Hierarchical Nanoreactor with Multiple Adsorption and Catalytic Sites for Robust Lithium–Sulfur Batteries

ACS Nano ◽  
2021 ◽  
Author(s):  
Ban Fei ◽  
Chaoqi Zhang ◽  
Daoping Cai ◽  
Jingying Zheng ◽  
Qidi Chen ◽  
...  
Keyword(s):  
Catalytic Sites ◽  
Lithium Sulfur Batteries ◽  
Multiple Adsorption ◽  
Lithium Sulfur

Engineering Oversaturated Fe‐N5 Multi‐functional Catalytic Sites for Durable Lithium‐Sulfur Batteries

2021 ◽  
Author(s):  
Yongguang Zhang ◽  
Jiabing Liu ◽  
Jiayi Wang ◽  
Yan Zhao ◽  
Dan Luo ◽  
...  
Keyword(s):  
Catalytic Sites ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

An N-doped porous carbon/MXene composite as a sulfur host for lithium–sulfur batteries

2019 ◽  
Vol 6 (10) ◽  
pp. 2894-2899 ◽  
Author(s):  
Youquan Zhang ◽  
Wenwen Tang ◽  
Renming Zhan ◽  
Heng Liu ◽  
Hao Chen ◽  
...  
Keyword(s):  
Sulfur Content ◽  
Porous Carbon ◽  
Lithium Sulfur Batteries ◽  
Sulfur Host ◽  
Multiple Adsorption ◽  
Lithium Sulfur

The sulfur content of the composite can reach 80%, and the composite has multiple adsorption for polysulfides.

scholarly journals Frontispiece: Engineering Oversaturated Fe‐N 5 Multifunctional Catalytic Sites for Durable Lithium‐Sulfur Batteries

2021 ◽  
Vol 60 (51) ◽  
Author(s):  
Yongguang Zhang ◽  
Jiabing Liu ◽  
Jiayi Wang ◽  
Yan Zhao ◽  
Dan Luo ◽  
...  
Keyword(s):  
Catalytic Sites ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

Tubular CoFeP@CN as a Mott–Schottky Catalyst with Multiple Adsorption Sites for Robust Lithium−Sulfur Batteries

2021 ◽  
pp. 2100432
Author(s):  
Chaoqi Zhang ◽  
Ruifeng Du ◽  
Jordi Jacas Biendicho ◽  
Mingjie Yi ◽  
Ke Xiao ◽  
...  
Keyword(s):  
Adsorption Sites ◽  
Lithium Sulfur Batteries ◽  
Multiple Adsorption ◽  
Lithium Sulfur

scholarly journals Frontispiz: Engineering Oversaturated Fe‐N 5 Multifunctional Catalytic Sites for Durable Lithium‐Sulfur Batteries

2021 ◽  
Vol 133 (51) ◽  
Author(s):  
Yongguang Zhang ◽  
Jiabing Liu ◽  
Jiayi Wang ◽  
Yan Zhao ◽  
Dan Luo ◽  
...  
Keyword(s):  
Catalytic Sites ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

scholarly journals ZnSe/N-Doped Carbon Nanoreactor with Multiple Adsorption Sites for Stable Lithium–Sulfur Batteries

ACS Nano ◽  
2020 ◽  
Vol 14 (11) ◽  
pp. 15492-15504
Author(s):  
Dawei Yang ◽  
Chaoqi Zhang ◽  
Jordi Jacas Biendicho ◽  
Xu Han ◽  
Zhifu Liang ◽  
...  
Keyword(s):  
Adsorption Sites ◽  
Lithium Sulfur Batteries ◽  
Multiple Adsorption ◽  
Lithium Sulfur

Cellulose Separators with Integrated Carbon Nanotube Interlayers for Lithium-Sulfur Batteries: An Investigation into the Complex Interplay Between Cell Components

2019 ◽  
Author(s):  
Yu-Chuan Chien ◽  
Ruijun Pan ◽  
Ming-Tao Lee ◽  
Leif Nyholm ◽  
Daniel Brandell ◽  
...  
Keyword(s):  
Coulombic Efficiency ◽  
Solid Electrolyte Interphase ◽  
Holistic Approach ◽  
Cycle Life ◽  
Complex Interplay ◽  
Positive Electrodes ◽  
Lithium Sulfur Batteries ◽  
Cell Components ◽  
Redox Shuttle ◽  
Lithium Sulfur

This work aims to address two major roadblocks in the development of lithium-sulfur (Li-S) batteries: the inefficient deposition of Li on the metallic Li electrode and the parasitic "polysulfide redox shuttle". These roadblocks are here approached, respectively, by the combination of a cellulose separator with a cathode-facing conductive porous carbon interlayer, based on their previously reported individual benefits. The cellulose separator increases cycle life by 33%, and the interlayer by a further 25%, in test cells with positive electrodes with practically relevant specifications and a relatively low electrolyte/sulfur (E/S) ratio. Despite the prolonged cycle life, the combination of the interlayer and cellulose separator increases the polysulfide shuttle current, leading to reduced Coulombic efficiency. Based on XPS analyses, the latter is ascribed to a change in the composition of the solid electrolyte interphase (SEI) on Li. Meanwhile, electrolyte decomposition is found to be slower in cells with cellulose-based separators, which explains their longer cycle life. These counterintuitive observations demonstrate the complicated interactions between the cell components in the Li-S system and how strategies aiming to mitigate one unwanted process may exacerbate another. This study demonstrates the value of a holistic approach to the development of Li-S chemistry.<br>

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