Design and Preparation of Benzoxazine Resin with High-Frequency Low Dielectric Constants and Ultralow Dielectric Losses

2019 ◽  
Vol 1 (4) ◽  
pp. 625-630 ◽  
Author(s):  
Jiangbing Chen ◽  
Ming Zeng ◽  
Zijian Feng ◽  
Tao Pang ◽  
Yiwan Huang ◽  
...  
Keyword(s):  
High Frequency ◽  
Dielectric Constants ◽  
Dielectric Losses ◽  
Low Dielectric

A facile method for the preparation of aliphatic main-chain benzoxazine copolymers with high-frequency low dielectric constants

2018 ◽  
Vol 9 (21) ◽  
pp. 2913-2925 ◽  
Author(s):  
Ming Zeng ◽  
Jiangbing Chen ◽  
Qingyu Xu ◽  
Yiwan Huang ◽  
Zijian Feng ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
High Frequency ◽  
Main Chain ◽  
Polymerization Kinetics ◽  
Dielectric Constants ◽  
Low Dielectric

The effects of the reaction solvent on the preparation, polymerization kinetics, and high-frequency dielectric properties of aliphatic main-chain benzoxazine copolymers were investigated.

scholarly journals Dielectric Constants of a Binary Solution Near the Critical Solution Temperature

1973 ◽  
Vol 51 (4) ◽  
pp. 545-550 ◽  
Author(s):  
I. Lubezky ◽  
R. McIntosh
Keyword(s):  
High Frequency ◽  
Binary Solution ◽  
Critical Concentration ◽  
Low Frequency ◽  
Dielectric Constants ◽  
Solution Temperature ◽  
Dielectric Losses ◽  
Theoretical Studies ◽  
Critical Solution Temperature ◽  
Experimental Knowledge

The dielectric constants and dielectric losses of solutions of nitrobenzene and 2,2,4-trimethyl pentane have been measured near the critical solution temperature over a concentration range of 22–75% by weight and in the frequency regions of 5–60 and 1000 – 4000 kHz. It was found that below a critical concentration of 35% maxima existed in ε′ and ε″ at a temperature of 0.3 °C above the critical solution temperature. At higher concentrations the maxima disappeared and phase separation was preceded only by changes in the thermal coefficients dε′/dT and dε″/dT. The present study combined with others indicates that two regions of loss exist for the system near the critical temperature: low frequency losses of a conductive nature and high frequency losses of the Debye type. The published experimental knowledge of such systems remains insufficient to enable a thorough test of the theoretical studies published recently by Snider.

Quartz fiber cloth-reinforced semi-aromatic thermosetting polyimide composite with high-frequency low dielectric constant

2019 ◽  
Vol 32 (1) ◽  
pp. 91-102 ◽  
Author(s):  
Zhen-he Wang ◽  
Hai-xia Yang ◽  
Shi-yong Yang
Keyword(s):  
High Frequency ◽  
Dielectric Constants ◽  
Molar Ratio ◽  
Mechanical And Thermal Properties ◽  
Quartz Fiber ◽  
Aromatic Diamines ◽  
Low Dielectric ◽  
Dielectric Performance ◽  
Different Temperatures ◽  
Good Heat Resistance

We report a series of semi-aromatic thermosetting polyimide (PI) resins that can be used as matrix for copper-clad laminates for high-frequency applications. The poly(amic ester) (PAE) resins derived from the diester of 1,2,4,5-cyclohexanetetracarboxylic dianhydride, aromatic diamines (the mixture of 2,2′-dimethylbenzidine and 2,2′-bis[4-(4-aminophenoxy) phenyl] propane), and the monoester of nadic anhydride were synthesized by Polymerization of Monomer Reactants (PMR) method. The structure conversion of PAE resins at different temperatures was investigated and the B-stage PI powders prepared by thermally baking the PAE resins at 220°C are nearly fully imidized. The viscosities of the B-stage PI powders and the mechanical and thermal properties of the cured PI resins were optimized by varying the molar ratio of the two diamines. The cured PI resins possess low and steady dielectric constants ( Dk) below 3.0 and dielectric dissipation factors ( Df) of less than 0.01 at high frequency of 1–12 GHz. Furthermore, the quartz fiber cloth-reinforced semi-aromatic thermosetting PI composites (QF/PI) exhibit excellent dielectric performance, good heat resistance, and mechanical properties. At a high frequency of 1–12 GHz, the Dk of QF/PI-4 is stable in the range of 3.16–3.2, and the Df is stable in the range of 0.0026–0.0046. These results suggest the potential of the semi-aromatic QF/PI for use in high-frequency IC boards.

