Multiscale Model for a Metal–Organic Framework: High-Spin Rebound Mechanism in the Reaction of the Oxoiron(IV) Species of Fe-MOF-74

ACS Catalysis ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 3287-3291 ◽  
Author(s):  
Hajime Hirao ◽  
Wilson Kwok Hung Ng ◽  
Adhitya Mangala Putra Moeljadi ◽  
Sareeya Bureekaew
Keyword(s):  
High Spin ◽  
Metal Organic Framework ◽  
Multiscale Model ◽  
Metal Organic ◽  
Organic Framework

Self-adaptation of manganese–chloride arrangement toward high spin Mn5(μ-Cl)4cluster-based metal–organic framework with S =15/2

2012 ◽  
Vol 41 (5) ◽  
pp. 1448-1450 ◽  
Author(s):  
Shao-Hsuan Lin ◽  
Chen-I Yang ◽  
Ting-Shen Kuo ◽  
Ming-Hsi Chiang ◽  
Kung-Chung Hsu ◽  
...  
Keyword(s):  
High Spin ◽  
Metal Organic Framework ◽  
Manganese Chloride ◽  
Metal Organic ◽  
Self Adaptation ◽  
Organic Framework

A new two-dimensional metal–organic framework with high spin-filtering efficiency

2015 ◽  
Vol 17 (26) ◽  
pp. 17437-17444 ◽  
Author(s):  
Bikash Mandal ◽  
Pranab Sarkar
Keyword(s):  
Transition Metals ◽  
High Spin ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Filtering Efficiency ◽  
Metal Organic ◽  
Spin Filtering ◽  
Organic Framework

A new metal–organic framework, consisting of substituted naphthalene molecules and transition metals, is proposed with good spin filtering properties.

Incorporation of Pyrazine and Bipyridine Linkers with High-Spin Fe(II) and Co(II) in a Metal–Organic Framework

2017 ◽  
Vol 56 (6) ◽  
pp. 3349-3356 ◽  
Author(s):  
Airi Kawamura ◽  
Arin R. Greenwood ◽  
Alexander S. Filatov ◽  
Audrey T. Gallagher ◽  
Giulia Galli ◽  
...  
Keyword(s):  
High Spin ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Synthesis, X-ray crystal structure and spin polarized DFT study of high spin Mn based metal-organic framework

2019 ◽  
Vol 1175 ◽  
pp. 439-444 ◽  
Author(s):  
Saghir Abbas ◽  
Khurshid Ayub ◽  
Manzar Sohail ◽  
Saqib Ali ◽  
Ralf Ludwig ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Spin ◽  
Metal Organic Framework ◽  
Dft Study ◽  
X Ray ◽  
Spin Polarized ◽  
Metal Organic ◽  
Organic Framework

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

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