Dual-Role Catalysis by Thiobenzoic Acid in Cα–H Arylation under Photoirradiation

ACS Catalysis ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 82-87
Author(s):  
Fumihisa Kobayashi ◽  
Masashi Fujita ◽  
Takafumi Ide ◽  
Yuta Ito ◽  
Kenji Yamashita ◽  
...  
Keyword(s):  
2014 ◽  
Vol 122 (03) ◽  
Author(s):  
A Chatzigeorgiou ◽  
R Garcia-Martin ◽  
KJ Chung ◽  
I Alexaki ◽  
A Klotzsche-von Ameln ◽  
...  

2008 ◽  
Vol 3 (S 1) ◽  
Author(s):  
U Bernhardt ◽  
HG Joost ◽  
H Al-Hasani
Keyword(s):  

2019 ◽  
Author(s):  
Angeliki Karapanagioti ◽  
Flora Spenzta ◽  
Georgios K. Dimitriadis ◽  
Narjes Nasiri-Ansari ◽  
Evi Lianidou ◽  
...  
Keyword(s):  

Author(s):  
Huihui Tang ◽  
Sungdae Park ◽  
Kam C. Yeung
Keyword(s):  

Author(s):  
Tiantian Chen ◽  
Yang Yang ◽  
Liyu Xie ◽  
Haijian Yang ◽  
Guangbin Dong ◽  
...  

<p>We report a Ni(0)-catalyzed cross coupling reaction between simple ketones and 1,3-dienes. A variety of a-allylic alkylation products were formed in an 1,2-addition manner with excellent regioselectivity. Water was found to significantly accelerate this transformation. A HO-Ni-H species generated from oxidative addition of Ni(0) to H<sub>2</sub>O is proposed to play a “dual role” in activating both the ketone and the diene substrate.</p>


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