scholarly journals Assembly of Disordered Cocontinuous Morphologies by Multiblock Copolymers with Random Block Sequence and Length Dispersity

2020 ◽  
Vol 2 (8) ◽  
pp. 3282-3290
Author(s):  
Di Zeng ◽  
Rohit Gupta ◽  
E. Bryan Coughlin ◽  
Ryan C. Hayward
Keyword(s):  
Multiblock Copolymers ◽  
Block Sequence ◽  
Random Block

Morphological studies of linear (AB)n multiblock copolymers and their blends

1992 ◽  
Vol 50 (1) ◽  
pp. 384-385
Author(s):  
Richard J. Spontak ◽  
Steven D. Smith ◽  
Arman Ashraf
Keyword(s):  
Electron Microscopy ◽  
Microphase Separation ◽  
Multiblock Copolymers ◽  
First Order ◽  
Morphological Studies ◽  
Transmission Electron ◽  
First Order Phase Transition ◽  
Covalently Bonded ◽  
Total Molecular Weight ◽  
First Order Phase

Block copolymers are composed of sequences of dissimilar chemical moieties covalently bonded together. If the block lengths of each component are sufficiently long and the blocks are thermodynamically incompatible, these materials are capable of undergoing microphase separation, a weak first-order phase transition which results in the formation of an ordered microstructural network. Most efforts designed to elucidate the phase and configurational behavior in these copolymers have focused on the simple AB and ABA designs. Few studies have thus far targeted the perfectly-alternating multiblock (AB)n architecture. In this work, two series of neat (AB)n copolymers have been synthesized from styrene and isoprene monomers at a composition of 50 wt% polystyrene (PS). In Set I, the total molecular weight is held constant while the number of AB block pairs (n) is increased from one to four (which results in shorter blocks). Set II consists of materials in which the block lengths are held constant and n is varied again from one to four (which results in longer chains). Transmission electron microscopy (TEM) has been employed here to investigate the morphologies and phase behavior of these materials and their blends.

Super2- Structures in Polydisperse Multiblock-Copolymers

1997 ◽  
Vol 7 (10) ◽  
pp. 1489-1497 ◽  
Author(s):  
A. N. Semenov
Keyword(s):  
Multiblock Copolymers

THE IMPACT OF MINERAL FERTILIZERS ON THE BIOLOGICAL YIELD OF SUGAR BEET CROP (BETA VULGARIS L. VAR. SACCHARIFERA)

2018 ◽  
Vol 28 (4) ◽  
pp. 1281-1284
Author(s):  
Petar Petrov ◽  
Bojan Mitrovski
Keyword(s):  
Sugar Beet ◽  
Field Trials ◽  
Mineral Fertilizers ◽  
Qualitative Properties ◽  
New Production ◽  
Economic Significance ◽  
Random Block ◽  
Biological Yield ◽  
Sugar Beet Crop ◽  
The Impact

Due to the great economic significance of the sugar beet, the new production trends are aimed at improving the quantitative and qualitative properties and one of the basic agro technical measures that is directly dependent on the yield and quality of the turnip is the properly conducted plant nutrition. Exporting high quantities of nutrients from the soil, the sugar beet requires application of advanced agro-technology, primarily application of adequate and controlled nutrition and irrigation. Application of this measure, in combination with soil processing, has sustained influence over the following cultures in the crop rotation in terms of nutrients regiment and fight against weeds.In order to determine the effects of mineral fertilizers on sugar beet, field experiment was conducted on fluvisol soil. The experiment is set according to a random block system, following the standard methods of agricultural chemistry for conducting field trials. The experiment includes eight variants, as follows: 1. Control (non-fertilized), 2. NP, 3. NK, 4. PK, 5. NPK, 6. N2PK, 7. N2P2K, 8. N3PK.In the phase of technological maturity of sugar beet, collection of the vegetative material and measurement of the height of the biological yield of the turnips was carried out. Based on the survey results, it can be concluded that the variant N2P2K has achieved the highest yield of swollen roots, i.e. 69.330 kg/ha. The highest yield of leafy greens was achieved in the variant N3PK, i.e. 41.920 kg/ha, which indicates the fact that nitrogen has direct influence over the vegetation mass of sugar beet.

scholarly journals Increasing selection gain and accuracy of harvest prediction models in Jatropha through genome-wide selection

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Adriano dos Santos ◽  
Erina Vitório Rodrigues ◽  
Bruno Galvêas Laviola ◽  
Larissa Pereira Ribeiro Teodoro ◽  
Paulo Eduardo Teodoro ◽  
...  
Keyword(s):  
Prediction Models ◽  
Block Design ◽  
Phenotypic Selection ◽  
Breeding Population ◽  
Breeding Cycle ◽  
Selection Cycle ◽  
Genome Wide ◽  
Random Block ◽  
Random Block Design ◽  
Number Of Individuals

AbstractGenome-wide selection (GWS) has been becoming an essential tool in the genetic breeding of long-life species, as it increases the gain per time unit. This study had a hypothesis that GWS is a tool that can decrease the breeding cycle in Jatropha. Our objective was to compare GWS with phenotypic selection in terms of accuracy and efficiency over three harvests. Models were developed throughout the harvests to evaluate their applicability in predicting genetic values in later harvests. For this purpose, 386 individuals of the breeding population obtained from crossings between 42 parents were evaluated. The population was evaluated in random block design, with six replicates over three harvests. The genetic effects of markers were predicted in the population using 811 SNP's markers with call rate = 95% and minor allele frequency (MAF) > 4%. GWS enables gains of 108 to 346% over the phenotypic selection, with a 50% reduction in the selection cycle. This technique has potential for the Jatropha breeding since it allows the accurate obtaining of GEBV and higher efficiency compared to the phenotypic selection by reducing the time necessary to complete the selection cycle. In order to apply GWS in the first harvests, a large number of individuals in the breeding population are needed. In the case of few individuals in the population, it is recommended to perform a larger number of harvests.

Toward Olefin Multiblock Copolymers with Tailored Properties: A Molecular Perspective

2021 ◽  
pp. 2100003
Author(s):  
Yousef Mohammadi ◽  
Mohammad Reza Saeb ◽  
Alexander Penlidis ◽  
Esmaiel Jabbari ◽  
Florian J. Stadler ◽  
...  
Keyword(s):  
Multiblock Copolymers

Multiblock Copolymers by Thiol Addition Across Norbornene

2014 ◽  
Vol 3 (5) ◽  
pp. 453-457 ◽  
Author(s):  
Catherine N. Walker ◽  
Joel M. Sarapas ◽  
Vanessa Kung ◽  
Ashley L. Hall ◽  
Gregory N. Tew
Keyword(s):  
Multiblock Copolymers
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