Intrinsically Conductive Perovskite Oxides with Enhanced Stability and Electrocatalytic Activity for Oxygen Reduction Reactions

ACS Catalysis ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 7865-7871 ◽  
Author(s):  
Xiaoming Ge ◽  
Yonghua Du ◽  
Bing Li ◽  
T. S. Andy Hor ◽  
Melinda Sindoro ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Electrocatalytic Activity ◽  
Perovskite Oxides ◽  
Reduction Reactions ◽  
Oxygen Reduction Reactions ◽  
Enhanced Stability

Compositional Engineering of Perovskite Oxides for Highly Efficient Oxygen Reduction Reactions

2015 ◽  
Vol 7 (16) ◽  
pp. 8562-8571 ◽  
Author(s):  
Dengjie Chen ◽  
Chi Chen ◽  
Zhenbao Zhang ◽  
Zarah Medina Baiyee ◽  
Francesco Ciucci ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Perovskite Oxides ◽  
Reduction Reactions ◽  
Oxygen Reduction Reactions ◽  
Highly Efficient

scholarly journals Electrocatalytic Activities towards the Electrochemical Oxidation of Formic Acid and Oxygen Reduction Reactions over Bimetallic, Trimetallic and Core–Shell-Structured Pd-Based Materials

Inorganics ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 36 ◽  
Author(s):  
Takao Gunji ◽  
Futoshi Matsumoto
Keyword(s):  
Fuel Cells ◽  
Formic Acid ◽  
Oxygen Reduction ◽  
Electrocatalytic Activity ◽  
Formic Acid Oxidation ◽  
Acid Oxidation ◽  
Core Shell ◽  
Promising Alternative ◽  
Reduction Reactions ◽  
Oxygen Reduction Reactions

The structural design of nanosized electrocatalysts is extremely important for cathodic oxygen reduction reactions (ORR) and anodic oxidation reactions in small organic compounds in direct fuel cells. While Pt is still the most commonly used electrode material for ORR, the Pd electrocatalyst is a promising alternative to Pt, because it exhibits much higher electrocatalytic activity towards formic acid electrooxidation, and the electrocatalytic activity of ORR on the Pd electrode is the higher than that of all other precious metals, except for Pt. In addition, the mass activity of Pt in a core–shell structure for ORR can be improved significantly by using Pd and Pd-based materials as core materials. Herein, we review various nanoscale Pd-based bimetallic, trimetallic and core–shell electrocatalysts for formic acid oxidation and ORR of polymer electrolyte fuel cells (PEFCs). This review paper is separated into two major topics: the electrocatalytic activity towards formic acid oxidation over various Pd-based electrocatalysts, and the activity of ORR on Pd-based materials and Pd core–Pt shell structures.

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