ATRP Initiators Based on Proton Transfer Benzazole Dyes: Solid-State Photoactive Polymer with Very Large Stokes Shift

2020 ◽  
Vol 2 (3) ◽  
pp. 1406-1416 ◽  
Author(s):  
Jônatas Faleiro Berbigier ◽  
Luís Gustavo Teixeira Alves Duarte ◽  
Matheus Fialho Zawacki ◽  
Bruno Bercini de Araújo ◽  
Cristtofer de Moura Santos ◽  
...  
Keyword(s):  
Solid State ◽  
Proton Transfer ◽  
Stokes Shift ◽  
Large Stokes Shift

scholarly journals Facile Synthesis of an Organic Solid State Near-Infrared-Emitter with Large Stokes Shift via Excited-State Intramolecular Proton Transfer

ACS Omega ◽  
2018 ◽  
Vol 3 (10) ◽  
pp. 14341-14348 ◽  
Author(s):  
Abhishek Kumar Gupta ◽  
Ashwani Kumar ◽  
Ranjit Singh ◽  
Manisha Devi ◽  
Abhimanew Dhir ◽  
...  
Keyword(s):  
Excited State ◽  
Solid State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Facile Synthesis ◽  
Large Stokes Shift ◽  
Organic Solid ◽  
Infrared Emitter

Deciphering the grounds of the suitability of acylhydrazones as efficient photoswitches

2019 ◽  
Vol 21 (29) ◽  
pp. 16075-16082 ◽  
Author(s):  
Miquel Moreno ◽  
Ricard Gelabert ◽  
José M. Lluch
Keyword(s):  
Proton Transfer ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Large Stokes Shift

Calculations on several acylhydrazones are carried out to explain their diverse photochemistry experimentally observed. Results disclose the role of the intramolecular proton transfer or the loss of the azidic proton in the large Stokes shift.

scholarly journals An NIR-emitting lysosome-targeting probe with large Stokes shift via coupling cyanine and excited-state intramolecular proton transfer

2017 ◽  
Vol 53 (26) ◽  
pp. 3697-3700 ◽  
Author(s):  
Dipendra Dahal ◽  
Lucas McDonald ◽  
Xiaoman Bi ◽  
Chathura Abeywickrama ◽  
Farai Gombedza ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Large Stokes Shift

A NIR-emitting probe with a large Stokes shift (Δλ ≈ 234 nm) can selectively show lysosome organelles without exhibiting “an alkalinizing effect”.

scholarly journals Large Stokes shift fluorescence activation in an RNA aptamer by intermolecular proton transfer to guanine

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mateusz Mieczkowski ◽  
Christian Steinmetzger ◽  
Irene Bessi ◽  
Ann-Kathrin Lenz ◽  
Alexander Schmiedel ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Base Pair ◽  
Fluorescent Proteins ◽  
Stokes Shift ◽  
Fluorescence Emission ◽  
Rna Aptamers ◽  
Rna Aptamer ◽  
Time Resolved ◽  
Large Stokes Shift ◽  
Mechanistic Basis

AbstractFluorogenic RNA aptamers are synthetic functional RNAs that specifically bind and activate conditional fluorophores. The Chili RNA aptamer mimics large Stokes shift fluorescent proteins and exhibits high affinity for 3,5-dimethoxy-4-hydroxybenzylidene imidazolone (DMHBI) derivatives to elicit green or red fluorescence emission. Here, we elucidate the structural and mechanistic basis of fluorescence activation by crystallography and time-resolved optical spectroscopy. Two co-crystal structures of the Chili RNA with positively charged DMHBO+ and DMHBI+ ligands revealed a G-quadruplex and a trans-sugar-sugar edge G:G base pair that immobilize the ligand by π-π stacking. A Watson-Crick G:C base pair in the fluorophore binding site establishes a short hydrogen bond between the N7 of guanine and the phenolic OH of the ligand. Ultrafast excited state proton transfer (ESPT) from the neutral chromophore to the RNA was found with a time constant of 130 fs and revealed the mode of action of the large Stokes shift fluorogenic RNA aptamer.

A novel 2-(2′-aminophenyl)benzothiazole derivative displays ESIPT and permits selective detection of Zn2+ ions: experimental and theoretical studies

RSC Advances ◽  
2016 ◽  
Vol 6 (75) ◽  
pp. 71496-71500 ◽  
Author(s):  
Subramaniyan Janakipriya ◽  
Selvaraj Tamilmani ◽  
Sathiah Thennarasu
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Theoretical Studies ◽  
Selective Detection ◽  
Large Stokes Shift ◽  
Benzothiazole Derivative ◽  
Experimental And Theoretical Studies

Synthesis of a novel 2-(2′-aminophenyl)benzothiazole based probe (1) and demonstration of excited state intramolecular proton transfer (ESIPT) with a large Stokes shift (∼246 nm) are presented.

Near-infrared fluorescent dyes with large Stokes shifts: light generation in BODIPYs undergoing excited state intramolecular proton transfer

2017 ◽  
Vol 15 (19) ◽  
pp. 4072-4076 ◽  
Author(s):  
Qiang Fei ◽  
Xianfeng Gu ◽  
Yajing Liu ◽  
Ben Shi ◽  
Hengyan Liu ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Near Infrared ◽  
Fluorescent Dyes ◽  
Stokes Shift ◽  
Intramolecular Proton Transfer ◽  
Large Stokes Shift ◽  
Light Generation ◽  
Stokes Shifts

New ESIPT-based BODIPYs are developed to render the NIR emissions with a large Stokes shift.

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