briefly discussed, and the paper ends with a short discussion of robust design.

Investigation of Plasma Treatment Conditions for Wafer-Scale Room-Temperature Bonding Using Ultrathin Au Films in Ambient Air

2019 ◽  
Vol 139 (7) ◽  
pp. 217-218
Author(s):  
Michitaka Yamamoto ◽  
Takashi Matsumae ◽  
Yuichi Kurashima ◽  
Hideki Takagi ◽  
Tadatomo Suga ◽  
...  
Keyword(s):  
Plasma Treatment ◽  
Room Temperature ◽  
Ambient Air ◽  
Wafer Scale ◽  
Treatment Conditions

Rapid, Non-Toxic Synthesis of Beta Zeolites

2018 ◽  
Author(s):  
Felix Hemmann ◽  
Jonathan Hackebeil ◽  
Andreas Lißner ◽  
Florian Mertens
Keyword(s):  
Hydrofluoric Acid ◽  
Molecular Sieves ◽  
Toxic Chemicals ◽  
Lewis Acidity ◽  
Beta Zeolite ◽  
Seeded Growth ◽  
Related Research ◽  
Beta Zeolites ◽  
Growth Method ◽  
Fast Synthesis

Molecular sieves with beta zeolite topology are promising catalysts for various reactions as they exhibits extraordinary Lewis acidity. However, their industrial application and related research in academica is hindered because their synthesis is time consuming and typically involves toxic chemicals as hydrofluoric acid. Therefore, tetraethylammonium fluorid was tested as a non-toxic fluotide source for the synthesis of beta zeolites. In combination with the previously reported nano-seeded growth method, a fast synthesis of beta zeolites only involving non-toxic chemicals was possible. Synthesized zeolites show comparable selectivity in the Bayer-Villinger oxidation as conventional zeolites synthesized with hydrofluoric acid.<br>

Behaviour of Alkylphenol Polyethoxylate Surfactants and of Nitrilotriacetate in Sewage Treatment

1987 ◽  
Vol 19 (3-4) ◽  
pp. 449-460 ◽  
Author(s):  
W. Giger ◽  
M. Ahel ◽  
M. Koch ◽  
H. U. Laubscher ◽  
C. Schaffner ◽  
...  
Keyword(s):  
Activated Sludge ◽  
Sewage Treatment ◽  
Operating Conditions ◽  
Municipal Sewage ◽  
Sludge Treatment ◽  
Loading Rates ◽  
Treatment Conditions ◽  
Physico Chemical ◽  
Treated Sewage ◽  
Removal Efficiencies

Effluents and sludges from several municipal sewage treatment plants in Switzerland were analyzed for nonylphenol polyethoxylates (NPnEO, n=3-20), nonylphenol mono- and diethoxylate (NPlEO, NP2EO), corresponding nonylphenoxy carboxylic acids (NP1EC, NP2EC) and nonylphenol (NP). These chemicals derive from nonionic surfactants of the NPnEO-type, and specific analitical techniques were used to study their behaviour during mechanical-biological sewage and subsequent sludge treatment. The parent NPnEO-surfactants, with concentrations in raw and mechanically treated sewage from 400-2200 mg/m3, were relatively efficiently removed by the activated sludge treatment. The abundances of the different metabolites varied depending on treatment conditions. The refractory nature of NPl/2EO, NP and NPl/2EC was recognized. Both biotransformations and physico-chemical processes determine the behaviour and fate of nonylphenolic substances in sewage treatment. Nitrilotriacetate (NTA) was found in primary effluents at concentrations between 430 and 1390 mg/m3. The various treatment plants showed different removal efficiencies for NTA depending on the operating conditions. Activated sludge treatment with low sludge loading rates and nitrifying conditions removed NTA with efficiencies between 95 and 99%. High sludge loading caused a decrease in NTA removal efficiencies from 70% to 39%.

