Disassembly of Supported Co and Ni Nanoparticles by Carbon Deposition for the Synthesis of Highly Dispersed and Active Catalysts

ACS Catalysis ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 6231-6239
Author(s):  
Feng Niu ◽  
Zhen Yan ◽  
Bright T. Kusema ◽  
Mounib Bahri ◽  
Ovidiu Ersen ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (15) ◽  
pp. 12699-12707 ◽  
Author(s):  
Jing Si ◽  
Guilong Liu ◽  
Jingge Liu ◽  
Lin Zhao ◽  
Shuangshuang Li ◽  
...  

To improve the anti-sintering and anti-carbon deposition ability of the supported metallic nano catalysts, a new scheme for designing and preparing catalysts for CO methanation is presented in this work.


RSC Advances ◽  
2018 ◽  
Vol 8 (29) ◽  
pp. 15999-16003 ◽  
Author(s):  
Xiaodi Guo ◽  
Hongpeng Kan ◽  
Xinxin Liu ◽  
Hongshuai Geng ◽  
Lianying Wang

Hollow hierarchical Ni@C nanocomposites with highly dispersed Ni nanoparticles (NPs) embedded in well-graphitized carbon matrix have been synthesized by solid-state pyrolysis of simple, well-defined organic–inorganic layered nickel hydroxide.


2018 ◽  
Vol 3 (4) ◽  
pp. 1129-1141 ◽  
Author(s):  
Astha Shukla ◽  
Rajib K. Singha ◽  
Manideepa Sengupta ◽  
Takehiko Sasaki ◽  
Chandrashekar Pendem ◽  
...  

2017 ◽  
Vol 38 (7) ◽  
pp. 1127-1137 ◽  
Author(s):  
Hong-Xia Cao ◽  
Jun Zhang ◽  
Cheng-Long Guo ◽  
Jingguang G. Chen ◽  
Xiang-Kun Ren

2019 ◽  
Vol 481 ◽  
pp. 1538-1548 ◽  
Author(s):  
Jiaojiao Tan ◽  
Jiaming Wang ◽  
Ziyang Zhang ◽  
Zhi Ma ◽  
Luhui Wang ◽  
...  

Energies ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5956
Author(s):  
Chengyang Zhang ◽  
Renkun Zhang ◽  
Hui Liu ◽  
Qinhong Wei ◽  
Dandan Gong ◽  
...  

Sintering and carbon deposition are the two main ways to deactivate Ni-based catalysts during methane reforming. Herein, a stable Ni-CeO2/SiO2(CSC) catalyst was prepared by a one-step colloidal solution combustion method (CSC) and used for dry reforming of methane. In the catalyst, the small Ni particles were confined by CeO2 particles and highly dispersed on the surface of SiO2, forming a spatial confinement structure with a rich Ni-CeO2 interface in the catalyst. The Ni-CeO2/SiO2(CSC) catalyst prepared by the one-step CSC method exhibited superior activity at 700 °C during dry reforming of methane, and the performance of the catalyst was stable after 20 h of reaction with only a small amount of carbon deposition present (1.8%). Due to the spatial confinement effect, Ni was stable and less than 5 nm during reaction. The small Ni particle size and rich Ni-CeO2 interface reduced the rate of carbon deposition. This colloidal combustion method could be applied to prepare stable metal-based catalysts with rich metal–oxide interfaces for high-temperature reactions.


Rare Metals ◽  
2020 ◽  
Author(s):  
Jiang-Wei Li ◽  
Qi Song ◽  
Jiang-Bing Li ◽  
Sheng-Chao Yang ◽  
Yan-Shan Gao ◽  
...  

2018 ◽  
Vol 1 (10) ◽  
pp. 5895-5906 ◽  
Author(s):  
Shengshuai Gao ◽  
Qingda An ◽  
Zuoyi Xiao ◽  
Shangru Zhai ◽  
Dongjiang Yang

RSC Advances ◽  
2017 ◽  
Vol 7 (3) ◽  
pp. 1531-1539 ◽  
Author(s):  
Bo Tang ◽  
Wei-Chao Song ◽  
En-Cui Yang ◽  
Xiao-Jun Zhao

Highly dispersed Ni nanoparticles within graphitic carbon layers were prepared by facile thermolysis of a Ni-MOF, which exhibited outstanding catalytic performance in the chemoselective hydrogenation of diverse functionalized nitro compounds.


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