Platinum Group Metal Phosphides as Heterogeneous Catalysts for the Gas-Phase Hydroformylation of Small Olefins

ACS Catalysis ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 3584-3590 ◽  
Author(s):  
Luis Alvarado Rupflin ◽  
Jaroslaw Mormul ◽  
Michael Lejkowski ◽  
Sven Titlbach ◽  
Rainer Papp ◽  
...  
Catalysts ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 122 ◽  
Author(s):  
Luis Alvarado Rupflin ◽  
Chiara Boscagli ◽  
Stephan Schunk

Platinum group metal phosphides are reviewed as catalytic materials for hydroprocessing and syngas-related catalysis. Starting from synthetic procedures leading to highly disperse nano-particular compounds, their properties in the applications are discussed and compared with relevant benchmarks, if available. Regarding their mode of action, two confronting mechanistic scenarios are presented: (i) a cooperative scenario in which catalytic sites of different functionalities are active in hydroprocessing and (ii) single site catalysis, which appears to be the relevant mode of action in syngas-related catalysis and which occurs over “frustrated” active sites.


2008 ◽  
Vol 127 (3-4) ◽  
pp. 304-311 ◽  
Author(s):  
Magdalena Hasik ◽  
Wincenty Turek ◽  
Anna Nyczyk ◽  
Edyta Stochmal ◽  
Andrzej Bernasik ◽  
...  

2017 ◽  
Vol 366 ◽  
pp. 18-26 ◽  
Author(s):  
Mounika Kodali ◽  
Carlo Santoro ◽  
Sergio Herrera ◽  
Alexey Serov ◽  
Plamen Atanassov

2011 ◽  
Vol 40 (4) ◽  
pp. 1875 ◽  
Author(s):  
Meng Zhou ◽  
Robert H. Crabtree

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