scholarly journals Porous (Ba,Sr)TiO3 ceramics for tailoring dielectric and tunability properties: Modelling and experiment

2017 ◽  
Vol 11 (4) ◽  
pp. 235-246 ◽  
Author(s):  
Roxana Stanculescu ◽  
Nadejda Horchidan ◽  
Carmen Galassi ◽  
Mihai Asandulesa ◽  
Leontin Padurariu ◽  
...  
Keyword(s):  
Finite Element Method ◽  
Dielectric Constants ◽  
Dielectric Losses ◽  
Field Inhomogeneity ◽  
3D Finite Element ◽  
Low Dielectric ◽  
Lamellar Graphite ◽  
Bst Ceramics ◽  
3D Finite Element Method ◽  
Ceramic Interfaces

3D Finite Element Method simulations were employed in order to describe tunability properties in anisotropic porous paraelectric structures. The simulations predicted that properties of a ceramic can be tailored by using various levels of porosity. Porous Ba0.6Sr0.4TiO3 (BST) ceramics have been studied in order to investigate the influence of porosity on their functional properties. The BST ceramics with various porosity levels have been obtained by solid-state reaction. Lamellar graphite in different concentration of 10, 20 and 35 vol.%was added as sacrificial pore forming agent. The structural, microstructural, dielectric and tunability properties were investigated. By comparison with dense BST ceramic, porous samples present a fracture mode transformation from intragranular to an intergranular fracture and a decrease of grain size. Lower dielectric constants, low dielectric losses, but higher values of tunability than in the dense material were obtained in the porous BST structures as a result of local field inhomogeneity generated by the presence of air pores-ceramic interfaces.

Dielectric Behavior and Phonon Damping in Low-Dielectric Constant Perovskite Materials

1998 ◽  
Vol 511 ◽  
Author(s):  
Ram S. Katiyar ◽  
Igor Siny ◽  
R. Guo ◽  
A. S. Bhalla
Keyword(s):  
Raman Spectra ◽  
Charge Compensation ◽  
Relaxor Ferroelectrics ◽  
Dielectric Behavior ◽  
Dielectric Constants ◽  
Dielectric Losses ◽  
Low Dielectric ◽  
Close Packed Structure ◽  
Crystal Fibers ◽  
Laser Heated

ABSTRACTWe have carried out a comparative study of the dielectric losses in some complex perovskites with both 1:1 and 1:2 compositions of the B ions, namely, SrAl1/2Nb1/2O3 (SAN), SrAl1/2Ta1/2O3 (SAT) and BaMg1/3Ta2/3O3 (BMT). The samples were prepared in two forms, viz. ceramics and single-crystal fibers, the latter were grown by laser heated pedestal growth technique (LHPG). All of these materials possess low dielectric constants, low losses and high Q values. In contrast to relaxor ferroelectrics, that as a rule exhibit broad features in their Raman spectra, SAN, SAT and especially BMT have very narrow phonon lines in the Raman spectra. A linear correlation is found between the microwave dielectric losses and the width of first order phonon lines in a sequence of BMT → SAT → SAN ceramics with increasing phonon damping. Moreover, the phonon damping decreases in materials with non-close-packed structure where there is enough space for undisturbed phonon vibrations. The problem of charge compensation in compounds with the Bsite disorder is also discussed.