On the defects of enamel coatings

2019 ◽  
pp. 145-150
Author(s):  
T. O. Soshina ◽  
V. R. Mukhamadyarovа
Keyword(s):  
Heat Treatment ◽  
Surface Tension ◽  
Electron Microscope ◽  
Enamel Coating ◽  
Surface Defects ◽  
Linear Expansion ◽  
Corrosion Properties ◽  
Treatment Conditions ◽  
Mechanical And Corrosion Properties ◽  
Coefficient Of Linear Expansion

The defects destroy the integrity of the enamel, and the paper examines the influence of the physical-mechanical and corrosion properties of frits and heat treatment on the defectiveness of the enamel coating. The surface defects were scanned by electron microscope. It has been established that the defectiveness of enamel coatings depends on the melting index, temperature coefficient of linear expansion, surface tension of the frits, and heat treatment conditions. When burning rate of the enamel coating decreases, the fine-meshed structure of the enamel changes, and the size of the defects decreases.

scholarly journals The Impact of Post-Manufacture Treatments on the Surface Characteristics Important for Finishing of OSB and Particleboard

Forests ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 975
Author(s):  
Antonio Copak ◽  
Vlatka Jirouš-Rajković ◽  
Nikola Španić ◽  
Josip Miklečić
Keyword(s):  
Water Vapour ◽  
Oriented Strand Board ◽  
Construction Material ◽  
Surface Characteristics ◽  
Surface Treatments ◽  
Factors Affecting ◽  
Treatment Conditions ◽  
Water Vapour Absorption ◽  
The Impact

Oriented strand board (OSB) is a commonly used structural wood-based panel for walls and roof siding, but recently the industry has become interested in OSB as a substrate for indoor and outdoor furniture. Particleboard is mainly used in furniture productions and has become popular as a construction material due to its numerous usage possibilities and inexpensive cost. Moisture is one of the most important factors affecting wood-based panel performance and the post-treatment conditions affected their affinity to water. When OSB and particleboard are used as substrates for coatings, their surface characteristics play an important role in determining the quality of the final product. Furthermore, roughness can significantly affect the interfacial phenomena such as adsorption, wetting, and adhesion which may have an impact on the coating performance. In this research particleboard and OSB panels were sanded, re-pressed and IR heated and the influence of surface treatments on hardness, roughness, wetting, water, and water vapour absorption was studied. Results showed that sanding improved the wetting of particleboard and OSB with water. Moreover, studied surface treatments increased water absorption and water penetration depth of OSB panels, and re-pressing had a positive effect on reducing the water vapour absorption of particleboard and OSB panels.

scholarly journals Heat Treatment Evaluation for the Camshafts Production of ADI Low Alloyed with Vanadium

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1036
Author(s):  
Eduardo Colin García ◽  
Alejandro Cruz Ramírez ◽  
Guillermo Reyes Castellanos ◽  
José Federico Chávez Alcalá ◽  
Jaime Téllez Ramírez ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Tensile Strength ◽  
Ductile Iron ◽  
Volume Fraction ◽  
Energy Impact ◽  
Treatment Conditions ◽  
Mold Casting ◽  
Grade 3 ◽  
Good Agreement

Ductile iron camshafts low alloyed with 0.2 and 0.3 wt % vanadium were produced by one of the largest manufacturers of the ductile iron camshafts in México “ARBOMEX S.A de C.V” by a phenolic urethane no-bake sand mold casting method. During functioning, camshafts are subject to bending and torsional stresses, and the lobe surfaces are highly loaded. Thus, high toughness and wear resistance are essential for this component. In this work, two austempering ductile iron heat treatments were evaluated to increase the mechanical properties of tensile strength, hardness, and toughness of the ductile iron camshaft low alloyed with vanadium. The austempering process was held at 265 and 305 °C and austempering times of 30, 60, 90, and 120 min. The volume fraction of high-carbon austenite was determined for the heat treatment conditions by XRD measurements. The ausferritic matrix was determined in 90 min for both austempering temperatures, having a good agreement with the microstructural and hardness evolution as the austempering time increased. The mechanical properties of tensile strength, hardness, and toughness were evaluated from samples obtained from the camshaft and the standard Keel block. The highest mechanical properties were obtained for the austempering heat treatment of 265 °C for 90 min for the ADI containing 0.3 wt % V. The tensile and yield strength were 1200 and 1051 MPa, respectively, while the hardness and the energy impact values were of 47 HRC and 26 J; these values are in the range expected for an ADI grade 3.

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