scholarly journals Three-Dimensional Solid-State Lithium-Ion Batteries Fabricated by Conformal Vapor-Phase Chemistry

ACS Nano ◽  
2018 ◽  
Vol 12 (5) ◽  
pp. 4286-4294 ◽  
Author(s):  
Alexander Pearse ◽  
Thomas Schmitt ◽  
Emily Sahadeo ◽  
David M. Stewart ◽  
Alexander Kozen ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Vapor Phase ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Phase Chemistry

scholarly journals Effect of the Etching Profile of a Si Substrate on the Capacitive Characteristics of Three-Dimensional Solid-State Lithium-Ion Batteries

Batteries ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 65
Author(s):  
Sergei Kurbatov ◽  
Alexander Mironenko ◽  
Victor Naumov ◽  
Alexander Skundin ◽  
Alexander Rudy
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
3D Structure ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Si Substrate ◽  
Surface Polishing ◽  
Plasma Chemical Etching ◽  
Submicron Scale ◽  
3D Solid

Along with the soaring demands for all-solid-state thin-film lithium-ion batteries, the problem of their energy density rise becomes very acute. The solution to this problem can be found in development of 3D batteries. The present work deals with the development of a technology for a 3D solid-state lithium-ion battery (3D SSLIB) manufacturing by plasma-chemical etching and magnetron sputtering technique. The results on testing of experimental samples of 3D SSLIB are presented. It was found that submicron-scale steps appearing on the surface of a 3D structure formed on Si substrate by the Bosch process radically change the crystal structure of the upper functional layers. Such changes can lead to disruption of the layers’ continuity, especially that of the down conductors. It is shown that surface polishing by liquid etching of the SiO2 layer and silicon reoxidation leads to surface smoothing, the replacement of the dendrite structure of functional layers by a block structure, and a significant improvement in the capacitive characteristics of the battery.

scholarly journals A Three-Dimensional Electrospun Li6.4La3Zr1.4Ta0.6O12–Poly (Vinylidene Fluoride-Hexafluoropropylene) Gel Polymer Electrolyte for Rechargeable Solid-State Lithium Ion Batteries

2021 ◽  
Vol 9 ◽  
Author(s):  
Donghuang Wang ◽  
Dan Cai ◽  
Yu Zhong ◽  
Zhao Jiang ◽  
Shengzhao Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolyte ◽  
Vinylidene Fluoride ◽  
Gel Polymer Electrolyte ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Porous Polymer ◽  
Electrospinning Technique ◽  
Electrolyte Uptake

Developing high-quality solid-state electrolytes is important for producing next-generation safe and stable solid-state lithium-ion batteries. Herein, a three-dimensional highly porous polymer electrolyte based on poly (vinylidenefluoride-hexafluoropropylene) (PVDF-HFP) with Li6.4La3Zr1.4Ta0.6O12 (LLZTO) nanoparticle fillers (PVDF-HFP-LLZTO) is prepared using the electrospinning technique. The PVDF-HFP-LLZTO gel polymer electrolyte possesses a high ionic conductivity of 9.44 × 10–4 S cm−1 and a Li-ion transference number of 0.66, which can be ascribed that the 3D hierarchical nanostructure with abundant porosity promotes the liquid electrolyte uptake and wetting, and LLZTO nanoparticles fillers decrease the crystallinity of PVDF-HFP. Thus, the solid-state lithium battery with LiFePO4 cathode, PVDF-HFP-LLZTO electrolyte, and Li metal anode exhibits enhanced electrochemical performance with improved cycling stability.

Electrolytes for advanced lithium ion batteries using silicon-based anodes

2019 ◽  
Vol 7 (16) ◽  
pp. 9432-9446 ◽  
Author(s):  
Zhixin Xu ◽  
Jun Yang ◽  
Hongping Li ◽  
Yanna Nuli ◽  
Jiulin Wang
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Recent Progress ◽  
Lithium Ion ◽  
Review Article ◽  
Silicon Based

Recent progress in electrolytes from the liquid to the solid state for Si-based anodes is comprehensively summarized in this review article.

Experimental and numerical analysis to identify the performance limiting mechanisms in solid-state lithium cells under pulse operating conditions

2019 ◽  
Vol 21 (41) ◽  
pp. 22740-22755 ◽  
Author(s):  
Mei-Chin Pang ◽  
Yucang Hao ◽  
Monica Marinescu ◽  
Huizhi Wang ◽  
Mu Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Numerical Analysis ◽  
Energy Density ◽  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Safety Concern ◽  
Lithium Ion ◽  
Thermal Runaway ◽  
Operating Conditions ◽  
Lithium Cells

Solid-state lithium batteries could reduce the safety concern due to thermal runaway while improving the gravimetric and volumetric energy density beyond the existing practical limits of lithium-ion batteries.

Layered Heterostructure Ionogel Electrolytes for High‐Performance Solid‐State Lithium‐Ion Batteries

2021 ◽  
pp. 2007864
Author(s):  
Woo Jin Hyun ◽  
Cory M. Thomas ◽  
Norman S. Luu ◽  
Mark C. Hersam
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion
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