High-Performance, Ultralow Platinum Membrane Electrode Assembly Fabricated by In Situ Deposition of a Pt Shell Layer on Carbon-Supported Pd Nanoparticles in the Catalyst Layer Using a Facile Pulse Electrodeposition Approach

ACS Catalysis ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 4318-4324 ◽  
Author(s):  
Dai Dang ◽  
Haobin Zou ◽  
Zi’ang Xiong ◽  
Sanying Hou ◽  
Ting Shu ◽  
...  
2019 ◽  
Vol 41 (1) ◽  
pp. 901-907 ◽  
Author(s):  
Xinyu Huang ◽  
William A. Rigdon ◽  
Jay Neutzler ◽  
Diana Larrabee ◽  
Joshua Sightler

2019 ◽  
Vol 80 ◽  
pp. 527-534 ◽  
Author(s):  
Ji Eun Park ◽  
Mohanraju Karuppannan ◽  
Oh Joong Kwon ◽  
Yong-Hun Cho ◽  
Yung-Eun Sung

Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 802
Author(s):  
Chang Sun ◽  
Yingxin Mu ◽  
Yuxin Wang

Electrochemical ammonia synthesis, which is an alternative approach to the Haber–Bosch process, has attracted the attention of researchers because of its advantages including mild working conditions, environmental protection, and simple process. However, the biggest problem in this field is the lack of high-performance catalysts. Here, we report high-efficiency electroreduction of N2 to NH3 on γ-MnO2-supported Pd nanoparticles (Pd/γ-MnO2) under ambient conditions, which exhibits excellent catalytic activity with an NH3 yield rate of 19.72 μg·mg−1Pd h−1 and a Faradaic efficiency of 8.4% at −0.05 V vs. the reversible hydrogen electrode (RHE). X-ray diffraction (XRD) and transmission electron microscopy (TEM) characterization shows that Pd nanoparticles are homogeneously dispersed on the γ-MnO2. Pd/γ-MnO2 outperforms other catalysts including Pd/C and γ-MnO2 because of its synergistic catalytic effect between Pd and Mn.


RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1333-1338 ◽  
Author(s):  
Huagen Liang ◽  
Ruoyu Xu ◽  
Kaicheng Chen ◽  
Chenyang Shen ◽  
Shibin Yin

Short-term constant voltage discharge test of the self-humidifying MEAs with different cathode structure at 60 °C and 30 psi under 20% RH.


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