Solid-State Synthesis of Defect-Rich Zr-UiO-66 Metal–Organic Framework Nanoparticles for the Catalytic Ring Opening of Epoxides with Alcohols

2021 ◽  
Author(s):  
Haojie Zhao ◽  
Beili Yi ◽  
Xiaomeng Si ◽  
Lei Cao ◽  
Longxing Su ◽  
...  
Keyword(s):  
Solid State ◽  
Ring Opening ◽  
Metal Organic Framework ◽  
Solid State Synthesis ◽  
Metal Organic ◽  
Ring Opening Of Epoxides ◽  
Organic Framework

Copper-based metal-organic framework for the facile ring-opening of epoxides

2008 ◽  
Vol 257 (2) ◽  
pp. 390-395 ◽  
Author(s):  
D JIANG ◽  
T MALLAT ◽  
F KRUMEICH ◽  
A BAIKER
Keyword(s):  
Ring Opening ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Ring Opening Of Epoxides ◽  
Organic Framework

scholarly journals Research Update: A hafnium-based metal-organic framework as a catalyst for regioselective ring-opening of epoxides with a mild hydride source

APL Materials ◽  
2014 ◽  
Vol 2 (12) ◽  
pp. 123901 ◽  
Author(s):  
Casey J. Stephenson ◽  
M. Hassan Beyzavi ◽  
Rachel C. Klet ◽  
Joseph T. Hupp ◽  
Omar K. Farha
Keyword(s):  
Ring Opening ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Ring Opening Of Epoxides ◽  
Organic Framework

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

ChemInform Abstract: Enantioselective Ring-Opening Reaction of Epoxides with MeOH Catalyzed by Homochiral Metal-Organic Framework.

ChemInform ◽  
2012 ◽  
Vol 43 (41) ◽  
pp. no-no
Author(s):  
Koichi Tanaka ◽  
Ken-ichi Otani ◽  
Takanori Murase ◽  
Shyota Nishihote ◽  
Zofia Urbanczyk-Lipkowska
Keyword(s):  
Ring Opening ◽  
Metal Organic Framework ◽  
Ring Opening Reaction ◽  
Metal Organic ◽  
Organic Framework

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

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