Dioxolanone-Anchored Poly(allyl ether)-Based Cross-Linked Dual-Salt Polymer Electrolytes for High-Voltage Lithium Metal Batteries

2019 ◽  
Vol 12 (1) ◽  
pp. 567-579 ◽  
Author(s):  
Vidyanand Vijayakumar ◽  
Diddo Diddens ◽  
Andreas Heuer ◽  
Sreekumar Kurungot ◽  
Martin Winter ◽  
...  
Keyword(s):  
High Voltage ◽  
Polymer Electrolytes ◽  
Allyl Ether ◽  
Lithium Metal ◽  
Lithium Metal Batteries

scholarly journals Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2468
Author(s):  
Hui Zhan ◽  
Mengjun Wu ◽  
Rui Wang ◽  
Shuohao Wu ◽  
Hao Li ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Specific Capacity ◽  
Sio2 Nanoparticles ◽  
Inorganic Materials ◽  
Solid Polymer Electrolytes ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries

Composite polymer electrolytes (CPEs) incorporate the advantages of solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs), which have shown huge potential in the application of safe lithium-metal batteries (LMBs). Effectively avoiding the agglomeration of inorganic fillers in the polymer matrix during the organic–inorganic mixing process is very important for the properties of the composite electrolyte. Herein, a partial cross-linked PEO-based CPE was prepared by porous vinyl-functionalized silicon (p-V-SiO2) nanoparticles as fillers and poly (ethylene glycol diacrylate) (PEGDA) as cross-linkers. By combining the mechanical rigidity of ceramic fillers and the flexibility of PEO, the as-made electrolyte membranes had excellent mechanical properties. The big special surface area and pore volume of nanoparticles inhibited PEO recrystallization and promoted the dissolution of lithium salt. Chemical bonding improved the interfacial compatibility between organic and inorganic materials and facilitated the homogenization of lithium-ion flow. As a result, the symmetric Li|CPE|Li cells could operate stably over 450 h without a short circuit. All solid Li|LiFePO4 batteries were constructed with this composite electrolyte and showed excellent rate and cycling performances. The first discharge-specific capacity of the assembled battery was 155.1 mA h g−1, and the capacity retention was 91% after operating for 300 cycles at 0.5 C. These results demonstrated that the chemical grafting of porous inorganic materials and cross-linking polymerization can greatly improve the properties of CPEs.

Flame-retardant single-ion conducting polymer electrolytes based on anion acceptors for high-safety lithium metal batteries

2021 ◽  
Author(s):  
Kuirong Deng ◽  
Tianyu Guan ◽  
Fuhui Liang ◽  
Xiaoqiong Zheng ◽  
Qingguang Zeng ◽  
...  
Keyword(s):  
Solid State ◽  
Flame Retardant ◽  
Conducting Polymer ◽  
Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Ion Conducting ◽  
Ion Conducting Polymer ◽  
Metal Anodes

Solid-state lithium metal batteries (LMBs) assembled with polymer electrolytes (PEs) and lithium metal anodes are promising batteries owing to their enhanced safeties and ultrahigh theoretical energy densities. Nevertheless, polymer electrolytes...

Double-Layered Multifunctional Composite Electrolytes for High-Voltage Solid-State Lithium-Metal Batteries

2021 ◽  
Vol 13 (10) ◽  
pp. 11958-11967
Author(s):  
Zhongran Yao ◽  
Kongjun Zhu ◽  
Xia Li ◽  
Jie Zhang ◽  
Jun Li ◽  
...  
Keyword(s):  
Solid State ◽  
High Voltage ◽  
Lithium Metal ◽  
Composite Electrolytes ◽  
Lithium Metal Batteries

Cyano-reinforced in-situ polymer electrolyte enabling long-life cycling for high-voltage lithium metal batteries

2021 ◽  
Vol 37 ◽  
pp. 215-223
Author(s):  
Zhaolin Lv ◽  
Qian Zhou ◽  
Shu Zhang ◽  
Shanmu Dong ◽  
Qinglei Wang ◽  
...  
Keyword(s):  
Polymer Electrolyte ◽  
High Voltage ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Long Life

Stabilizing ultrahigh-nickel layered oxide cathodes for high-voltage lithium metal batteries

2021 ◽  
Author(s):  
Xianhui Zhang ◽  
Lianfeng Zou ◽  
Zehao Cui ◽  
Hao Jia ◽  
Mark H. Engelhard ◽  
...  
Keyword(s):  
High Voltage ◽  
Lithium Metal ◽  
Layered Oxide ◽  
Lithium Metal Batteries ◽  
Oxide Cathodes ◽  
Layered Oxide Cathodes
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