Role of Ion-Pairs in Brønsted Acid Catalysis

ACS Catalysis ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 6630-6633 ◽  
Author(s):  
Heejae Kim ◽  
Erli Sugiono ◽  
Yuki Nagata ◽  
Manfred Wagner ◽  
Mischa Bonn ◽  
...  
Keyword(s):  
Acid Catalysis ◽  
Ion Pairs ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Bronsted Acid Catalysis

The role of Brønsted acid catalysis in inter-metal ligand exchange reactions

2001 ◽  
pp. 3242 ◽  
Author(s):  
Ian J. Blackmore ◽  
Vernon C. Gibson ◽  
Andrew J. Graham ◽  
Matthew Jolly ◽  
Edward L. Marshall ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Acid Catalysis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Exchange Reactions ◽  
Brönsted Acid ◽  
Metal Ligand ◽  
Bronsted Acid Catalysis

Practical catalytic enantioselective synthesis of 2,3-dihydroquin-azolinones by chiral brønsted acid catalysis

2021 ◽  
Author(s):  
Yongbiao Guo ◽  
Zhenhua Gao ◽  
Junchen Li ◽  
Xiaojing Bi ◽  
Enxue Shi ◽  
...  
Keyword(s):  
Phosphoric Acid ◽  
Acid Catalysis ◽  
Enantioselective Synthesis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Chiral Bronsted Acid ◽  
Bronsted Acid Catalysis

An efficient, practical and scalable protocol to prepare chiral 2,3-dihydroquinazolinones was developed under catalysis of spirocyclic SPINOL-phosphoric acid.

Inhibition by Water during Heterogeneous Brønsted Acid Catalysis by Three-Dimensional Crystalline Organic Salts

2021 ◽  
Author(s):  
Alexander Gak ◽  
Svetlana Kuznetsova ◽  
Yulia Nelyubina ◽  
Alexander A. Korlyukov ◽  
Han Li ◽  
...  
Keyword(s):  
Acid Catalysis ◽  
Three Dimensional ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Organic Salts ◽  
Brönsted Acid ◽  
Bronsted Acid Catalysis

scholarly journals New opportunities in the stereoselective dearomatization of indoles

2016 ◽  
Vol 88 (3) ◽  
pp. 207-214 ◽  
Author(s):  
Elisabetta Manoni ◽  
Assunta De Nisi ◽  
Marco Bandini
Keyword(s):  
Acid Catalysis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Reaction Conditions ◽  
Brönsted Acid ◽  
High Yields ◽  
First Time ◽  
Tailored Design ◽  
Bronsted Acid Catalysis

AbstractThe regio- and stereoselective dearomatization of indoles is realized for the first time by combining readily available indolyl precursors and electron-rich allenes, namely allenamides and aryloxyallenes. Inter- as well as intramolecular condensations were realized under gold and Brønsted acid catalysis providing a range of densely functionalized indoline and indolenine cores in high yields and excellent stereochemical outcome. Chemodivergent reaction profiles (Micheal-type addition vs. [2+2]-cycloaddition) were realized by a tailored design of both reaction conditions and functionalization of the reaction partners.

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