scholarly journals Role of Lattice Oxygen Participation in Understanding Trends in the Oxygen Evolution Reaction on Perovskites

ACS Catalysis ◽  
2018 ◽  
Vol 8 (5) ◽  
pp. 4628-4636 ◽  
Author(s):  
Jong Suk Yoo ◽  
Xi Rong ◽  
Yusu Liu ◽  
Alexie M. Kolpak
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Lattice Oxygen

Dual Role of Deep Eutectic Solvent as a Solvent and Template for the Synthesis of Octahedral Cobalt Vanadate for an Oxygen Evolution Reaction

2018 ◽  
Vol 6 (12) ◽  
pp. 16255-16266 ◽  
Author(s):  
Gaurav M. Thorat ◽  
Harsharaj S. Jadhav ◽  
Animesh Roy ◽  
Wook-Jin Chung ◽  
Jeong Gil Seo
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Deep Eutectic Solvent ◽  
Dual Role

Lattice Oxygen Redox Chemistry in Solid-State Electrocatalysts for Water Oxidation

2021 ◽  
Author(s):  
Ning Zhang ◽  
Yang Chai
Keyword(s):  
Solid State ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Water Electrolysis ◽  
Redox Chemistry ◽  
Lattice Oxygen ◽  
Vital Importance ◽  
Production Of Hydrogen ◽  
Overall Efficiency

Fundamental understandings towards oxygen evolution reaction (OER) are of vital importance as it dominates the overall efficiency of water electrolysis – a compelling technique for sustainable production of hydrogen feedstock....

The role of selenium vacancies in the enhancement of electrocatalytic activity of CoNiSe2 for the oxygen evolution reaction

2021 ◽  
Vol 514 ◽  
pp. 230596
Author(s):  
Abdelhadi El Jaouhari ◽  
Amine Slassi ◽  
Bowen Zhang ◽  
Anton Pershin ◽  
Wei Liu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity

Stabilizing role of Mo in TiO2-MoOx supported Ir catalyst toward oxygen evolution reaction

2021 ◽  
Vol 280 ◽  
pp. 119433 ◽  
Author(s):  
Eom-Ji Kim ◽  
Jaewook Shin ◽  
Junu Bak ◽  
Sang Jae Lee ◽  
Ki hyun Kim ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction

The Role of Surface States in the Oxygen Evolution Reaction on Hematite

2014 ◽  
Vol 126 (49) ◽  
pp. 13622-13626 ◽  
Author(s):  
Beniamino Iandolo ◽  
Anders Hellman
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Surface States

scholarly journals Fe-Doping in Double Perovskite PrBaCo2(1-x)Fe2xO6-δ: Insights into Structural and Electronic Effects to Enhance Oxygen Evolution Catalyst Stability

Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 263 ◽  
Author(s):  
Bae-Jung Kim ◽  
Emiliana Fabbri ◽  
Ivano Castelli ◽  
Mario Borlaf ◽  
Thomas Graule ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Double Perovskite ◽  
Alkaline Media ◽  
Catalyst Stability ◽  
Electronic Effects ◽  
Single Transition ◽  
Charge Stability ◽  
X Ray Absorption

Perovskite oxides have been gaining attention for its capability to be designed as an ideal electrocatalyst for oxygen evolution reaction (OER). Among promising candidates, the layered double perovskite—PrBaCo2O6-δ (PBC)—has been identified as the most active perovskite electrocatalyst for OER in alkaline media. For a single transition metal oxide catalyst, the addition of Fe enhances its electrocatalytic performance towards OER. To understand the role of Fe, herein, Fe is incorporated in PBC in different ratios, which yielded PrBaCo2(1-x)Fe2xCo6-δ (x = 0, 0.2 and 0.5). Fe-doped PBCF’s demonstrate enhanced OER activities and stabilities. Operando X-ray absorption spectroscopy (XAS) revealed that Co is more stable in a lower oxidation state upon Fe incorporation by establishing charge stability. Hence, the degradation of Co is inhibited such that the perovskite structure is prolonged under the OER conditions, which allows it to serve as a platform for the oxy(hydroxide) layer formation. Overall, our findings underline synergetic effects of incorporating Fe into Co-based layered double perovskite in achieving a higher activity and stability during oxygen evolution reaction.

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