Low-Temperature Catalytic CO2 Dry Reforming of Methane on Ni-Si/ZrO2 Catalyst

ACS Catalysis ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 6495-6506 ◽  
Author(s):  
Ye Wang ◽  
Lu Yao ◽  
Yannan Wang ◽  
Shenghong Wang ◽  
Qing Zhao ◽  
...  
Keyword(s):  
Low Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Zro2 Catalyst

scholarly journals Preparation, Characterization, and Activity of Pd/PSS-Modified Membranes in the Low Temperature Dry Reforming of Methane with and without Addition of Extra Steam

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 518
Author(s):  
Cecilia Mateos-Pedrero ◽  
Miguel A. Soria ◽  
Antonio Guerrero-Ruíz ◽  
Inmaculada Rodríguez-Ramos
Keyword(s):  
Low Temperature ◽  
Flow Reactor ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Porous Stainless Steel ◽  
Pd Membrane ◽  
Continuous Flow Reactor ◽  
Oxidation In Air ◽  
H2 Yield ◽  
Water Gas

The external surface of a commercial porous stainless steel (PSS) was modified by either oxidation in air at varying temperatures (600, 700, and 800 °C) or coating with different oxides (SiO2, Al2O3, and ZrO2). Among them, PSS-ZrO2 appears as the most suitable carrier for the synthesis of the Pd membrane. A composite Pd membrane supported on the PSS-ZrO2 substrate was prepared by the electroless plating deposition method. Supported Ru catalysts were first evaluated for the low-temperature methane dry reforming (DRM) reaction in a continuous flow reactor (CR). Ru/ZrO2-La2O3 catalyst was found to be active and stable, so it was used in a membrane reactor (MR), which enhances the methane conversions above the equilibrium values. The influence of adding H2O to the feed of DRM was investigated over a Ru/ZrO2-La2O3 catalyst in the MR. Activity results are compared with those measured in a CR. The addition of H2O into the feed favors other reactions such as Water-Gas Shift (RWGS) and Steam Reforming (SR), which occur together with DRM, resulting in a dramatic decrease of CO2 conversion and CO production, but a marked increase of H2 yield.

Transient studies of low-temperature dry reforming of methane over Ni-CaO/ZrO2-La2O3

2013 ◽  
Vol 129 ◽  
pp. 450-459 ◽  
Author(s):  
B. Bachiller-Baeza ◽  
C. Mateos-Pedrero ◽  
M.A. Soria ◽  
A. Guerrero-Ruiz ◽  
U. Rodemerck ◽  
...  
Keyword(s):  
Low Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane

A Single‐Source Precursor Approach to Self‐Supported Nickel–Manganese‐Based Catalysts with Improved Stability for Effective Low‐Temperature Dry Reforming of Methane

ChemPlusChem ◽  
2016 ◽  
Vol 81 (4) ◽  
pp. 370-377 ◽  
Author(s):  
Prashanth W. Menezes ◽  
Arindam Indra ◽  
Patrick Littlewood ◽  
Caren Göbel ◽  
Reinhard Schomäcker ◽  
...  
Keyword(s):  
Low Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Single Source ◽  
Single Source Precursor ◽  
Improved Stability ◽  
Nickel Manganese

Low-temperature catalytic CO2 dry reforming of methane on Ni-based catalysts: A review

2018 ◽  
Vol 169 ◽  
pp. 199-206 ◽  
Author(s):  
Ye Wang ◽  
Lu Yao ◽  
Shenghong Wang ◽  
Dehua Mao ◽  
Changwei Hu
Keyword(s):  
Low Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane

scholarly journals Ultrathin Washcoat and Very Low Loading Monolithic Catalyst with Outstanding Activity and Stability in Dry Reforming of Methane

Nanomaterials ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 445 ◽  
Author(s):  
Fazia Agueniou ◽  
Hilario Vidal ◽  
María Pilar Yeste ◽  
Juan C. Hernández-Garrido ◽  
Miguel A. Cauqui ◽  
...  
Keyword(s):  
Thermodynamic Limit ◽  
Catalyst Layer ◽  
Active Phase ◽  
Dry Reforming ◽  
Redox Properties ◽  
Dry Reforming Of Methane ◽  
Alumina Catalyst ◽  
Monolithic Catalyst ◽  
Prolonged Time ◽  
Zro2 Catalyst

A Ni/CeO2/ZrO2 catalyst with improved redox properties has been washcoated onto a honeycomb cordierite monolith in the form of a nonconventional alumina-catalyst layer, just a few nanometers thick. In spite of the very low active phase loading, the monolith depicts outstanding performance in dry reforming of methane, both in terms of activity, with values reaching the thermodynamic limit already at 750 °C, even under extreme Weight Hourly Space Velocities (WHSV 115–346 L·g−1·h−1), as well as in terms of stability during prolonged Time on Stream (TOS 24–48 h).

Catalyst assisted by non-thermal plasma in dry reforming of methane at low temperature

2018 ◽  
Vol 299 ◽  
pp. 263-271 ◽  
Author(s):  
David Yap ◽  
Jean-Michel Tatibouët ◽  
Catherine Batiot-Dupeyrat
Keyword(s):  
Low Temperature ◽  
Thermal Plasma ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Non Thermal Plasma

Low-temperature dry reforming of methane to produce syngas in an electric field over La-doped Ni/ZrO 2 catalysts

2017 ◽  
Vol 158 ◽  
pp. 96-103 ◽  
Author(s):  
Tomohiro Yabe ◽  
Kenta Mitarai ◽  
Kazumasa Oshima ◽  
Shuhei Ogo ◽  
Yasushi Sekine
Keyword(s):  
Low Temperature ◽  
Electric Field ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
La Doped

Role of Electric Field and Surface Protonics on Low-Temperature Catalytic Dry Reforming of Methane

2019 ◽  
Vol 7 (6) ◽  
pp. 5690-5697 ◽  
Author(s):  
Tomohiro Yabe ◽  
Kensei Yamada ◽  
Kota Murakami ◽  
Kenta Toko ◽  
Kazuharu Ito ◽  
...  
Keyword(s):  
Low Temperature ◽  
Electric Field ◽  
Dry Reforming ◽  
Dry Reforming Of Methane

Stable low-temperature dry reforming of methane over mesoporous La2O3-ZrO2 supported Ni catalyst

2012 ◽  
Vol 113-114 ◽  
pp. 19-30 ◽  
Author(s):  
Sergey Sokolov ◽  
Evgenii V. Kondratenko ◽  
Marga-Martina Pohl ◽  
Axel Barkschat ◽  
Uwe Rodemerck
Keyword(s):  
Low Temperature ◽  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Ni Catalyst ◽  
Supported Ni Catalyst ◽  
Supported Ni
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