Robust Bijels for Reactive Separation via Silica-Reinforced Nanoparticle Layers

Giuseppe Di Vitantonio; Tiancheng Wang; Martin F. Haase; Kathleen J. Stebe; Daeyeon Lee

doi:10.1021/acsnano.8b05718

Robust Bijels for Reactive Separation via Silica-Reinforced Nanoparticle Layers

ACS Nano ◽

10.1021/acsnano.8b05718 ◽

2018 ◽

Vol 13 (1) ◽

pp. 26-31 ◽

Cited By ~ 14

Author(s):

Giuseppe Di Vitantonio ◽

Tiancheng Wang ◽

Martin F. Haase ◽

Kathleen J. Stebe ◽

Daeyeon Lee

Keyword(s):

Reactive Separation

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Perspectives on Reactive Separation and Removal of Hydrogen Sulfide

Chemical Engineering Science X ◽

10.1016/j.cesx.2021.100105 ◽

2021 ◽

pp. 100105

Author(s):

Kalyani Jangam ◽

Yu-Yen Chen ◽

Lang Qin ◽

Liang-Shih Fan

Keyword(s):

Hydrogen Sulfide ◽

Reactive Separation

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Reactive separation of ethylene from the effluent gas of methane oxidative coupling via alkylation of benzene to ethylbenzene on ZSM-5

Chemical Engineering Science ◽

10.1016/j.ces.2009.02.031 ◽

2009 ◽

Vol 64 (12) ◽

pp. 2773-2780 ◽

Cited By ~ 11

Author(s):

P.O. Graf ◽

L. Lefferts

Keyword(s):

Oxidative Coupling ◽

Methane Oxidative Coupling ◽

Alkylation Of Benzene ◽

Reactive Separation

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A Continuous Reactive Separation Process for Ethyl Lactate Formation

Organic Process Research & Development ◽

10.1021/op0500640 ◽

2005 ◽

Vol 9 (5) ◽

pp. 599-607 ◽

Cited By ~ 42

Author(s):

Navinchandra Asthana ◽

Aspi Kolah ◽

Dung T. Vu ◽

Carl T. Lira ◽

Dennis J. Miller

Keyword(s):

Separation Process ◽

Ethyl Lactate ◽

Lactate Formation ◽

Reactive Separation

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Reactive separation of p-nitro phenol (PNP) from aqueous solution using tri-n-butyl phosphate: equilibrium and COSMO-RS studies

Separation Science and Technology ◽

10.1080/01496395.2018.1552294 ◽

2018 ◽

Vol 54 (16) ◽

pp. 2738-2748 ◽

Cited By ~ 3

Author(s):

Anju Kumari ◽

Ankur Gaur ◽

Hasan Uslu ◽

Sushil Kumar

Keyword(s):

Aqueous Solution ◽

Reactive Separation

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The use of ionic liquids as efficient extraction medium in the reactive separation of cycloolefins from cyclohexane

Chemical Engineering Journal ◽

10.1016/j.cej.2009.01.049 ◽

2009 ◽

Vol 154 (1-3) ◽

pp. 241-245 ◽

Cited By ~ 21

Author(s):

Daniel Gorri ◽

Alicia Ruiz ◽

Alfredo Ortiz ◽

Inmaculada Ortiz

Keyword(s):

Ionic Liquids ◽

Efficient Extraction ◽

Reactive Separation

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Reactive Separation Processes

Reactive Separation Processes ◽

10.1201/9780203741238-1 ◽

2019 ◽

pp. 1-17

Author(s):

William A. Leet ◽

Santi Kulprathipanja

Keyword(s):

Separation Processes ◽

Reactive Separation

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Experimental and modeling of reactive separation of protocatechuic acid

Chemical Engineering Research and Design ◽

10.1016/j.cherd.2018.01.054 ◽

2018 ◽

Vol 132 ◽

pp. 593-605 ◽

Cited By ~ 16

Author(s):

Biswajit S. De ◽

Kailas L. Wasewar ◽

Vicky R. Dhongde ◽

Anjali A. Ingle ◽

Himangshu Mondal

Keyword(s):

Protocatechuic Acid ◽

Reactive Separation

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Optimization and experimental design by response surface method for reactive extraction of glutaric acid

International Journal of Chemical Reactor Engineering ◽

10.1515/ijcre-2021-0185 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Anuj Kumar ◽

Pranay Mohadikar ◽

Fiona Mary Anthony ◽

Diwakar Z. Shende ◽

Kailas L. Wasewar ◽

...

Keyword(s):

Experimental Design ◽

Response Surface ◽

Glutaric Acid ◽

Extraction Efficiency ◽

Fermentation Broth ◽

Maximum Efficiency ◽

Surface Model ◽

Environment Friendly ◽

Independent Variables ◽

Reactive Separation

Abstract Glutaric acid is an attractive chemical compound which can be used for the manufacturing of polyesters, polyamides, and polyols. It can be produced by the synthesis (chemical method) and fermentation (biological method) process. Glutaric acid is presented with the lowest quantity in the fermentation broth and industrial waste streams. The separation methods of glutaric acid are difficult, costly, and non-environment friendly from fermentation broth. Reactive separation is a simple, cheapest, and environment-friendly process for the recovery of carboxylic acid. Which can be employed for the separation of glutaric acid with lower cost and environment-friendly process. In this study, response surface methodology (RSM) was used as a mathematical technique to optimize and experimental design for investigation of the reactive separation of glutaric acid from the aqueous phase. As per RSM study, 20 experiments with different independent variables such as concentration of glutaric acid, % v/v of trioctylamine, and pH for recovery of glutaric acid were performed. The optimum condition with maximum efficiency (η) 92.03% for 20% trioctylamine and pH = 3 at 0.08 mol/L of glutaric acid initial concentration were observed. The lower concentration of trioctylamine provides sufficient extraction efficiency of glutaric acid. This method can also be used for the separation from fermentation broth because a lower concentration of trioctylamine which makes this process environment-friendly. The optimization condition-defined quadratic response surface model is significant with R 2 of 0.9873. The independent variables defined the effect on the extraction efficiency of glutaric acid. This data can be used for the separation of glutaric acid from industries waste and fermentation broth.

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