scholarly journals Electrolyte Solvation Structure at Solid–Liquid Interface Probed by Nanogap Surface-Enhanced Raman Spectroscopy

ACS Nano ◽  
2018 ◽  
Vol 12 (10) ◽  
pp. 10159-10170 ◽  
Author(s):  
Guang Yang ◽  
Ilia N. Ivanov ◽  
Rose E. Ruther ◽  
Robert L. Sacci ◽  
Veronika Subjakova ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Liquid Interface ◽  
Surface Enhanced ◽  
Solvation Structure ◽  
Surface Enhanced Raman ◽  
Solid Liquid Interface ◽  
Solid Liquid

Probing Electrolyte Solvents at Solid/Liquid Interface Using Gap-Mode Surface-Enhanced Raman Spectroscopy

2019 ◽  
Vol 166 (2) ◽  
pp. A178-A187 ◽  
Author(s):  
Guang Yang ◽  
Robert L. Sacci ◽  
Ilia N. Ivanov ◽  
Rose E. Ruther ◽  
Kevin A. Hays ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Liquid Interface ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Gap Mode

Bacterial detection and differentiation via direct volatile organic compound sensing with surface enhanced Raman spectroscopy

2017 ◽  
Author(s):  
Caitlin S. DeJong ◽  
David I. Wang ◽  
Aleksandr Polyakov ◽  
Anita Rogacs ◽  
Steven J. Simske ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Bacterial Infections ◽  
Direct Detection ◽  
Point Of Care ◽  
Surface Enhanced Raman Spectroscopy ◽  
E Coli ◽  
Recent Emergence ◽  
Surface Enhanced ◽  
Volatile Organic ◽  
Surface Enhanced Raman

Through the direct detection of bacterial volatile organic compounds (VOCs), via surface enhanced Raman spectroscopy (SERS), we report here a reconfigurable assay for the identification and monitoring of bacteria. We demonstrate differentiation between highly clinically relevant organisms: <i>Escherichia coli</i>, <i>Enterobacter cloacae</i>, and <i>Serratia marcescens</i>. This is the first differentiation of bacteria via SERS of bacterial VOC signatures. The assay also detected as few as 10 CFU/ml of <i>E. coli</i> in under 12 hrs, and detected <i>E. coli</i> from whole human blood and human urine in 16 hrs at clinically relevant concentrations of 10<sup>3</sup> CFU/ml and 10<sup>4</sup> CFU/ml, respectively. In addition, the recent emergence of portable Raman spectrometers uniquely allows SERS to bring VOC detection to point-of-care settings for diagnosing bacterial infections.

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