scholarly journals Guidelines for the Rational Design of Ni-Based Double Hydroxide Electrocatalysts for the Oxygen Evolution Reaction

ACS Catalysis ◽  
2015 ◽  
Vol 5 (9) ◽  
pp. 5380-5387 ◽  
Author(s):  
Oscar Diaz-Morales ◽  
Isis Ledezma-Yanez ◽  
Marc T. M. Koper ◽  
Federico Calle-Vallejo
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Rational Design ◽  
Double Hydroxide

scholarly journals 2D Layered Double Hydroxide Nanosheets and Their Derivatives Toward Efficient Oxygen Evolution Reaction

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Xueyi Lu ◽  
Hairong Xue ◽  
Hao Gong ◽  
Mingjun Bai ◽  
Daiming Tang ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Rational Design ◽  
Direct Synthesis ◽  
Future Research ◽  
Highly Active ◽  
Host Metal ◽  
Conductive Substrates ◽  
Double Hydroxide ◽  
Double Hydroxides

AbstractLayered double hydroxides (LDHs) have attracted tremendous research interest in widely spreading applications. Most notably, transition-metal-bearing LDHs are expected to serve as highly active electrocatalysts for oxygen evolution reaction (OER) due to their layered structure combined with versatile compositions. Furthermore, reducing the thickness of platelet LDH crystals to nanometer or even molecular scale via cleavage or delamination provides an important clue to enhance the activity. In this review, recent progresses on rational design of LDH nanosheets are reviewed, including direct synthesis via traditional coprecipitation, homogeneous precipitation, and newly developed topochemical oxidation as well as chemical exfoliation of parent LDH crystals. In addition, diverse strategies are introduced to modulate their electrochemical activity by tuning the composition of host metal cations and intercalated counter-anions, and incorporating dopants, cavities, and single atoms. In particular, hybridizing LDHs with conductive components or in situ growing them on conductive substrates to produce freestanding electrodes can further enhance their intrinsic catalytic activity. A brief discussion on future research directions and prospects is also summarized.

scholarly journals Postsynthetic treatment of nickel–iron layered double hydroxides for the optimum catalysis of the oxygen evolution reaction

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Daire Tyndall ◽  
Sonia Jaskaniec ◽  
Brian Shortall ◽  
Ahin Roy ◽  
Lee Gannon ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Size Control ◽  
Operating Conditions ◽  
Nickel Iron ◽  
Treatment Techniques ◽  
Site Density ◽  
Synthetic Approaches ◽  
Double Hydroxide ◽  
Double Hydroxides

AbstractNickel–iron-layered double hydroxide (NiFe LDH) platelets with high morphological regularity and submicrometre lateral dimensions were synthesized using a homogeneous precipitation technique for highly efficient catalysis of the oxygen evolution reaction (OER). Considering edge sites are the point of activity, efforts were made to control platelet size within the synthesized dispersions. The goal is to controllably isolate and characterize size-reduced NiFe LDH particles. Synthetic approaches for size control of NiFe LDH platelets have not been transferable based on published work with other LDH materials and for that reason, we instead use postsynthetic treatment techniques to improve edge-site density. In the end, size-reduced NiFe LDH/single-wall carbon nanotube (SWCNT) composites allowed to further reduce the OER overpotential to 237 ± 7 mV (<L> = 0.16 ± 0.01 μm, 20 wt% SWCNT), which is one of the best values reported to date. This approach as well improved the long-term activity of the catalyst in operating conditions.

Hierarchically porous FeNi3@FeNi layered double hydroxide nanostructures: One-step fast electrodeposition and highly efficient electrocatalytic performances for overall water splitting

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hierarchically Porous ◽  
One Step ◽  
Double Hydroxide

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...

LDH-derived phosphide/N-doped graphene oxide hierarchical electrocatalyst for enhanced oxygen evolution reaction

CrystEngComm ◽  
2022 ◽  
Author(s):  
Meng Ya Yang ◽  
Rong Zhao ◽  
Yi Liu ◽  
Hua Lin
Keyword(s):  
Graphene Oxide ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hierarchical Structure ◽  
Oxygen Evolution Reaction ◽  
High Efficient ◽  
Doped Graphene ◽  
Double Hydroxide

In this work, high efficient electrocatalyst Fe-Ni2P/N-GO with hierarchical structure was developed through phosphating NiFe-based layered double hydroxide (LDH) supported by N-doped graphene oxide (GO), which was assembled by the...

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