scholarly journals Green Composites from a Bioplastic Blend of Poly(3-hyroxybutyrate-co-3-hydroxyvalerate) and Carbon Dioxide-Derived Poly(propylene carbonate) and Filled with a Corn Ethanol-Industry Co-product

ACS Omega ◽  
2021 ◽  
Author(s):  
Kjeld W. Meereboer ◽  
Akhilesh Kumar Pal ◽  
Manjusri Misra ◽  
Amar K. Mohanty
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Corn Ethanol ◽  
Green Composites ◽  
Poly Propylene

Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Succinic Anhydride ◽  
Poly Propylene ◽  
Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

scholarly journals Study on Thermal Decomposition Behaviors of Terpolymers of Carbon Dioxide, Propylene Oxide, and Cyclohexene Oxide

2018 ◽  
Vol 19 (12) ◽  
pp. 3723 ◽  
Author(s):  
Shaoyun Chen ◽  
Min Xiao ◽  
Luyi Sun ◽  
Yuezhong Meng
Keyword(s):  
Carbon Dioxide ◽  
Thermal Stability ◽  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Propylene Carbonate ◽  
Cyclohexene Oxide ◽  
Block Polymers ◽  
Rate Method ◽  
Poly Propylene ◽  
Thermal Stability Of

The terpolymerization of carbon dioxide (CO2), propylene oxide (PO), and cyclohexene oxide (CHO) were performed by both random polymerization and block polymerization to synthesize the random poly (propylene cyclohexene carbonate) (PPCHC), di-block polymers of poly (propylene carbonate–cyclohexyl carbonate) (PPC-PCHC), and tri-block polymers of poly (cyclohexyl carbonate–propylene carbonate–cyclohexyl carbonate) (PCHC-PPC-PCHC). The kinetics of the thermal degradation of the terpolymers was investigated by the multiple heating rate method (Kissinger-Akahira-Sunose (KAS) method), the single heating rate method (Coats-Redfern method), and the Isoconversional kinetic analysis method proposed by Vyazovkin with the data from thermogravimetric analysis under dynamic conditions. The values of ln k vs. T−1 for the thermal decomposition of four polymers demonstrate the thermal stability of PPC and PPC-PCHC are poorer than PPCHC and PCHC-PPC-PCHC. In addition, for PPCHC and PCHC-PPC-PCHC, there is an intersection between the two rate constant lines, which means that, for thermal stability of PPCHC, it is more stable than PCHC-PPC-PCHC at the temperature less than 309 °C and less stable when the decomposed temperature is more than 309 °C. Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and thermogravimetric analysis/infrared spectrometry (TG/FTIR) techniques were applied to investigate the thermal degradation behavior of the polymers. The results showed that unzipping was the main degradation mechanism of all polymers so the final pyrolysates were cyclic propylene carbonate and cyclic cyclohexene carbonate. For the block copolymers, the main chain scission reaction first occurs at PC-PC linkages initiating an unzipping reaction of PPC chain and then, at CHC–CHC linkages, initiating an unzipping reaction of the PCHC chain. That is why the T−5% of di-block and tri-block polymers were not much higher than that of PPC while two maximum decomposition temperatures were observed for both the block copolymer and the second one were much higher than that of PPC. For PPCHC, the random arranged bulky cyclohexane groups in the polymer chain can effectively suppress the backbiting process and retard the unzipping reaction. Thus, it exhibited much higher T−5% than that of PPC and block copolymers.

Aluminum porphyrin complexes via delicate ligand design: emerging efficient catalysts for high molecular weight poly(propylene carbonate)

RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 54043-54050 ◽  
Author(s):  
Xingfeng Sheng ◽  
Yong Wang ◽  
Yusheng Qin ◽  
Xianhong Wang ◽  
Fosong Wang
Keyword(s):  
Carbon Dioxide ◽  
Molecular Weight ◽  
High Molecular Weight ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Ligand Design ◽  
Poly Propylene ◽  
High Molecular Weight Poly

Due to the deep concern over residual, toxic cobalt or chromium, bifunctional aluminum porphyrin complexes were prepared to catalyze the copolymerization of propylene oxide and carbon dioxide.

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