Zwitterion-Induced Organic–Metal Hybrid Catalysis in Aerobic Oxidation

ACS Catalysis ◽  
2021 ◽  
pp. 3498-3506
Author(s):  
Rong-Bin Hu ◽  
Ying-Pong Lam ◽  
Wing-Hin Ng ◽  
Chun-Yuen Wong ◽  
Ying-Yeung Yeung
Keyword(s):  
Aerobic Oxidation ◽  
Organic Metal

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Oxidase Catalysis via an Aerobically Generated Dess-Martin Periodinane Analogue

2018 ◽  
Author(s):  
Asim Maity ◽  
Sung-Min Hyun ◽  
Alan Wortman ◽  
David Powers
Keyword(s):  
Chemical Synthesis ◽  
Aerobic Oxidation ◽  
Substrate Oxidation ◽  
Oxidation Catalysis ◽  
Hypervalent Iodine ◽  
Oxidation Reactions ◽  
Broad Array ◽  
Oxidation Chemistry ◽  
Reactive Oxidants

<p>Hypervalent iodine(V) reagents, such as Dess-Martin periodinane (DMP) and 2-iodoxybenzoic acid (IBX), are broadly useful oxidants in chemical synthesis. Development of strategies to access these reagents from O2 would immediately enable use of O2 as a terminal oxidant in a broad array of substrate oxidation reactions. Recently we disclosed the aerobic synthesis of I(III) reagents by intercepting reactive oxidants generated during aldehyde autoxidation. Here, we couple aerobic oxidation of iodobenzenes with disproportionation of the initially generated I(III) compounds to generate I(V) reagents. The aerobically generated I(V) reagents exhibit substrate oxidation chemistry analogous to that of DMP. Further, the developed aerobic generation of I(V) has enabled the first application of I(V) intermediates in aerobic oxidation catalysis.</p>

Recent Development in Aerobic Oxidation of Amines

2012 ◽  
Vol 9 (3) ◽  
pp. 319-340
Author(s):  
Bo-Tao Xin ◽  
Qing-Fa Zhou ◽  
Tao Lu
Keyword(s):  
Aerobic Oxidation

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

Modular Synthesis of 3-Substituted Isocoumarins via Silver-Catalyzed Aerobic Oxidation/6-Endo Heterocyclization of ortho-Alkynylbenzaldehydes

2021 ◽  
Author(s):  
Hao Wu ◽  
Yi-Chun Wang ◽  
Andrey Shatskiy ◽  
Qiu-Yan Li ◽  
Jian-Quan Liu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Modular Synthesis ◽  
Convenient Access

A method involving silver-catalyzed aerobic oxidation/6-endo heterocyclization of ortho-alkynylbenzaldehydes to yield 3-substituted isocumarins is described. The developed protocol allows convenient access to a range of synthetically useful 3-substituted isocoumarins and...

Insights into oxygen activation on metal clusters for catalyst design

2021 ◽  
Author(s):  
LiXin Chen ◽  
Zi Wen ◽  
Zhi Wen Chen ◽  
Qing Jiang ◽  
Chandra Veer Singh
Keyword(s):  
Metal Clusters ◽  
Aerobic Oxidation ◽  
Oxygen Activation ◽  
Vital Role ◽  
Catalyst Design ◽  
Activation Mechanism ◽  
Oxidation Reactions

The activation mechanism of O2 molecules plays a vital role in the development of catalysts for aerobic oxidation reactions. To gain insights into the activation mechanism of O2, the square...

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