scholarly journals High Aspect Ratio Plasmonic Nanotrench Structures with Large Active Surface Area for Label-Free Mid-Infrared Molecular Absorption Sensing

2018 ◽  
Vol 1 (3) ◽  
pp. 1212-1218 ◽  
Author(s):  
Evgeniy Shkondin ◽  
Taavi Repän ◽  
Mohammad Esmail Aryaee Panah ◽  
Andrei V. Lavrinenko ◽  
Osamu Takayama
Keyword(s):  
Aspect Ratio ◽  
Surface Area ◽  
High Aspect Ratio ◽  
Active Surface ◽  
Active Surface Area ◽  
Label Free ◽  
Molecular Absorption ◽  
Mid Infrared

Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

2019 ◽  
Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Layer ◽  
Active Surface ◽  
Active Surface Area ◽  
High Concentration ◽  
Copper Electrodes ◽  
Surface Enhanced ◽  
Local Current

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>

Accelerating ion diffusion with unique three-dimensionally interconnected nanopores for self-membrane high-performance pseudocapacitors

Nanoscale ◽  
2017 ◽  
Vol 9 (46) ◽  
pp. 18311-18317 ◽  
Author(s):  
Yuan Gao ◽  
Yuanjing Lin ◽  
Zehua Peng ◽  
Qingfeng Zhou ◽  
Zhiyong Fan
Keyword(s):  
Aspect Ratio ◽  
Surface Area ◽  
Structural Stability ◽  
High Aspect Ratio ◽  
High Performance ◽  
Three Dimensional ◽  
Rate Capability ◽  
Large Surface Area ◽  
Nanoporous Structure ◽  
Ion Diffusion

Three-dimensional interconnected nanoporous structure (3-D INPOS) possesses high aspect ratio, large surface area, as well as good structural stability. Profiting from its unique interconnected architecture, the 3-D INPOS pseudocapacitor achieves a largely enhanced capacitance and rate capability.

Increasing Active Surface Area to Fabricate Ultra-Hydrophobic Surface by Using “Black Silicon” with Bosch Etching Process

2012 ◽  
Vol 12 (6) ◽  
pp. 4919-4927 ◽  
Author(s):  
Nithi Atthi ◽  
Jakrapong Supadech ◽  
Gaetan Dupuy ◽  
On-uma Nimittrakoolchai ◽  
Apirak Pankiew ◽  
...  
Keyword(s):  
Surface Area ◽  
Hydrophobic Surface ◽  
Active Surface ◽  
Etching Process ◽  
Black Silicon ◽  
Active Surface Area

Label-free biosensing by means of periodic lattices of high aspect ratio SU-8 nano-pillars

2010 ◽  
Vol 25 (12) ◽  
pp. 2553-2558 ◽  
Author(s):  
M. Holgado ◽  
C.A. Barrios ◽  
F.J. Ortega ◽  
F.J. Sanza ◽  
R. Casquel ◽  
...  
Keyword(s):  
Aspect Ratio ◽  
High Aspect Ratio ◽  
Label Free

Functionalization and Tip-open of Carbon Nanotubes for High-Performance Symmetric Supercapacitor

2021 ◽  
Author(s):  
Yaxiong Zhang ◽  
Erqing Xie
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Aspect Ratio ◽  
Specific Surface ◽  
Surface Area ◽  
Chemical Stability ◽  
High Aspect Ratio ◽  
High Performance ◽  
Large Specific Surface Area ◽  
Symmetric Supercapacitor

Carbon nanotubes (CNTs) have been widely studied as supercapacitor electrodes because of their excellent conductivity, high aspect ratio, excellent mechanical properties, chemical stability, and large specific surface area. However, the...

scholarly journals TCAD Simulations of High-Aspect-Ratio Nano-biosensor for Label-Free Sensing Application

2021 ◽  
Author(s):  
Rakshita Pritam Singh Dhar ◽  
Naveen Kumar ◽  
Cristina Medina-Bailon ◽  
Cesar Pascual Garcia ◽  
Vihar Petkov Georigiev
Keyword(s):  
Aspect Ratio ◽  
High Aspect Ratio ◽  
Label Free ◽  
Sensing Application ◽  
Tcad Simulations

Facile deposition of Pt nanoparticles on Sb-doped SnO2 support with outstanding active surface area for the oxygen reduction reaction

2018 ◽  
Vol 8 (10) ◽  
pp. 2672-2685 ◽  
Author(s):  
Rhiyaad Mohamed ◽  
Tobias Binninger ◽  
Patricia J. Kooyman ◽  
Armin Hoell ◽  
Emiliana Fabbri ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Surface Area ◽  
Pt Nanoparticles ◽  
Active Surface ◽  
Reduction Reaction ◽  
Active Surface Area

Synthesis of Sb–SnO2 supported Pt nanoparticles with an outstanding ECSA for the oxygen reduction reaction.

scholarly journals High-aspect-ratio mushroom-like silica nanopillars immersed in air: epsilon-near-zero metamaterials mediated by a phonon-polaritonic anisotropy

RSC Advances ◽  
2019 ◽  
Vol 9 (29) ◽  
pp. 16431-16438
Author(s):  
Kota Ito ◽  
Yuri Yamada ◽  
Atsushi Miura ◽  
Hideo Iizuka
Keyword(s):  
Block Copolymers ◽  
Aspect Ratio ◽  
High Aspect Ratio ◽  
Self Assembly ◽  
Infrared Range ◽  
Mid Infrared ◽  
Zero Response ◽  
Epsilon Near Zero

High-aspect-ratio mushroom-like silica nanopillars fabricated from self-assembly of block-copolymers exhibit a uniaxial epsilon-near-zero response in the mid-infrared range.

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