scholarly journals Steric Effect of a Capping Ligand on the Formation of Supramolecular Coordination Networks of Ni(II): Solid-State Entrapment of Cyclic Water Dimer

ACS Omega ◽  
2020 ◽  
Vol 5 (34) ◽  
pp. 21873-21882
Author(s):  
Sandeep Kumar ◽  
Sadhika Khullar ◽  
Sanjay K. Mandal
Keyword(s):  
Solid State ◽  
Steric Effect ◽  
Water Dimer ◽  
Coordination Networks ◽  
Supramolecular Coordination

Water-sulfate anion interplay in the evolution of solid state architectures and emission properties of Zn and Cd coordination networks with four azine ligands

2020 ◽  
Vol 286 ◽  
pp. 121312 ◽  
Author(s):  
Vasile Lozovan ◽  
Victor Ch. Kravtsov ◽  
Eduard B. Coropceanu ◽  
Anatolii V. Siminel ◽  
Olga V. Kulikova ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Networks ◽  
Sulfate Anion ◽  
Emission Properties

Organometalloligands as Components in Supramolecular Coordination Networks

ChemInform ◽  
2006 ◽  
Vol 37 (27) ◽  
Author(s):  
Moonhyun Oh ◽  
Jeffrey A. Reingold ◽  
Dwight A. Sweigart
Keyword(s):  
Coordination Networks ◽  
Supramolecular Coordination

scholarly journals Synthesis, Crystal Structure, and Solid-State NMR Investigations of Heteronuclear Zn/Co Coordination Networks — A Comparative Study

2013 ◽  
Vol 52 (8) ◽  
pp. 4431-4442 ◽  
Author(s):  
Anusree Viswanath Kuttatheyil ◽  
Daniel Lässig ◽  
Jörg Lincke ◽  
Merten Kobalz ◽  
Maria Baias ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Comparative Study ◽  
Solid State Nmr ◽  
Coordination Networks

Synthesis and characterization of a cadmium(II)–organic supramolecular coordination compound based on the multifunctional 2-amino-5-sulfobenzoic acid ligand

2016 ◽  
Vol 72 (12) ◽  
pp. 939-946 ◽  
Author(s):  
Gan-Yin Yuan ◽  
Lei Zhang ◽  
Meng-Jie Wang ◽  
Kou-Lin Zhang
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Coordination Compound ◽  
Coordination Compounds ◽  
Structural Characteristics ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Two Dimensional ◽  
Ambient Conditions ◽  
Supramolecular Coordination

Much attention has been paid by chemists to the construction of supramolecular coordination compounds based on the multifunctional ligand 5-sulfosalicylic acid (H3SSA) due to the structural and biological interest of these compounds. However, no coordination compounds have been reported for the multifunctional amino-substituted sulfobenzoate ligand 2-amino-5-sulfobenzoic acid (H2asba). We expected that H2asba could be a suitable building block for the assembly of supramolecular networks due to its interesting structural characteristics. The reaction of cadmium(II) nitrate with H2asba in the presence of the auxiliary flexible dipyridylamide ligandN,N′-bis[(pyridin-4-yl)methyl]oxamide (4bpme) under ambient conditions formed a new mixed-ligand coordination compound, namely bis(3-amino-4-carboxybenzenesulfonato-κO1)diaquabis{N,N′-bis[(pyridin-4-yl)methyl]oxamide-κN}cadmium(II)–N,N′-bis[(pyridin-4-yl)methyl]oxamide–water (1/1/4), [Cd(C7H6NO5S)2(C14H14N4O2)2(H2O)2]·C14H14N4O2·4H2O, (1), which was characterized by single-crystal and powder X-ray diffraction analysis (PXRD), FT–IR spectroscopy, thermogravimetric analysis (TG), and UV–Vis and photoluminescence spectroscopic analyses in the solid state. The central CdIIatom in (1) occupies a special position on a centre of inversion and exhibits a slightly distorted octahedral geometry, being coordinated by two N atoms from two monodentate 4bpme ligands, four O atoms from two monodentate 4-amino-3-carboxybenzenesulfonate (Hasba−) ligands and two coordinated water molecules. Interestingly, complex (1) further extends into a threefold polycatenated 0D→2D (0D is zero-dimensional and 2D is two-dimensional) interpenetrated supramolecular two-dimensional (4,4) layer through intermolecular hydrogen bonding. The interlayer hydrogen bonding further links adjacent threefold polycatenated two-dimensional layers into a three-dimensional network. The optical properties of complex (1) indicate that it may be used as a potential indirect band gap semiconductor material. Complex (1) exhibits an irreversible dehydration–rehydration behaviour. The fluorescence properties have also been investigated in the solid state at room temperature.

Heterochiral Doped Supramolecular Coordination Networks for High-Performance Optoelectronics

2019 ◽  
Vol 11 (22) ◽  
pp. 20174-20182 ◽  
Author(s):  
Xiaobo Shang ◽  
Inho Song ◽  
Jeong Hyeon Lee ◽  
Wanuk Choi ◽  
Hiroyoshi Ohtsu ◽  
...  
Keyword(s):  
High Performance ◽  
Coordination Networks ◽  
Supramolecular Coordination

Anion-Directed Coordination Networks of a Flexible S-Pivot Ligand and Anion Exchange in the Solid State

2015 ◽  
Vol 15 (11) ◽  
pp. 5427-5436 ◽  
Author(s):  
Eunji Lee ◽  
Huiyeong Ju ◽  
Seulgi Kim ◽  
Ki-Min Park ◽  
Shim Sung Lee
Keyword(s):  
Solid State ◽  
Anion Exchange ◽  
Coordination Networks

scholarly journals 2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

2018 ◽  
Vol 24 (26) ◽  
pp. 6722-6726 ◽  
Author(s):  
Dimuthu C. Senevirathna ◽  
Melissa V. Werrett ◽  
Victoria L. Blair ◽  
Michael Mehring ◽  
Philip C. Andrews
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Coordination Networks ◽  
Metathesis Reactions ◽  
2D And 3D

Solid-State Interconversions of Coordination Networks and Hydrogen-Bonded Salts

2007 ◽  
Vol 119 (7) ◽  
pp. 1142-1146 ◽  
Author(s):  
Christopher J. Adams ◽  
Howard M. Colquhoun ◽  
Paul C. Crawford ◽  
Matteo Lusi ◽  
A. Guy Orpen
Keyword(s):  
Solid State ◽  
Coordination Networks ◽  
Hydrogen Bonded
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