scholarly journals 3D Printing of Mixed Matrix Films Based on Metal–Organic Frameworks and Thermoplastic Polyamide 12 by Selective Laser Sintering for Water Applications

2019 ◽  
Vol 11 (43) ◽  
pp. 40564-40574 ◽  
Author(s):  
Rui Li ◽  
Shangqin Yuan ◽  
Wang Zhang ◽  
Han Zheng ◽  
Wei Zhu ◽  
...  
ChemPlusChem ◽  
2019 ◽  
Vol 84 (2) ◽  
pp. 222-225 ◽  
Author(s):  
Elmeri Lahtinen ◽  
Rafaella L. M. Precker ◽  
Manu Lahtinen ◽  
Evamarie Hey-Hawkins ◽  
Matti Haukka

2020 ◽  
Vol 86 (10) ◽  
pp. 31-35
Author(s):  
N. Ya. Mokshina ◽  
V. V. Khripushin ◽  
M. S. Shcherbakova

The key point of 3D printing by selective laser sintering is the necessity of complete filling of the working chamber of the printer with a powder material. Since the powder is not completely consumed during the printing process, 25 – 30 wt.% of secondary (unused in the previous cycle) power is added to the primary material in each cycle. Repeated recirculation leads to degradation of the properties of the working powder mixture and increases the probability of rejects. We present the results of a colorimetric study of aging of polyamide-12 powder used in 3D printing by the method of selective laser sintering. Scanning and computer processing of digital images of primary and secondary polyamide powders obtained by colorimetry were performed using MathLab program package. Colorimetric analysis included the expression of the sample color using the parameters of color models applied in digital technologies for synthesizing colored images. The number of cycles before the onset of intensive destruction is no more than three, which is consistent with the practical experience in printing by selective laser sintering. The results characterizing change in the color of the secondary powder depending on the duration of thermal exposure and the gas medium are presented. It is shown that long-term storage of the powder for subsequent use is not advisable, since the initiators of destruction are already present in the material. Thermal oxidative destruction is shown to be a critical factor limiting the use of secondary powder along with changes in the crystallinity and fractional composition of particles. Computer processing of images of polymer powder obtained by the colorimetric method can be used to control the aging process of consumables and to predict the probability of rejections in 3D printing.


2019 ◽  
Vol 304 (4) ◽  
pp. 1800718 ◽  
Author(s):  
Alejandro H. Espera ◽  
Arnaldo D. Valino ◽  
Jerome O. Palaganas ◽  
Lucio Souza ◽  
Qiyi Chen ◽  
...  

2021 ◽  
Vol 288 ◽  
pp. 116882 ◽  
Author(s):  
Chao Cai ◽  
Wei Shian Tey ◽  
Jiayao Chen ◽  
Wei Zhu ◽  
Xingjian Liu ◽  
...  

2021 ◽  
Vol 412 ◽  
pp. 128675
Author(s):  
Shaojie Sun ◽  
Guoxia Fei ◽  
Xiaorong Wang ◽  
Miao Xie ◽  
Quanfen Guo ◽  
...  

ACS Omega ◽  
2019 ◽  
Vol 4 (7) ◽  
pp. 12012-12017 ◽  
Author(s):  
Elmeri Lahtinen ◽  
Lotta Turunen ◽  
Mikko M. Hänninen ◽  
Kalle Kolari ◽  
Heikki M. Tuononen ◽  
...  

2018 ◽  
Vol 24 (5) ◽  
pp. 813-820 ◽  
Author(s):  
Junjie Wu ◽  
Xiang Xu ◽  
Zhihao Zhao ◽  
Minjie Wang ◽  
Jie Zhang

Purpose The purpose of this paper is to investigate the effect of selective laser sintering (SLS) method on morphology and performance of polyamide 12. Design/methodology/approach Crystallization behavior is critical to the properties of semi-crystalline polymers. The crystallization condition of SLS process is much different from others. The morphology of polyamide 12 produced by SLS technology was investigated using scanning electron microscopy, polarized light microscopy, differential scanning calorimetry, X-ray diffraction and wide-angle X-ray diffraction. Findings Too low fill laser power brought about bad fusion of powders, while too high energy input resulted in bad performance due to chain scission of macromolecules. There were three types of crystal in the raw powder material, denoted as overgrowth crystal, ring-banded spherulite and normal spherulite. Originality/value In this work, SLS samples with different sintering parameters, as well as compression molding sample for the purpose of comparison, were made to study the morphology and crystal structure of sintered PA12 in detail.


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