Interpreting Abnormal Charge–Discharge Plateau Migration in CuxS during Long-Term Cycling

2019 ◽  
Vol 11 (4) ◽  
pp. 3961-3970 ◽  
Author(s):  
Zuguang Yang ◽  
Ting Chen ◽  
Chunjin Wu ◽  
Jie Qu ◽  
Zhenguo Wu ◽  
...  
Keyword(s):  
2017 ◽  
Vol 43 (1) ◽  
pp. 45-49 ◽  
Author(s):  
Hikaru Tsuchida ◽  
Zairan Cheng ◽  
Kiyoharu Nakagawa ◽  
Hirokazu Oda

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 729 ◽  
Author(s):  
Jisu Kim ◽  
Youn-Ji Heo ◽  
Jin-Yong Hong ◽  
Sung-Kon Kim

Porous carbon electrodes that accumulate charges at the electrode/electrolyte interface have been extensively investigated for use as electrochemical capacitor (EC) electrodes because of their great attributes for driving high-performance energy storage. Here, we report porous carbon nanofibers (p-CNFs) for EC electrodes made by the formation of a composite of monodisperse silica nanoparticles and polyacrylonitrile (PAN), oxidation/carbonization of the composite, and then silica etching. The pore features are controlled by changing the weight ratio of PAN to silica nanoparticles. The electrochemical performances of p-CNF as an electrode are estimated by measuring cyclic voltammetry and galvanostatic charge/discharge. Particularly, the p-CNF electrode shows exceptional areal capacitance (13 mF cm−2 at a current of 0.5 mA cm−2), good rate-retention capability (~98% retention of low-current capacitance), and long-term cycle stability for at least 5000 charge/discharge cycles. Based on the results, we believe that this electrode has potential for use as high-performance EC electrodes.


2017 ◽  
Vol 1 (5) ◽  
pp. 1082-1089 ◽  
Author(s):  
Ryohei Mori

To develop a high-capacity rechargeable aluminum–air battery with resistance toward the degradation induced by long-term charge–discharge electrochemical reactions, non-oxide ceramic materials, e.g., TiN, TiC, and TiB2, were used as air cathode materials with the ionic liquid 1-ethyl-3-methylimidazolium chloride as the electrolyte.


2017 ◽  
Vol 164 (7) ◽  
pp. A1474-A1479 ◽  
Author(s):  
Benjamin Streipert ◽  
Stephan Röser ◽  
Johannes Kasnatscheew ◽  
Pia Janßen ◽  
Xia Cao ◽  
...  

2020 ◽  
Vol 49 (17) ◽  
pp. 5730-5735 ◽  
Author(s):  
Yao Xiao ◽  
Beibei Guo ◽  
Jing Zhang ◽  
Chun Hu ◽  
Ruguang Ma ◽  
...  

A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.


2021 ◽  
Vol 9 (4) ◽  
pp. 2111-2119
Author(s):  
Xiaoming Liu ◽  
Xiaowen Zhan ◽  
Zachary D. Hood ◽  
Wangda Li ◽  
Donovan N. Leonard ◽  
...  

Atomic-resolution scanning transmission electron microscopy reveals the initiation and progression mechanism of microcracks and voids in LiNi0.8Co0.15Al0.05O2 (NCA) cathodes upon extended charge/discharge cycles.


1998 ◽  
Vol 513 ◽  
Author(s):  
S. Suda ◽  
Z. -P. Li ◽  
Y.-M. Sun ◽  
B.-H. Liu ◽  
X.-P. Gao

ABSTRACTProperties and characteristics of hydriding alloys are strongly dependent on surface compositions and morphologies. For instance, oxides such as La203 on AB5 alloys and ZrO2 on AB2, AB, and body-centered-cubic (BCC) alloys act as the barriers for the conversion of molecular and ionic hydrogen to atomic hydrogen at the surface, thus reducing the kinetics in both the gas-solid and electrochemical reactions.Alloy surfaces chemically treated by an aqueous F-ion containing solution have been developed to solve such problems. F-treated surfaces exhibit significantly improved characteristics in regard to the hydrogen uptakes and the protection against impurities and electrolyte solution. In addition, highly conductive metallic Ni layers can be formed on the surface of the alloy particles by the fluorination.The authors report the properties and characteristics of fluorinated hydriding alloys, mainly of a typical AB2 Laves phase material which represents the difficult activation characteristics and poor long-term durability during electrochemical charge/discharge cycles.


RSC Advances ◽  
2015 ◽  
Vol 5 (99) ◽  
pp. 81235-81242 ◽  
Author(s):  
Shuaifeng Lou ◽  
Bin Shen ◽  
Pengjian Zuo ◽  
Geping Yin ◽  
Lijie Yang ◽  
...  

The SEI evolution on the surface and Li/Co hybrid alignment in bulk phase are main factors for capacity degradation of LiCoO2 electrodes with high SOC in long-term cycling.


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