Relationship between Lattice Strain and Efficiency for Sn-Perovskite Solar Cells

2019 ◽  
Vol 11 (34) ◽  
pp. 31105-31110 ◽  
Author(s):  
Kohei Nishimura ◽  
Daisuke Hirotani ◽  
Muhammad Akmal Kamarudin ◽  
Qing Shen ◽  
Taro Toyoda ◽  
...  
Science ◽  
2020 ◽  
Vol 370 (6512) ◽  
pp. 108-112 ◽  
Author(s):  
Gwisu Kim ◽  
Hanul Min ◽  
Kyoung Su Lee ◽  
Do Yoon Lee ◽  
So Me Yoon ◽  
...  

High-efficiency lead halide perovskite solar cells (PSCs) have been fabricated with α-phase formamidinium lead iodide (FAPbI3) stabilized with multiple cations. The alloyed cations greatly affect the bandgap, carrier dynamics, and stability, as well as lattice strain that creates unwanted carrier trap sites. We substituted cesium (Cs) and methylenediammonium (MDA) cations in FA sites of FAPbI3 and found that 0.03 mol fraction of both MDA and Cs cations lowered lattice strain, which increased carrier lifetime and reduced Urbach energy and defect concentration. The best-performing PSC exhibited power conversion efficiency >25% under 100 milliwatt per square centimeter AM 1.5G illumination (24.4% certified efficiency). Unencapsulated devices maintained >80% of their initial efficiency after 1300 hours in the dark at 85°C.


2019 ◽  
Vol 7 (12) ◽  
pp. 6877-6882 ◽  
Author(s):  
Yuanyuan Zhao ◽  
Yudi Wang ◽  
Jialong Duan ◽  
Xiya Yang ◽  
Qunwei Tang

Substitution of Pb2+ sites with smaller isovalent ions is used to optimize the crystal lattice of inorganic CsPbBr3 perovskite through releasing lattice strain, increasing the formation energy of vacancies and tuning the bandgap energy distribution.


2019 ◽  
Author(s):  
Shuzi Hayase ◽  
Kohei Nishimura ◽  
Gaurav Kapil ◽  
Chi Huey Ng ◽  
Kengo Hamada ◽  
...  

Nano Energy ◽  
2020 ◽  
Vol 73 ◽  
pp. 104803 ◽  
Author(s):  
Wei Hui ◽  
Ying Xu ◽  
Fei Xia ◽  
Hui Lu ◽  
Bixin Li ◽  
...  

Author(s):  
junjie fang ◽  
Zicheng Ding ◽  
Xiaoming Chang ◽  
Jing Lu ◽  
Tinghuan Yang ◽  
...  

Solution-processed perovskite solar cells (PSCs) have made great progress in past years. However, most fabrication methods of PSCs in lab cannot be directly transferred to industrial printing, and the toxic...


Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.


Author(s):  
Lucas Scalon ◽  
Francineide Lopes de Araújo ◽  
Caio Costa Oliveira ◽  
Ana Flávia Nogueira

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