Rigidity Dictates Spontaneous Helix Formation of Thermoresponsive Colloidal Chains in Poor Solvent

ACS Nano ◽  
2021 ◽  
Author(s):  
Bipul Biswas ◽  
Debarshi Mitra ◽  
Fayis KP ◽  
Suresh Bhat ◽  
Apratim Chatterji ◽  
...  
Keyword(s):  
1978 ◽  
Vol 39 (9) ◽  
pp. 955-960 ◽  
Author(s):  
E. Geissler ◽  
A.M. Hecht

2003 ◽  
Vol 771 ◽  
Author(s):  
Yuli Wang ◽  
Ying Chih Chang

AbstractWe introduce a simple “solvent quenching” approach to align the rigid-rod à-helical poly(α-benzyl-L-glutamate) (PBLG) chains in the surface-grafted monolayer. By sequentially treating with a good solvent and a poor solvent, a unidirectionally aligned PBLG monolayer with an average tilt angle as small as 3° is obtained.


2021 ◽  
Author(s):  
Huanan Yu ◽  
Wentao Qu ◽  
Feng Liu ◽  
Georg H. Mehl

Gold nanoparticles (NPs) were surface functionalized with hexanethiol groups and chiral nematic discogen ligands. A superlattice, liquid crystal behaviour and helix formation of the discs and a second helical organisation of the NPs were detected.


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