Water-Tolerant DUT-Series Metal–Organic Frameworks: A Theoretical–Experimental Study for the Chemical Fixation of CO2 and Catalytic Transfer Hydrogenation of Ethyl Levulinate to γ-Valerolactone

2019 ◽  
Vol 11 (44) ◽  
pp. 41458-41471 ◽  
Author(s):  
Jintu Francis Kurisingal ◽  
Yadagiri Rachuri ◽  
Athulya S. Palakkal ◽  
Renjith S. Pillai ◽  
Yunjang Gu ◽  
...  
Keyword(s):  
Experimental Study ◽  
Metal Organic Frameworks ◽  
Transfer Hydrogenation ◽  
Chemical Fixation ◽  
Catalytic Transfer Hydrogenation ◽  
Ethyl Levulinate ◽  
Metal Organic ◽  
Catalytic Transfer

Catalytic transfer hydrogenation of ethyl levulinate to γ-valerolactone over zirconium-based metal–organic frameworks

2016 ◽  
Vol 18 (16) ◽  
pp. 4542-4552 ◽  
Author(s):  
Anil H. Valekar ◽  
Kyung-Ho Cho ◽  
Sachin K. Chitale ◽  
Do-Young Hong ◽  
Ga-Young Cha ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Ethyl Levulinate ◽  
Metal Organic ◽  
Catalytic Transfer

A series of zirconium-based MOFs with different ligand functionalities and porosities were applied for catalytic transfer hydrogenation of ethyl levulinate to form γ-valerolactone, using isopropanol as a hydrogen donor.

Phosphorus-modified zirconium metal organic frameworks for catalytic transfer hydrogenation of furfural

2020 ◽  
Vol 44 (46) ◽  
pp. 20308-20315
Author(s):  
Yue Wang ◽  
Jin Huang ◽  
Shiyu Lu ◽  
Pei Li ◽  
Xinxin Xia ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Metal Organic ◽  
Catalytic Transfer ◽  
Zirconium Metal ◽  
Organic Framework

Phosphorus-modified Zr-metal organic framework (P/Zr-MOF) catalysts were synthesized by a (NH4)2HPO4 pyrolysis approach starting from Zr-MOFs.

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