Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido–Germanium(II) and −Tin(II) Hydride Complexes

ACS Catalysis ◽  
2017 ◽  
Vol 7 (3) ◽  
pp. 1853-1859 ◽  
Author(s):  
Terrance J. Hadlington ◽  
Christos E. Kefalidis ◽  
Laurent Maron ◽  
Cameron Jones
Keyword(s):  
Carbon Dioxide ◽  
Hydride Complexes ◽  
Efficient Reduction

Strong Interactions of Metal-Support for Efficient Reduction of Carbon Dioxide into Ethylene

Nano Energy ◽  
2021 ◽  
pp. 106460
Author(s):  
Dongxing Tan ◽  
Bari Wulan ◽  
Xueying Cao ◽  
Jintao Zhang
Keyword(s):  
Carbon Dioxide ◽  
Strong Interactions ◽  
Efficient Reduction ◽  
Metal Support

Facet- and structure-dependent catalytic activity of cuprous oxide/polypyrrole particles towards the efficient reduction of carbon dioxide to methanol

Nanoscale ◽  
2018 ◽  
Vol 10 (25) ◽  
pp. 11869-11880 ◽  
Author(s):  
Arun Prakash Periasamy ◽  
Rini Ravindranath ◽  
Sakkarapalayam Murugesan Senthil Kumar ◽  
Wen-Ping Wu ◽  
Ting-Rui Jian ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Anion Exchange ◽  
Cuprous Oxide ◽  
High Index ◽  
Exchange Mechanism ◽  
Faradaic Efficiency ◽  
Efficient Reduction

Cu2O(OL-MH)/Ppy particles selectively reduce CO2to methanol with a faradaic efficiency of 93 ± 1.2% due to an efficient anion exchange mechanism, dominant low-index (111) facets and high-index (311), (211) facets of Cu2O.

Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

2016 ◽  
Vol 52 (99) ◽  
pp. 14262-14265 ◽  
Author(s):  
Qiang-Qiang Ma ◽  
Ting Liu ◽  
Shujun Li ◽  
Jie Zhang ◽  
Xuenian Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Palladium Catalysts ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Efficient Reduction ◽  
Thiolate Complexes

New palladium catalysts developed for highly efficient hydroboration of CO2 under very mild conditions with turnover frequencies up to 1780 h−1.

Coupling of methyl coenzyme M reduction with carbon dioxide activation in extracts of Methanobacterium thermoautotrophicum

1982 ◽  
Vol 152 (2) ◽  
pp. 840-847
Author(s):  
J A Romesser ◽  
R S Wolfe
Keyword(s):  
Carbon Dioxide ◽  
Co2 Reduction ◽  
Methanobacterium Thermoautotrophicum ◽  
Coenzyme M ◽  
Cell Extracts ◽  
Low Concentrations ◽  
Efficient Reduction ◽  
High Concentrations ◽  
Reduction Of Co2 ◽  
Stimulation Of

The stimulation of carbon dioxide reduction to methane by addition of 2-(methylthio)ethanesulfonate (CH3-S-CoM) to cell extracts of Methanobacterium thermoautotrophicum was investigated. Similar stimulation of CO2 reduction by CH3-S-CoM was found for cell extracts of Methanobacterium bryantii and Methanospirillum hungatei. The CH3-S-CoM requirement could be met by the methanogenic precursors formaldehyde, serine, or pyruvate, or by 2-(ethylthio)ethanesulfonate (CH3CH2-S-CoM), but not by other coenzyme M derivatives. Efficient reduction of CO2 to CH4 was favored by low concentrations of CH3-S-CoM and high concentrations of CO2. Sulfhydryl compounds were identified as effective inhibitors of CO2 reduction. Both an allosteric model and a free-radical model for the mechanism of CO2 activation and reduction are discussed.

Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts

2016 ◽  
Vol 128 (33) ◽  
pp. 9900-9904 ◽  
Author(s):  
Ming Ma ◽  
Bartek J. Trześniewski ◽  
Jie Xie ◽  
Wilson A. Smith
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Efficient Reduction
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