Perovskite/Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] Bulk Heterojunction for High-Efficient Carbon-Based Large-Area Solar Cells by Gradient Engineering

2018 ◽  
Vol 10 (49) ◽  
pp. 42328-42334 ◽  
Author(s):  
Jianhua Han ◽  
Xuewen Yin ◽  
Yu Zhou ◽  
Hui Nan ◽  
Youchen Gu ◽  
...  
2015 ◽  
Vol 212 (10) ◽  
pp. 2246-2254 ◽  
Author(s):  
Hui Jin ◽  
Ardalan Armin ◽  
Mike Hambsch ◽  
Qianqian Lin ◽  
Paul L. Burn ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2779 ◽  
Author(s):  
Manas R. Samantaray ◽  
Abhay Kumar Mondal ◽  
Govindhasamy Murugadoss ◽  
Sudhagar Pitchaimuthu ◽  
Santanu Das ◽  
...  

This article provides an overview of the structural and physicochemical properties of stable carbon-based nanomaterials and their applications as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). The research community has long sought to harvest highly efficient third-generation DSSCs by developing carbon-based CEs, which are among the most important components of DSSCs. Since the initial introduction of DSSCs, Pt-based electrodes have been commonly used as CEs owing to their high-electrocatalytic activities, thus, accelerating the redox couple at the electrode/electrolyte interface to complete the circuit. However, Pt-based electrodes have several limitations due to their cost, abundance, complicated facility, and low corrosion resistance in a liquid electrolyte, which further restricts the large-area applications of DSSCs. Although carbon-based nanostructures showed the best potential to replace Pt-CE of DSSC, several new properties and characteristics of carbon-CE have been reported for future enhancements in this field. In this review, we discuss the detailed synthesis, properties, and performances of various carbonaceous materials proposed for DSSC-CE. These nano-carbon materials include carbon nanoparticles, activated carbon, carbon nanofibers, carbon nanotube, two-dimensional graphene, and hybrid carbon material composites. Among the CE materials currently available, carbon-carbon hybridized electrodes show the best performance efficiency (up to 10.05%) with a high fill factor (83%). Indeed, up to 8.23% improvements in cell efficiency may be achieved by a carbon-metal hybrid material under sun condition. This review then provides guidance on how to choose appropriate carbon nanomaterials to improve the performance of CEs used in DSSCs.


2019 ◽  
Vol 48 (7) ◽  
pp. 734-737 ◽  
Author(s):  
Jianhua Han ◽  
Xuewen Yin ◽  
Yu Zhou ◽  
Hui Nan ◽  
Youchen Gu ◽  
...  

2011 ◽  
Vol 209 (1) ◽  
pp. 199-203 ◽  
Author(s):  
M. R. Rajesh Menon ◽  
M. V. Maheshkumar ◽  
K. Sreekumar ◽  
C. Sudha Kartha ◽  
K. P. Vijayakumar

MRS Bulletin ◽  
2005 ◽  
Vol 30 (1) ◽  
pp. 33-36 ◽  
Author(s):  
René A. J. Janssen ◽  
Jan C. Hummelen ◽  
N. Serdar Sariciftci

AbstractNanostructured phase-separated blends, or bulk heterojunctions, of conjugated polymers and fullerene derivatives form a very attractive approach to large-area, solid-state organic solar cells. The key feature of these cells is that they combine easy processing from solution on a variety of substrates with good performance. Efficiencies of up to 5% in solar light have been achieved, and lifetimes are increasing to thousands of hours. Further improvements can be expected and some of the promising strategies towards that goal are presented in this article.


2012 ◽  
Vol 116 (28) ◽  
pp. 14820-14825 ◽  
Author(s):  
Bo Wu ◽  
Than Zaw Oo ◽  
Xianglin Li ◽  
Xinfeng Liu ◽  
Xiangyang Wu ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42305-42317
Author(s):  
Md. Aatif ◽  
J. P. Tiwari

Solution-processed inverted bulk heterojunction (BHJ) organic solar cells (OSCs) are expected to play a significant role in the future of large-area flexible devices and printed electronics.


2015 ◽  
Vol 748 ◽  
pp. 45-48
Author(s):  
Shi Yan ◽  
Long Feng Lv ◽  
Yan Bing Hou

Bulk-heterojunction polymer solar cells (BHJ-PSCs) have attracted considerable attention because of their unique advantages of lightweight, low cost, mechanical flexibility and suitable for large-area fabrication [1–3]. In the last decades, much attention has been paid to the donor and acceptor system P3HT:PCBM, However, because of the relatively large bandgap of P3HT (∼1.9 eV) and the relatively small energy difference between the lowest unoccupied molecular orbital (LUMO) of PCBM and the highest occupied molecular orbital (HOMO) of P3HT, the photovoltaic performance of the PSCs based on P3HT:PCBM is still significantly lower than the inorganic solar cells. Recently more work has been done on the novel donor materials which have a reduced energy gap with an ability of harvesting more of the sun’s spectral emission and a high charge carriers mobility for charge transport. One of the most promising new donor polymer is poly [N-9"-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3' -benzothiadiazole)] (PCDTBT) with a HOMO level of 5.5eV which is 0.4 eV down-shifted than that of P3HT. When PCDTBT is blended with the fullerene acceptor PC70BM, it showed excellent photovoltaic performance with a power conversion efficiency of ∼ 6%. [6]


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