Inhibitor, Co-Catalyst, or Co-Reactant? Probing the Different Roles of H2S during CO2 Hydrogenation on the MoS2 Catalyst

ACS Catalysis ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 10044-10059 ◽  
Author(s):  
Lohit Sharma ◽  
Ronak Upadhyay ◽  
Srinivas Rangarajan ◽  
Jonas Baltrusaitis
Keyword(s):  
Co2 Hydrogenation ◽  
Co Catalyst ◽  
Mos2 Catalyst

Theoretical insights into CO2 hydrogenation to methanol by a Mn–PNP complex

2019 ◽  
Vol 9 (8) ◽  
pp. 1867-1878 ◽  
Author(s):  
Shyama Charan Mandal ◽  
Kuber Singh Rawat ◽  
Surajit Nandi ◽  
Biswarup Pathak
Keyword(s):  
Hydrogenation Reaction ◽  
Co2 Hydrogenation ◽  
Co Catalyst

Unravelling the role of an amide intermediate in co-catalyst-based sequential CO2 hydrogenation reaction to methanol.

scholarly journals CO2 hydrogenation to value-added chemicals over CeO2-supported bimetallic Fe-Co catalyst

2021 ◽  
Author(s):  
Tina He ◽  
Dimitriy Vovchok ◽  
Cheng Zhang ◽  
Sanjaya Senanayake
Keyword(s):  
Value Added ◽  
Co2 Hydrogenation ◽  
Co Catalyst

Directly Catalytic Decomposition of H2S to Sulfur and Hydrogen under Microwave Conditions

2010 ◽  
Vol 129-131 ◽  
pp. 317-321 ◽  
Author(s):  
Li Li Ren
Keyword(s):  
Hydrogen Sulfide ◽  
Microwave Heating ◽  
Decomposition Rate ◽  
Catalytic Decomposition ◽  
Co Catalyst ◽  
X Zeolite ◽  
Mos2 Catalyst

The catalytic decomposition of hydrogen sulfide (H2S) under microwave heating was studied. The effect of microwave supply power on H2S decomposition rate was investigated over MoS2 catalyst and found that 100W was an optimal microwave supply power for this reaction. That is to say, the pathway of H2S decomposition under microwave conditions is different with that under conversional conditions. The activities of Co catalyst with different supports were also compared. The results show that under microwave heating conditions, comparing with Co/ZSM-5 and Co/X-zeolite, Co/5A has a higher activity for decomposition of H2S.

Photoinduced Reaction Pathway Change for Boosting CO2 Hydrogenation over a MnO-Co Catalyst

ACS Catalysis ◽  
2021 ◽  
pp. 10316-10323
Author(s):  
Bohang Zhao ◽  
Mengyao Sun ◽  
Fanpeng Chen ◽  
Weichao Wang ◽  
Siyu Lu ◽  
...  
Keyword(s):  
Reaction Pathway ◽  
Co2 Hydrogenation ◽  
Co Catalyst ◽  
Photoinduced Reaction

Atomically Alloyed Fe–Co Catalyst Derived from a N-Coordinated Co Single-Atom Structure for CO2 Hydrogenation

ACS Catalysis ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2267-2278 ◽  
Author(s):  
Sun-Mi Hwang ◽  
Seung Ju Han ◽  
Hae-Gu Park ◽  
Hojeong Lee ◽  
Kwangjin An ◽  
...  
Keyword(s):  
Co2 Hydrogenation ◽  
Single Atom ◽  
Co Catalyst

CO2 hydrogenation to methanol catalyzed by Ni5Ga3 metal alloy

2019 ◽  
Author(s):  
Yuhan Men ◽  
Xin Fang ◽  
Fan Wu ◽  
Ranjeet Singh ◽  
Penny Xiao ◽  
...  
Keyword(s):  
Co2 Hydrogenation ◽  
Metal Alloy

scholarly journals Production of Fuels and Chemicals from a CO2/H2 Mixture

Reactions ◽  
2020 ◽  
Vol 1 (2) ◽  
pp. 130-146
Author(s):  
Yali Yao ◽  
Baraka Celestin Sempuga ◽  
Xinying Liu ◽  
Diane Hildebrandt
Keyword(s):  
Co2 Hydrogenation ◽  
Water Gas Shift ◽  
Liquid Fuels ◽  
Saturated Hydrocarbons ◽  
Reverse Water Gas Shift ◽  
Cu Catalyst ◽  
In Series ◽  
Fuels And Chemicals ◽  
Water Gas ◽  
Aspen Simulation

In order to explore co-production alternatives, a once-through process for CO2 hydrogenation to chemicals and liquid fuels was investigated experimentally. In this approach, two different catalysts were considered; the first was a Cu-based catalyst that hydrogenates CO2 to methanol and CO and the second a Fisher–Tropsch (FT) Co-based catalyst. The two catalysts were loaded into different reactors and were initially operated separately. The experimental results show that: (1) the Cu catalyst was very active in both the methanol synthesis and reverse-water gas shift (R-WGS) reactions and these two reactions were restricted by thermodynamic equilibrium; this was also supported by an Aspen plus simulation of an (equilibrium) Gibbs reactor. The Aspen simulation results also indicated that the reactor can be operated adiabatically under certain conditions, given that the methanol reaction is exothermic and R-WGS is endothermic. (2) the FT catalyst produced mainly CH4 and short chain saturated hydrocarbons when the feed was CO2/H2. When the two reactors were coupled in series and the presence of CO in the tail gas from the first reactor (loaded with Cu catalyst) significantly improves the FT product selectivity toward higher carbon hydrocarbons in the second reactor compared to the standalone FT reactor with only CO2/H2 in the feed.

Understanding the structure-performance relationship of cubic In2O3 catalysts for CO2 hydrogenation

2021 ◽  
Vol 49 ◽  
pp. 101543
Author(s):  
Bin Qin ◽  
Zhimin Zhou ◽  
Shenggang Li ◽  
Peng Gao
Keyword(s):  
Co2 Hydrogenation ◽  
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