scholarly journals Preparation and Characterization of Electrospun Fluoro-Containing Poly(imide-benzoxazole) Nano-Fibrous Membranes with Low Dielectric Constants and High Thermal Stability

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 537
Author(s):  
Meng-Ge Huangfu ◽  
Deng-Xiong Shen ◽  
Xin-Xin Zhi ◽  
Yan Zhang ◽  
Yan-Jiang Jia ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Dielectric Properties ◽  
High Frequency ◽  
Rapid Development ◽  
Dielectric Constants ◽  
Polymer Materials ◽  
Aromatic Diamines ◽  
Low Dielectric ◽  
Fibrous Membranes ◽  
Poly Imide

The rapid development of advanced high-frequency mobile communication techniques has advanced urgent requirements for polymer materials with high-temperature resistance and good dielectric properties, including low dielectric constants (low-Dk) and low dielectric dissipation factors (low-Df). The relatively poor dielectric properties of common polymer candidates, such as standard polyimides (PIs) greatly limited their application in high-frequency areas. In the current work, benzoxazole units were successfully incorporated into the molecular structures of the fluoro-containing PIs to afford the poly(imide-benzoxazole) (PIBO) nano-fibrous membranes (NFMs) via electrospinning fabrication. First, the PI NFMs were prepared by the electrospinning procedure from organo-soluble PI resins derived from 2,2′-bis(3,4-dicarboxy-phenyl)hexafluoropropane dianhydride (6FDA) and aromatic diamines containing ortho-hydroxy-substituted benzamide units, including 2,2-bis[3-(4-aminobenzamide)-4-hydroxylphenyl]hexafluoropropane (p6FAHP) and 2,2-bis[3-(3-aminobenzamide)-4-hydroxyphenyl]hexafluoropropane (m6FAHP). Then, the PI NFMs were thermally dehydrated at 350 °C in nitrogen to afford the PIBO NFMs. The average fiber diameters (dav) for the PIBO NFMs were 1225 nm for PIBO-1 derived from PI-1 (6FDA-p6FAHP) precursor and 816 nm for PIBO-2 derived from PI-2 (6FDA-m6FAHP). The derived PIBO NFMs showed good thermal stability with the glass transition temperatures (Tgs) over 310 °C and the 5% weight loss temperatures (T5%) higher than 500 °C in nitrogen. The PIBO NFMs showed low dielectric features with the Dk value of 1.64 for PIBO-1 and 1.82 for PIBO-2 at the frequency of 1 MHz, respectively. The Df values were in the range of 0.010~0.018 for the PIBO NFMs.

Microstructure, Crystalline Phase, and Dielectric Property Analyses of TiO2 Composition with ZrO2 Addition

2010 ◽  
Vol 660-661 ◽  
pp. 641-645
Author(s):  
José Vitor C. Souza ◽  
Pedro José Castro ◽  
Maria do Carmo de Andrade Nono ◽  
Sergio Luiz Mineiro
Keyword(s):  
High Dielectric Constant ◽  
Raw Materials ◽  
Weight Ratio ◽  
Satellite Communications ◽  
Dielectric Constants ◽  
Sintering Behavior ◽  
Dielectric Losses ◽  
Low Dielectric ◽  
A Value ◽  
High Dielectric

For microwave applications, including mobile and satellite communications, ceramic resonators should have a high dielectric constant, low dielectric losses, and high frequency stability. In this sense, TiO2-ZrO2 ceramics have been investigated as a function of sintering behavior, phase composition, and microstructure. The ceramics were densified reaching a value of about 86% of theoretical density at 1400°C sintering temperature. The ceramics are prepared by mixing raw materials with the following TiO2-ZrO2 weight % ratio: 100 to 0, 90 to 10, and 80 to 20, respectively. The measured dielectric constants are between 79 and 88 values, while the quality factor due to dielectric losses are between 2820 and 5170. These results point out the influence of Ti/Zr ratio on controlling the dielectric properties.

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