scholarly journals Computational Study on Metal-Ion-Decorated Prismane Molecules for Selective Adsorption of CO2 from Flue Gas Mixtures

ACS Omega ◽  
2020 ◽  
Vol 5 (48) ◽  
pp. 31146-31155
Author(s):  
Padmaja D. Wakchaure ◽  
Bishwajit Ganguly
Keyword(s):  
Flue Gas ◽  
Metal Ion ◽  
Computational Study ◽  
Selective Adsorption ◽  
Gas Mixtures ◽  
Adsorption Of Co2

A microporous MOF with a polar pore surface exhibiting excellent selective adsorption of CO2 from CO2–N2 and CO2–CH4 gas mixtures with high CO2 loading

2017 ◽  
Vol 46 (44) ◽  
pp. 15280-15286 ◽  
Author(s):  
Arun Pal ◽  
Santanu Chand ◽  
Syed Meheboob Elahi ◽  
Madhab C. Das
Keyword(s):  
Flue Gas ◽  
Selective Adsorption ◽  
Landfill Gas ◽  
Gas Mixtures ◽  
Gas Mixture ◽  
Pore Surface ◽  
High Co2 ◽  
Selective Sorption ◽  
Adsorption Of Co2

A microporous MOF (IITKGP-5) with polar pore surface exhibits highly selective sorption of CO2 from flue gas as well as landfill gas mixture with IAST selectivity for 435.5 and 151.6 at 273 K/100 kPa respectively.

scholarly journals Selective Adsorption of CO2 from Light Gas Mixtures by Using a Structurally Dynamic Porous Coordination Polymer

2011 ◽  
Vol 123 (46) ◽  
pp. 11080-11084 ◽  
Author(s):  
Kristi L. Kauffman ◽  
Jeffrey T. Culp ◽  
Andrew J. Allen ◽  
Laura Espinal ◽  
Winnie Wong-Ng ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Gas Mixtures ◽  
Porous Coordination Polymer ◽  
Adsorption Of Co2

scholarly journals Selective Adsorption of CO2 from Light Gas Mixtures by Using a Structurally Dynamic Porous Coordination Polymer

2011 ◽  
Vol 50 (46) ◽  
pp. 10888-10892 ◽  
Author(s):  
Kristi L. Kauffman ◽  
Jeffrey T. Culp ◽  
Andrew J. Allen ◽  
Laura Espinal ◽  
Winnie Wong-Ng ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Gas Mixtures ◽  
Porous Coordination Polymer ◽  
Adsorption Of Co2

scholarly journals An Experimental Approach to Adsorption of CO2 + CH4 Gas Mixtures Onto Coal (European RFCS CARBOLAB Research Project)

2014 ◽  
Vol 63 ◽  
pp. 5870-5878 ◽  
Author(s):  
Stéphane Lafortune ◽  
Francis Adelise ◽  
Gaëtan Bentivegna ◽  
Christophe Didier ◽  
Régis Farret ◽  
...  
Keyword(s):  
Experimental Approach ◽  
Gas Mixtures ◽  
Research Project ◽  
Adsorption Of Co2

An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO2 over C2H2

2016 ◽  
Vol 138 (9) ◽  
pp. 3022-3030 ◽  
Author(s):  
Maw Lin Foo ◽  
Ryotaro Matsuda ◽  
Yuh Hijikata ◽  
Rajamani Krishna ◽  
Hiroshi Sato ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Gate Effect ◽  
Porous Coordination Polymer ◽  
Adsorption Of Co2

Development of calix[4]arenes modified at their narrow- and wider-rims as potential metal ions sensor layers for microcantilever sensors: further studies

2021 ◽  
Author(s):  
Paris E. Georghiou ◽  
Shofiur Rahman ◽  
Yousif Assiri ◽  
Gopi Kishore Valluru ◽  
Melita Menelaou ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Computational Study ◽  
Aqueous Media ◽  
Experimental Studies ◽  
Ionic Species ◽  
Alkoxy Group ◽  
Self Assembled Monolayers ◽  
Microcantilever Sensors ◽  
Assembled Monolayers

The development of a microcantilever (MCL) sensing device capable of simultaneously detecting several metal ionic species in aqueous media with low limits of detection requires a variety of sensing layers which are ion-specific. Calix[4]arenes are robust molecules which can be easily modified and have been extensively studied for their ion binding properties. They are also capable of forming self-assembled monolayers (SAMs) onto the gold layers of MCLs and are capable of detecting various metal ions with different anionic counterions in aqueous solutions. In this paper we report on the effect of the alkoxy group in the narrow rim [O-(alkoxycarbonyl)methoxy] substituents of bimodal calix[4]arenes which have been used as metal ion MCL sensing layers, using classical solution state experimental studies. A DFT computational study to compare the experimental results with several metal ions is also reported herein.

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