Simple Ligand Modifications with Pendent OH Groups Dramatically Impact the Activity and Selectivity of Ruthenium Catalysts for Transfer Hydrogenation: The Importance of Alkali Metals

Cameron M. Moore; Byongjoo Bark; Nathaniel K. Szymczak

doi:10.1021/acscatal.6b00229

Simple Ligand Modifications with Pendent OH Groups Dramatically Impact the Activity and Selectivity of Ruthenium Catalysts for Transfer Hydrogenation: The Importance of Alkali Metals

ACS Catalysis ◽

10.1021/acscatal.6b00229 ◽

2016 ◽

Vol 6 (3) ◽

pp. 1981-1990 ◽

Cited By ~ 58

Author(s):

Cameron M. Moore ◽

Byongjoo Bark ◽

Nathaniel K. Szymczak

Keyword(s):

Alkali Metals ◽

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Oh Groups

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Quantum Chemical Calculations with the Inclusion of Nonspecific and Specific Solvation: Asymmetric Transfer Hydrogenation with Bifunctional Ruthenium Catalysts

Journal of the American Chemical Society ◽

10.1021/ja3097674 ◽

2013 ◽

Vol 135 (7) ◽

pp. 2604-2619 ◽

Cited By ~ 109

Author(s):

Pavel A. Dub ◽

Takao Ikariya

Keyword(s):

Quantum Chemical Calculations ◽

Quantum Chemical ◽

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Asymmetric Transfer Hydrogenation ◽

Specific Solvation

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Rapid transfer hydrogenation of acetophenone using ruthenium catalysts bearing commercially available and readily accessible nitrogen and phosphorous donor ligands

Applied Catalysis A General ◽

10.1016/j.apcata.2018.11.031 ◽

2019 ◽

Vol 570 ◽

pp. 367-375 ◽

Cited By ~ 4

Author(s):

Drew J. Braden ◽

Renan Cariou ◽

John W. Shabaker ◽

Russell A. Taylor

Keyword(s):

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Donor Ligands ◽

Rapid Transfer

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Water-Soluble Arene Ruthenium Catalysts Containing Sulfonated Diamine Ligands for Asymmetric Transfer Hydrogenation of α-Aryl Ketones and Imines in Aqueous Solution.

ChemInform ◽

10.1002/chin.200734038 ◽

2007 ◽

Vol 38 (34) ◽

Author(s):

Jerome Canivet ◽

Georg Suess-Fink

Keyword(s):

Aqueous Solution ◽

Ruthenium Catalysts ◽

Water Soluble ◽

Transfer Hydrogenation ◽

Asymmetric Transfer Hydrogenation ◽

Aryl Ketones ◽

Diamine Ligands

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Synthesis and Application of Magnetic Noyori-Type Ruthenium Catalysts for Asymmetric Transfer Hydrogenation Reactions in Water

ACS Sustainable Chemistry & Engineering ◽

10.1021/acssuschemeng.6b00197 ◽

2016 ◽

Vol 4 (5) ◽

pp. 2698-2705 ◽

Cited By ~ 19

Author(s):

Corina M. Eichenseer ◽

Benjamin Kastl ◽

Miquel A. Pericàs ◽

Paul R. Hanson ◽

Oliver Reiser

Keyword(s):

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Asymmetric Transfer Hydrogenation ◽

Hydrogenation Reactions

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Highly efficient homogeneous and heterogenized ruthenium catalysts for transfer hydrogenation of carbonyl compounds

RSC Advances ◽

10.1039/c4ra04136d ◽

2014 ◽

Vol 4 (53) ◽

pp. 27955-27962 ◽

Cited By ~ 15

Author(s):

S. Ganesamoorthy ◽

P. Jerome ◽

K. Shanmugasundaram ◽

R. Karvembu

Keyword(s):

Carbonyl Compounds ◽

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Highly Efficient

[Ru(acac)2(CH3CN)2] and its SiO2 immobilized form were found to be efficient catalysts for the transfer hydrogenation of carbonyl compounds.

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Transfer Hydrogenation in Water via a Ruthenium Catalyst with OH Groups near the Metal Center on a bipy Scaffold

Organometallics ◽

10.1021/om200638p ◽

2011 ◽

Vol 30 (23) ◽

pp. 6339-6342 ◽

Cited By ~ 121

Author(s):

Ismael Nieto ◽

Michelle S. Livings ◽

John B. Sacci ◽

Lauren E. Reuther ◽

Matthias Zeller ◽

...

Keyword(s):

Ruthenium Catalyst ◽

Metal Center ◽

Transfer Hydrogenation ◽

Oh Groups

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Transfer Hydrogenation of Unsaturated Substrates by Half-sandwich Ruthenium Catalysts using Ammonium Formate as Reducing Reagent

ChemistrySelect ◽

10.1002/slct.201701423 ◽

2017 ◽

Vol 2 (25) ◽

pp. 7751-7757 ◽

Cited By ~ 8

Author(s):

Van Hung Mai ◽

San-Hwa Lee ◽

Georgii I. Nikonov

Keyword(s):

Ruthenium Catalysts ◽

Ammonium Formate ◽

Transfer Hydrogenation ◽

Half Sandwich

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New N,N,N-Donors Resulting in Highly Active Ruthenium Catalysts for Transfer Hydrogenation at Room Temperature

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201100459 ◽

2011 ◽

Vol 2011 (23) ◽

pp. 3431-3437 ◽

Cited By ~ 56

Author(s):

Leila Taghizadeh Ghoochany ◽

Saeid Farsadpour ◽

Yu Sun ◽

Werner R. Thiel

Keyword(s):

Room Temperature ◽

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Highly Active

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A Modular Design of Ruthenium Catalysts with Diamine and BINOL-Derived Phosphinite Ligands that Are Enantiomerically-Matched for the Effective Asymmetric Transfer Hydrogenation of Simple Ketones.

ChemInform ◽

10.1002/chin.200543036 ◽

2005 ◽

Vol 36 (43) ◽

Author(s):

Rongwei Guo ◽

Christian Elpelt ◽

Xuanhua Chen ◽

Datong Song ◽

Robert H. Morris

Keyword(s):

Modular Design ◽

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Asymmetric Transfer Hydrogenation

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CNN Pincer Ruthenium Catalysts for Hydrogenation and Transfer Hydrogenation of Ketones: Experimental and Computational Studies

Chemistry - A European Journal ◽

10.1002/chem.201402229 ◽

2014 ◽

Vol 20 (42) ◽

pp. 13603-13617 ◽

Cited By ~ 38

Author(s):

Walter Baratta ◽

Salvatore Baldino ◽

Maria José Calhorda ◽

Paulo J. Costa ◽

Gennaro Esposito ◽

...

Keyword(s):

Ruthenium Catalysts ◽

Transfer Hydrogenation ◽

Computational Studies

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