Low-k and Recyclable High-Performance POSS/Polyamide Composites Based on Diels–Alder Reaction

2019 ◽  
Vol 1 (5) ◽  
pp. 944-952 ◽  
Author(s):  
Kaiju Luo ◽  
Guocheng Song ◽  
Yan Wang ◽  
Junrong Yu ◽  
Jing Zhu ◽  
...  
Keyword(s):  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Low K

High performance epoxy coating with cross-linkable solvent via Diels-Alder reaction for anti-corrosion of concrete

2020 ◽  
Vol 139 ◽  
pp. 105473 ◽  
Author(s):  
Jinfeng Chi ◽  
Guoliang Zhang ◽  
Qingyi Xie ◽  
Chunfeng Ma ◽  
Guangzhao Zhang
Keyword(s):  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Epoxy Coating ◽  
Diels Alder Reaction

Esterification of 5-Norbornene-2,3-Dicarboxylic Anhydride under Titanium Catalyst

2013 ◽  
Vol 634-638 ◽  
pp. 642-646 ◽  
Author(s):  
Sung Ho Park ◽  
Jun Seong Park ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo
Keyword(s):  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
1H Nmr ◽  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Titanium Catalyst ◽  
Light Yellow ◽  
Diels Alder Reaction ◽  
Yield And Purity

Norbornene dicarboxylate was synthesized through esterification under titanium catalyst. The alcohols are 2-ethyl-1-hexanol, n-octanol, 3,5,5-trimethyl-1-hexanol, and n-decanol. The Structures of compounds were identified by 1H-NMR, and then components were identified by high performance liquid chromatography (HPLC). The yield and purity was over 90 % and 95 %, and color of compounds was colorless or light yellow. The maleate as a by-product was occured by the retro Diels-Alder reaction.

High-performance bio-based epoxies from ferulic acid and furfuryl alcohol: synthesis and properties

2021 ◽  
Author(s):  
Jiale Ye ◽  
Songqi Ma ◽  
Binbo Wang ◽  
Qingming Chen ◽  
Kaifeng Huang ◽  
...  
Keyword(s):  
Ferulic Acid ◽  
Furfuryl Alcohol ◽  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Alcohol Synthesis ◽  
Diels Alder Reaction

Ferulic acid-derived diepoxy was facilely synthesized and co-cross-linked with furfuryl alcohol monoepoxy accompanying the Diels–Alder reaction to achieve high-performance thermosets.

scholarly journals Synthesis of Robust MOFs@COFs Porous Hybrid Materials via an Aza‐Diels–Alder Reaction: Towards High‐Performance Supercapacitor Materials

2020 ◽  
Vol 59 (44) ◽  
pp. 19602-19609 ◽  
Author(s):  
Haijun Peng ◽  
Jésus Raya ◽  
Fanny Richard ◽  
Walid Baaziz ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

scholarly journals Studies on Preparation, Characterization and Application of Porous Functionalized Glycidyl Methacrylate-Based Microspheres

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1438 ◽  
Author(s):  
Przemysław Pączkowski ◽  
Barbara Gawdzik
Keyword(s):  
Glycidyl Methacrylate ◽  
High Performance ◽  
Chemical Structure ◽  
Alder Reaction ◽  
Diels Alder ◽  
Porous Structures ◽  
Reverse Phase Hplc ◽  
Polymeric Microspheres ◽  
Diels Alder Reaction ◽  
One Step

A one-step swelling and polymerization technique was used in the synthesis of porous glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) monodisperse polymeric microspheres. The polystyrene (PS) seed obtained in the dispersion polymerization was used as a shape template. The presence of epoxide rings in the chemical structure of microspheres enables their post-polymerization chemical modifications involving: the Diels-Alder reaction with sodium cyclopentadienide and maleic anhydride, the reaction with 4,4′-(bismaleimido)diphenylmethane, and the thiol-Michael reaction with methacryloyl chloride and 2-mercaptopropionic acid. Changing the reaction mixture composition—the amounts of crosslinking monomer and PS seed as well as the type and concentration of porogen porous microspheres of different porous structures were obtained. Their porous structures were characterized in the dry and swollen states. The copolymers obtained from the equimolar monomers mixture modified in the above way were applied as the column packing materials and tested in the reverse-phase HPLC (High-Performance Liquid Chromatography). A few factors influencing morphology and porous structure of microspheres were studied.

Zeolite catalytic synthesis of high‐performance jet‐fuel‐range spiro‐fuel by one‐pot Mannich–Diels–Alder reaction

AIChE Journal ◽  
2019 ◽  
Vol 66 (1) ◽  
Author(s):  
Lun Pan ◽  
Junjian Xie ◽  
Genkuo Nie ◽  
Zheng Li ◽  
Xiangwen Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Jet Fuel ◽  
Alder Reaction ◽  
Catalytic Synthesis ◽  
Diels Alder ◽  
One Pot ◽  
Diels Alder Reaction

scholarly journals Tailoring the Properties of Diels-Alder Reaction Crosslinked High-performance Thermosets by Different Bismaleimides

2019 ◽  
Vol 38 (3) ◽  
pp. 268-277 ◽  
Author(s):  
Kai-Ju Luo ◽  
Li-Bo Huang ◽  
Yan Wang ◽  
Jun-Rong Yu ◽  
Jing Zhu ◽  
...  
Keyword(s):  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

scholarly journals Synthesis of Robust MOFs@COFs Porous Hybrid Materials via an Aza‐Diels–Alder Reaction: Towards High‐Performance Supercapacitor Materials

2020 ◽  
Vol 132 (44) ◽  
pp. 19770-19777 ◽  
Author(s):  
Haijun Peng ◽  
Jésus Raya ◽  
Fanny Richard ◽  
Walid Baaziz ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction
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