Structural Transformation of Porous Polyoxometalate Frameworks and Highly Efficient Biomimetic Aerobic Oxidation of Aliphatic Alcohols

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 6573-6580 ◽  
Author(s):  
Min Zhao ◽  
Xian-Wei Zhang ◽  
Chuan-De Wu
Keyword(s):  
Structural Transformation ◽  
Aerobic Oxidation ◽  
Aliphatic Alcohols ◽  
Highly Efficient

Visible-light-responsive lanthanide coordination polymers for highly efficient photocatalytic aerobic oxidation of amines and thiols

2021 ◽  
Author(s):  
Zhifen Guo ◽  
Xin Liu ◽  
Yan Che ◽  
Hongzhu Xing ◽  
Peng Chen
Keyword(s):  
Visible Light ◽  
Molecular Oxygen ◽  
Coordination Polymers ◽  
Aerobic Oxidation ◽  
Synthesis And Characterization ◽  
Lanthanide Coordination Polymers ◽  
Highly Efficient ◽  
Photocatalytic Reactions ◽  
Energy Issues

Development of visible-light-induced photocatalytic reactions using molecular oxygen as terminal oxidant is intriguing in view of the current environmental and energy issues. We report herein the synthesis and characterization of...

Highly efficient oxidation of alcohols catalyzed by a porphyrin-inspired manganese complex

2015 ◽  
Vol 51 (56) ◽  
pp. 11268-11271 ◽  
Author(s):  
Wen Dai ◽  
Ying Lv ◽  
Lianyue Wang ◽  
Sensen Shang ◽  
Bo Chen ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Aliphatic Alcohols ◽  
Manganese Complex ◽  
Highly Efficient ◽  
Oxidation Of Alcohols ◽  
Novel Strategy

A novel strategy for catalytic oxidation of a variety of benzylic, allylic, propargylic, and aliphatic alcohols to the corresponding aldehydes or ketones has been successfully developed.

An Efficient Chromium(III)-Catalyzed Aerobic Oxidation of Methylarenes in Water for the Green Preparation of Corresponding Acids

2021 ◽  
Author(s):  
Feng Jiang ◽  
Shanshan Liu ◽  
Wenshu Zhao ◽  
Han Yu ◽  
Li-Kai Yan ◽  
...  
Keyword(s):  
Efficient Method ◽  
Aerobic Oxidation ◽  
Highly Efficient

A highly efficient method to oxidize methylarenes to corresponding acids with reusable Cr catalyst was developed. The reaction can be carried out in water with 1 atm oxygen and K2S2O8...

A hybrid composite of hydroxyapatite and Ca–Al layered double hydroxide supported Au nanoparticles for highly efficient base-free aerobic oxidation of glucose

2019 ◽  
Vol 48 (25) ◽  
pp. 9161-9172 ◽  
Author(s):  
Yunfeng Zhuge ◽  
Guoli Fan ◽  
Yanjun Lin ◽  
Lan Yang ◽  
Feng Li
Keyword(s):  
Layered Double Hydroxide ◽  
Hybrid Composite ◽  
Au Nanoparticles ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Highly Efficient ◽  
Double Hydroxide ◽  
Oxidation Of Glucose

A novel hybrid composite of hydroxyapatite/Ca–Al layered double hydroxide supported Au nanoparticles exhibited robust catalytic performance in base-free aerobic oxidation of glucose.

Co-N-C catalysts synthesized by pyrolysis of Co-based deep eutectic solvents for aerobic oxidation of alcohols

2018 ◽  
Vol 42 (19) ◽  
pp. 15871-15878 ◽  
Author(s):  
Xin Zhao ◽  
Yan Zhou ◽  
Ai-Ling Jin ◽  
Kuan Huang ◽  
Fujian Liu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Deep Eutectic Solvents ◽  
Highly Efficient ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones

DES derived Co-N-C composites were used for highly efficient aerobic oxidation of alcohols into the corresponding aldehydes and ketones.

Highly efficient iron phthalocyanine catalyzed oxidative synthesis of imines from alcohols and amines

2013 ◽  
Vol 91 (8) ◽  
pp. 732-737 ◽  
Author(s):  
Manju Bala ◽  
Praveen Kumar Verma ◽  
Neeraj Kumar ◽  
Upendra Sharma ◽  
Bikram Singh
Keyword(s):  
Lewis Acid ◽  
Oxidative Coupling ◽  
Aliphatic Alcohols ◽  
Nucleophilic Attack ◽  
Iron Phthalocyanine ◽  
Acid Base ◽  
Base Interaction ◽  
Highly Efficient ◽  
Activation Of Alcohols ◽  
Acid Base Interaction

An efficient iron phthalocyanine catalyzed method was developed for direct oxidative coupling of alcohols with amines to afford corresponding imines. The present protocol is applicable to various substituted aromatic and aliphatic alcohols and amines. The reaction is believed to proceed via activation of alcohols by iron phthalocyanines through Lewis acid–base interaction to form aldehydes, which by nucleophilic attack of amines are converted into the corresponding imines.

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