Copper Makes the Difference: Visible Light-Mediated Atom Transfer Radical Addition Reactions of Iodoform with Olefins

ACS Catalysis ◽  
2020 ◽  
Vol 10 (17) ◽  
pp. 9899-9906 ◽  
Author(s):  
Sebastian Engl ◽  
Oliver Reiser
Keyword(s):  
Visible Light ◽  
Radical Addition ◽  
Addition Reactions ◽  
Atom Transfer ◽  
Atom Transfer Radical Addition ◽  
The Difference

N-Chloroamines as substrates for metal-free photochemical atom-transfer radical addition reactions in continuous flow

2021 ◽  
Author(s):  
Alexander Steiner ◽  
Oscar de Frutos ◽  
Juan A. Rincón ◽  
Carlos Mateos ◽  
Jason Williams ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Radical Addition ◽  
Addition Reactions ◽  
Atom Transfer ◽  
Metal Free ◽  
Atom Transfer Radical Addition

N-Chloroamines have recently seen interest as substrates for atom-transfer radical addition (ATRA) reactions with olefins, to form β-chloroamine products, with complete atom incorporation. We report the development of a fully...

Tricarbonyl rhenium(i) tetrazolato and N-heterocyclic carbene complexes: versatile visible-light-mediated photoredox catalysts

2019 ◽  
Vol 48 (33) ◽  
pp. 12749-12754 ◽  
Author(s):  
Thomas P. Nicholls ◽  
Liam K. Burt ◽  
Peter V. Simpson ◽  
Massimiliano Massi ◽  
Alex C. Bissember
Keyword(s):  
Visible Light ◽  
Radical Addition ◽  
Atom Transfer ◽  
Carbene Complexes ◽  
Atom Transfer Radical Addition

This study demonstrates that structurally-diverse, photoactive rhenium(i) tricarbonyl complexes can mediate representative atom-transfer radical addition, hydrodehalogenation, and α-amino C–H functionalisation reactions.

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