High-Energy Density Li–O2 Battery with a Polymer Electrolyte-Coated CNT Electrode via the Layer-by-Layer Method

2020 ◽  
Vol 12 (15) ◽  
pp. 17385-17395 ◽  
Author(s):  
Hyunpyo Lee ◽  
Dong Joon Lee ◽  
Mokwon Kim ◽  
Hyunjin Kim ◽  
Young Shik Cho ◽  
...  
Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1433 ◽  
Author(s):  
Ahmed S. F. M. Asnawi ◽  
Shujahadeen B. Aziz ◽  
Muaffaq M. Nofal ◽  
Muhamad H. Hamsan ◽  
Mohamad A. Brza ◽  
...  

In this study, the solution casting method was employed to prepare plasticized polymer electrolytes of chitosan (CS):LiCO2CH3:Glycerol with electrochemical stability (1.8 V). The electrolyte studied in this current work could be established as new materials in the fabrication of EDLC with high specific capacitance and energy density. The system with high dielectric constant was also associated with high DC conductivity (5.19 × 10−4 S/cm). The increase of the amorphous phase upon the addition of glycerol was observed from XRD results. The main charge carrier in the polymer electrolyte was ion as tel (0.044) < tion (0.956). Cyclic voltammetry presented an almost rectangular plot with the absence of a Faradaic peak. Specific capacitance was found to be dependent on the scan rate used. The efficiency of the EDLC was observed to remain constant at 98.8% to 99.5% up to 700 cycles, portraying an excellent cyclability. High values of specific capacitance, energy density, and power density were achieved, such as 132.8 F/g, 18.4 Wh/kg, and 2591 W/kg, respectively. The low equivalent series resistance (ESR) indicated that the EDLC possessed good electrolyte/electrode contact. It was discovered that the power density of the EDLC was affected by ESR.


2019 ◽  
Vol 43 (47) ◽  
pp. 18935-18942 ◽  
Author(s):  
Cheng-Long Geng ◽  
Le-Qing Fan ◽  
Chun-Yan Wang ◽  
Yong-Lan Wang ◽  
Si-Jia Sun ◽  
...  

A redox-active gel polymer electrolyte with a high working voltage was synthesized and used for assembling a quasi-solid-state supercapacitor possessing high energy density.


RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55225-55232 ◽  
Author(s):  
Kanjun Sun ◽  
Feitian Ran ◽  
Guohu Zhao ◽  
Yanrong Zhu ◽  
Yanping Zheng ◽  
...  

A novel redox-mediated gel polymer (PVA–H2SO4–ARS) is prepared, and a symmetric supercapacitor using the gel polymer as electrolyte and activated carbon as electrode is also assembled.


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