P-Doped Porous Carbon as Metal Free Catalysts for Selective Aerobic Oxidation with an Unexpected Mechanism

ACS Nano ◽  
2016 ◽  
Vol 10 (2) ◽  
pp. 2305-2315 ◽  
Author(s):  
Mehulkumar A. Patel ◽  
Feixiang Luo ◽  
M. Reza Khoshi ◽  
Emann Rabie ◽  
Qing Zhang ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Aerobic Oxidation ◽  
Metal Free ◽  
Selective Aerobic Oxidation

Biomass-derived phosphorus-doped carbon materials as efficient metal-free catalysts for selective aerobic oxidation of alcohols

2019 ◽  
Vol 21 (19) ◽  
pp. 5274-5283 ◽  
Author(s):  
Xiwei Hu ◽  
Mengying Fan ◽  
Yangyang Zhu ◽  
Qian Zhu ◽  
Qiang Song ◽  
...  
Keyword(s):  
Functional Groups ◽  
Carbon Materials ◽  
Structural Characteristics ◽  
Aerobic Oxidation ◽  
Metal Free ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation ◽  
Phosphorus Doped

Heteroatom-doped carbon materials (HDCMs) with abundant active functional groups and stable structural characteristics are promising catalysts for eco-friendly metal-free catalysis.

scholarly journals NHC-catalysed highly selective aerobic oxidation of nonactivated aldehydes

2013 ◽  
Vol 9 ◽  
pp. 602-607 ◽  
Author(s):  
Lennart Möhlmann ◽  
Stefan Ludwig ◽  
Siegfried Blechert
Keyword(s):  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Environmentally Friendly ◽  
Heterocyclic Carbenes ◽  
Metal Free ◽  
Reaction Proceeds ◽  
Selective Aerobic Oxidation ◽  
Terminal Oxidation ◽  
Oxidation Agent

This publication describes a highly selective oxidation of aldehydes to the corresponding acids or esters. The reaction proceeds under metal-free conditions by using N-heterocyclic carbenes as organocatalysts in combination with environmentally friendly oxygen as the terminal oxidation agent.

Doped Graphene as a Metal-Free Carbocatalyst for the Selective Aerobic Oxidation of Benzylic Hydrocarbons, Cyclooctane and Styrene

2013 ◽  
Vol 19 (23) ◽  
pp. 7547-7554 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Ana Primo ◽  
Patricia Concepcion ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Free ◽  
Doped Graphene ◽  
Selective Aerobic Oxidation

scholarly journals Transition-metal free highly selective aerobic oxidation of hindered 2-alkylindoles

Tetrahedron ◽  
2015 ◽  
Vol 71 (34) ◽  
pp. 5531-5537 ◽  
Author(s):  
Morteza Shiri ◽  
Behnaz Farajpour ◽  
Zahra Bozorgpour-Savadjani ◽  
Suhas A. Shintre ◽  
Neil A. Koorbanally ◽  
...  
Keyword(s):  
Transition Metal ◽  
Aerobic Oxidation ◽  
Metal Free ◽  
Selective Aerobic Oxidation

ChemInform Abstract: Transition-Metal Free Highly Selective Aerobic Oxidation of Hindered 2-Alkylindoles.

ChemInform ◽  
2015 ◽  
Vol 46 (49) ◽  
pp. no-no
Author(s):  
Morteza Shiri ◽  
Behnaz Farajpour ◽  
Zahra Bozorgpour-Savadjani ◽  
Suhas A. Shintre ◽  
Neil A. Koorbanally ◽  
...  
Keyword(s):  
Transition Metal ◽  
Aerobic Oxidation ◽  
Metal Free ◽  
Selective Aerobic Oxidation

The selective oxidation of glycerol over metal-free photocatalysts: insights into the solvent effect on catalytic efficiency and product distribution

2021 ◽  
Author(s):  
Pingbo Zhang ◽  
Chengguang Yue ◽  
Mingming Fan ◽  
Agus Haryonob ◽  
Yan Leng ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Catalytic Efficiency ◽  
Product Distribution ◽  
Dft Theory ◽  
Oxidative Esterification ◽  
Metal Free ◽  
Selective Aerobic Oxidation ◽  
Theory Calculation

Solvent effect in selective aerobic oxidation of glycerol over O-doped g-C3N4 was studied combining with control experiments and DFT theory calculation. Notably, a novel oxidative esterification of glycerol to yield esters was discovered in CH3CN.

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

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