Mesoporous Core–Shell Nanostructures Bridging Metal and Biocatalyst for Highly Efficient Cascade Reactions

ACS Catalysis ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 1375-1380 ◽  
Author(s):  
Shiqi Gao ◽  
Zihan Wang ◽  
Li Ma ◽  
Yunting Liu ◽  
Jing Gao ◽  
...  
Keyword(s):  
Cascade Reactions ◽  
Core Shell ◽  
Highly Efficient ◽  
Shell Nanostructures

Cu nanowires shelled with NiFe layered double hydroxide nanosheets as bifunctional electrocatalysts for overall water splitting

2017 ◽  
Vol 10 (8) ◽  
pp. 1820-1827 ◽  
Author(s):  
Luo Yu ◽  
Haiqing Zhou ◽  
Jingying Sun ◽  
Fan Qin ◽  
Fang Yu ◽  
...  
Keyword(s):  
Water Splitting ◽  
Layered Double Hydroxide ◽  
Core Shell ◽  
Cu Nanowires ◽  
Highly Efficient ◽  
Overall Water Splitting ◽  
Shell Nanostructures ◽  
Bifunctional Electrocatalysts ◽  
Double Hydroxide

3D core–shell nanostructures of few-layer NiFe LDH nanosheets grown on Cu nanowires are fabricated toward highly efficient overall water splitting.

Rational assembly of a biointerfaced core@shell nanocomplex towards selective and highly efficient synergistic photothermal/photodynamic therapy

Nanoscale ◽  
2015 ◽  
Vol 7 (47) ◽  
pp. 20197-20210 ◽  
Author(s):  
Chenchen Qin ◽  
Jinbo Fei ◽  
Anhe Wang ◽  
Yang Yang ◽  
Junbai Li
Keyword(s):  
Photodynamic Therapy ◽  
Core Shell ◽  
Two Photon ◽  
Highly Efficient ◽  
Shell Nanostructures

A biointerfaced nanocomplex with well-defined core@shell nanostructures is rationally assembled for combining photothermal and photodynamic therapy in a one-time synergistic manner under NIR two-photon illumination.

Highly efficient and stable nonplatinum anode catalyst with Au@Pd core–shell nanostructures for methanol electrooxidation

2012 ◽  
Vol 295 ◽  
pp. 217-222 ◽  
Author(s):  
Qiang Tan ◽  
Chunyu Du ◽  
Geping Yin ◽  
Pengjian Zuo ◽  
Xinqun Cheng ◽  
...  
Keyword(s):  
Methanol Electrooxidation ◽  
Core Shell ◽  
Anode Catalyst ◽  
Highly Efficient ◽  
Shell Nanostructures

One-Dimensional TiO2@GaON Core-Shell Nanowires with Controlled Shell Thickness from Atomic Layer Deposition for Stable and Efficient Photoelectrochemical Water Splitting

2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Band Gap ◽  
Water Splitting ◽  
Atomic Layer ◽  
Photoelectrochemical Water Splitting ◽  
Core Shell ◽  
Photoelectrochemical Performance ◽  
Highly Efficient ◽  
Layer Deposition ◽  
Shell Nanowires

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>

scholarly journals Highly efficient photocatalytic H2O2 production on core–shell CdS@CdIn2S4 heterojunction in non-sacrificial system

2021 ◽  
Author(s):  
Ning Zhang ◽  
Sufen Lin ◽  
Fuchen Wang ◽  
Yongdi Liu ◽  
Jinlong Zhang ◽  
...  
Keyword(s):  
Core Shell ◽  
H2o2 Production ◽  
Highly Efficient

scholarly journals Iron Based Core-Shell Structures as Versatile Materials: Magnetic Support and Solid Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 72
Author(s):  
Christian Zambrzycki ◽  
Runbang Shao ◽  
Archismita Misra ◽  
Carsten Streb ◽  
Ulrich Herr ◽  
...  
Keyword(s):  
Water Purification ◽  
Functional Materials ◽  
Core Material ◽  
Solid Catalyst ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
The Core ◽  
Shell Nanostructures ◽  
Sio2 Shell ◽  
Iron Based

Core-shell materials are promising functional materials for fundamental research and industrial application, as their properties can be adapted for specific applications. In particular, particles featuring iron or iron oxide as core material are relevant since they combine magnetic and catalytic properties. The addition of an SiO2 shell around the core particles introduces additional design aspects, such as a pore structure and surface functionalization. Herein, we describe the synthesis and application of iron-based core-shell nanoparticles for two different fields of research that is heterogeneous catalysis and water purification. The iron-based core shell materials were characterized by transmission electron microscopy, as well as N2-physisorption, X-ray diffraction, and vibrating-sample magnetometer measurements in order to correlate their properties with the performance in the target applications. Investigations of these materials in CO2 hydrogenation and water purification show their versatility and applicability in different fields of research and application, after suitable individual functionalization of the core-shell precursor. For design and application of magnetically separable particles, the SiO2 shell is surface-functionalized with an ionic liquid in order to bind water pollutants selectively. The core requires no functionalization, as it provides suitable magnetic properties in the as-made state. For catalytic application in synthesis gas reactions, the SiO2-stabilized core nanoparticles are reductively functionalized to provide the catalytically active metallic iron sites. Therefore, Fe@SiO2 core-shell nanostructures are shown to provide platform materials for various fields of application, after a specific functionalization.

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