scholarly journals High-Performance Bipolar Membrane Development for Improved Water Dissociation

2020 ◽  
Vol 2 (11) ◽  
pp. 4559-4569 ◽  
Author(s):  
Yingying Chen ◽  
Jacob A. Wrubel ◽  
W. Ellis Klein ◽  
Sadia Kabir ◽  
Wilson A. Smith ◽  
...  
2021 ◽  
Vol 9 (12) ◽  
pp. 7955-7966
Author(s):  
Jae-Hun Kim ◽  
In Seop Chang ◽  
Seung-Hyeon Moon

An acid–base junction flow battery (ABJFB) is a new type of energy conversion system using neutralization and water dissociation in the presence of acid and base electrolytes.


2020 ◽  
Vol 92 (9) ◽  
pp. 6263-6268 ◽  
Author(s):  
Yue Sun ◽  
Shiyuan Lin ◽  
Feifang Zhang ◽  
Bingcheng Yang

1999 ◽  
Vol 42 (6) ◽  
pp. 589-598 ◽  
Author(s):  
Tongwen Xu ◽  
Weihua Yang ◽  
Binglin He

Author(s):  
Subarna Kole ◽  
Gokul Venugopalan ◽  
Deepra Bhattacharya ◽  
Le Zhang ◽  
John Cheng ◽  
...  

Left image is the relationship for the overpotential for water dissociation as a function of bipolar junction electric field whereas the right image presents micrographs and the procedure to make bipolar membranes with micropatterned interfaces.


2020 ◽  
Author(s):  
Xinyue Wang ◽  
Xiahan Sang ◽  
Chung-Li Dong ◽  
Siyu Yao ◽  
Ling Shuai ◽  
...  

Abstract Electrocatalysts play a key role in accelerating the sluggish electrochemical CO2 reduction (ECR) involving multi-electron and proton transfer. Herein, we develop a proton capture strategy via accelerating the water dissociation reaction catalyzed by transition metal nanoparticles (NPs) adjacent to atomically dispersed Ni-Nx active sites (Ni@NiNCM) to accelerate the proton transfer to the latter for boosting the intermediate protonation step, and hence the whole ECR process. For the first time, the accelerated protonation process is amply demonstrated experimentally. Aberration-corrected scanning transmission electron microscopy and synchrotron radiation X-ray absorption spectroscopy, together with DFT calculations, revealed that the Ni NPs accelerated the adsorbed H (Had) generation and transfer to the adjacent Ni-Nx sites for boosting the intermediate protonation and the overall ECR processes. This proton capture strategy is highly general, which can be extended to the design and preparation of various high-performance catalysts for diverse electrochemical reactions even beyond ECR.


2007 ◽  
Vol 316 (2) ◽  
pp. 604-611 ◽  
Author(s):  
Yanhong Xue ◽  
Tongwen Xu ◽  
Rongqiang Fu ◽  
Yiyun Cheng ◽  
Weihua Yang

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