Inductive Effect Boosting Catalytic Performance of Advanced Fe1–xVxOδ Catalysts in Low-Temperature NH3 Selective Catalytic Reduction: Insight into the Structure, Interaction, and Mechanisms

ACS Catalysis ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 6760-6774 ◽  
Author(s):  
Jincheng Mu ◽  
Xinyong Li ◽  
Wenbo Sun ◽  
Shiying Fan ◽  
Xinyang Wang ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24177-24187 ◽  
Author(s):  
Haidi Xu ◽  
Mengmeng Sun ◽  
Shuang Liu ◽  
Yuanshan Li ◽  
Jianli Wang ◽  
...  

The calcined temperature of the carrier obviously affected SCR activity of catalysts, WO3/Ce0.68Zr0.32O2-500 showed the best low-temperature NH3-SCR activity due to its more Lewis acid sites and stronger redox property.


Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1423
Author(s):  
Marwa Saad ◽  
Agnieszka Szymaszek ◽  
Anna Białas ◽  
Bogdan Samojeden ◽  
Monika Motak

The goal of the study was to modify activated carbon (AC) with nitrogen groups and ceria and to test the obtained materials in low temperature selective catalytic reduction of nitrogen oxides. For that purpose, the starting AC was oxidized with HNO3 of various concentrations, modified with urea and doped with 0.5 wt.% of Ce. It was observed that the increased concentration of acid influenced the catalytic activity, since textural and surface chemistry of activated carbon was changed. The most active sample was that modified with 14 M HNO3 and it reached 96% of NO conversion at 300 °C. Additionally, the addition of Ce improved the catalytic performance of modified AC, and NO was reduced according to oxidation–reduction mechanism, characteristic for supported metal oxides. Nevertheless, the samples promoted with Ce emitted significantly higher amount of CO2 comparing to the non-promoted ones.


RSC Advances ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 1979-1986 ◽  
Author(s):  
Siyi Zheng ◽  
Lei Song ◽  
Siyang Tang ◽  
Changjun Liu ◽  
Hairong Yue ◽  
...  

A novel Mn–SiO2@TiO2 nano-cup catalyst with synergy of MnO2 and acid sites for efficient low-temperature SCR reaction.


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