scholarly journals Consecutive Junction-Induced Efficient Charge Separation Mechanisms for High-Performance MoS2/Quantum Dot Phototransistors

2018 ◽  
Vol 10 (44) ◽  
pp. 38264-38271 ◽  
Author(s):  
Sangyeon Pak ◽  
Yuljae Cho ◽  
John Hong ◽  
Juwon Lee ◽  
Sanghyo Lee ◽  
...  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Long Hu ◽  
Qian Zhao ◽  
Shujuan Huang ◽  
Jianghui Zheng ◽  
Xinwei Guan ◽  
...  

AbstractAll-inorganic CsPbI3 perovskite quantum dots have received substantial research interest for photovoltaic applications because of higher efficiency compared to solar cells using other quantum dots materials and the various exciting properties that perovskites have to offer. These quantum dot devices also exhibit good mechanical stability amongst various thin-film photovoltaic technologies. We demonstrate higher mechanical endurance of quantum dot films compared to bulk thin film and highlight the importance of further research on high-performance and flexible optoelectronic devices using nanoscale grains as an advantage. Specifically, we develop a hybrid interfacial architecture consisting of CsPbI3 quantum dot/PCBM heterojunction, enabling an energy cascade for efficient charge transfer and mechanical adhesion. The champion CsPbI3 quantum dot solar cell has an efficiency of 15.1% (stabilized power output of 14.61%), which is among the highest report to date. Building on this strategy, we further demonstrate a highest efficiency of 12.3% in flexible quantum dot photovoltaics.


Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 717
Author(s):  
Hassan Algadi ◽  
Ahmad Umar ◽  
Hasan Albargi ◽  
Turki Alsuwian ◽  
Sotirios Baskoutas

A low-cost and simple drop-casting method was used to fabricate a carbon nanodot (C-dot)/all-inorganic perovskite (CsPbBr3) nanosheet bilayer heterojunction photodetector on a SiO2/Si substrate. The C-dot/perovskite bilayer heterojunction photodetector shows a high performance with a responsivity (R) of 1.09 A/W, almost five times higher than that of a CsPbBr3-based photodetector (0.21 A/W). In addition, the hybrid photodetector exhibits a fast response speed of 1.318/1.342 µs and a highly stable photocurrent of 6.97 µA at 10 V bias voltage. These figures of merits are comparable with, or much better than, most reported perovskite heterojunction photodetectors. UV–Vis absorption and photoluminescent spectra measurements reveal that the C-dot/perovskite bilayer heterojunction has a band gap similar to the pure perovskite layer, confirming that the absorption and emission in the bilayer heterojunction is dominated by the top layer of the perovskite. Moreover, the emission intensity of the C-dot/perovskite bilayer heterojunction is less than that of the pure perovskite layer, indicating that a significant number of charges were extracted by the C-dot layer. The studied band alignment of the C-dots and perovskites in the dark and under emission reveals that the photodetector has a highly efficient charge separation mechanism at the C-dot/perovskite interface, where the recombination rate between photogenerated electrons and holes is significantly reduced. This highly efficient charge separation mechanism is the main reason behind the enhanced performance of the C-dot/perovskite bilayer heterojunction photodetector.


2020 ◽  
Vol 350 ◽  
pp. 47-55
Author(s):  
Yuan-Yuan Geng ◽  
Chun-Lan Tao ◽  
Shi-Fang Duan ◽  
Jovan San Martin ◽  
Yixiong Lin ◽  
...  

2018 ◽  
Vol 6 (21) ◽  
pp. 9839-9845 ◽  
Author(s):  
Sha-Sha Yi ◽  
Jun-Min Yan ◽  
Qing Jiang

The carbon quantum dot (CQD) sensitized integrated Ti:Fe2O3@g-C3N4 core–shell nanoarrays demonstrate superior PEC water oxidation performance which can be ascribed to efficient charge separation efficiency derived from the well-confined heterojunction structure together with the high catalytic activity of the CQDs for H2O2 decomposition.


2016 ◽  
Vol 8 (22) ◽  
pp. 13902-13908 ◽  
Author(s):  
Byung-Sung Kim ◽  
Darren C. J. Neo ◽  
Bo Hou ◽  
Jong Bae Park ◽  
Yuljae Cho ◽  
...  

2019 ◽  
Vol 2 (2) ◽  
pp. 1027-1032 ◽  
Author(s):  
Yulu Zhou ◽  
Sizhuo Yang ◽  
Donghua Fan ◽  
Jake Reilly ◽  
Hongwei Zhang ◽  
...  

2019 ◽  
Vol 7 (38) ◽  
pp. 11797-11805 ◽  
Author(s):  
Guh-Hwan Lim ◽  
Kyu Seung Lee ◽  
Young Jae Park ◽  
Jaeho Shim ◽  
Jin Woo Choi ◽  
...  

Herein, we demonstrate that two-dimensional (2D) CdSeS quantum dot monolayers (QDM) can strongly influence efficient charge transport and charge separation, improving the performance of inverted polymer solar cells (iPSCs).


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