Out-of-Plane Mechanical Properties of 2D Hybrid Organic–Inorganic Perovskites by Nanoindentation

2018 ◽  
Vol 10 (26) ◽  
pp. 22167-22173 ◽  
Author(s):  
Qing Tu ◽  
Ioannis Spanopoulos ◽  
Shiqiang Hao ◽  
Chris Wolverton ◽  
Mercouri G. Kanatzidis ◽  
...  
Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 62
Author(s):  
Xu Xu ◽  
Zeping Zhang ◽  
Wenjuan Yao

Graphene and graphene oxide (GO) usually have grain boundaries (GBs) in the process of synthesis and preparation. Here, we “attach” GBs into GO, a new molecular configuration i.e., polycrystalline graphene oxide (PGO) is proposed. This paper aims to provide an insight into the stability and mechanical properties of PGO by using the molecular dynamics method. For this purpose, the “bottom-up” multi-structure-spatial design performance of PGO and the physical mechanism associated with the spatial structure in mixed dimensions (combination of sp2 and sp3) were studied. Also, the effect of defect coupling (GBs and functional groups) on the mechanical properties was revealed. Our results demonstrate that the existence of the GBs reduces the mechanical properties of PGO and show an “induction” role during the tensile fracture process. The presence of functional groups converts in-plane sp2 carbon atoms into out-of-plane sp3 hybrid carbons, causing uneven stress distribution. Moreover, the mechanical characteristics of PGO are very sensitive to the oxygen content of functional groups, which decrease with the increase of oxygen content. The weakening degree of epoxy groups is slightly greater than that of hydroxyl groups. Finally, we find that the mechanical properties of PGO will fall to the lowest values due to the defect coupling amplification mechanism when the functional groups are distributed at GBs.


2021 ◽  
Vol 30 ◽  
pp. 263498332110061
Author(s):  
Gunyong Hwang ◽  
Dong Hyun Kim ◽  
Myungsoo Kim

This research aims to optimize the mechanical properties of woven fabric composites, especially the elastic modulus. A micromechanics model of woven fabric composites was used to obtain the mechanical properties of the fiber composite, and a genetic algorithm (GA) was employed for the optimization tool. The structure of the fabric fiber was expressed using the width, thickness, and wave pattern of the fiber strands in the woven fabric composites. In the GA, the chromosome string consisted of the thickness and width of the fill and warp strands, and the objective function was determined to maximize the elastic modulus of the composite. Numerical analysis showed that the longitudinal mechanical properties of the strands contributed significantly to the overall elastic modulus of the composites because the longitudinal property was notably larger than the transverse property. Therefore, to improve the in-plane elastic modulus, the resulting geometry of the composites possessed large volumes of related strands with large cross-sectional areas and small strand waviness. However, the numerical results of the out-of-plane elastic modulus generated large strand waviness, which contributed to the fiber alignment in the out-of-plane direction. The findings of this research are expected to be an excellent resource for the structural design of woven fabric composites.


2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Seyed Ali Mirsalehi ◽  
Amir Ali Youzbashi ◽  
Amjad Sazgar

AbstractIn this study, epoxy hybrid nanocomposites reinforced by carbon fibers (CFs) were fabricated by a filament winding. To improve out-of-plane (transverse) mechanical properties, 0.5 and 1.0 Wt.% multi-walled carbon nanotubes (MWCNTs) were embedded into epoxy/CF composites. The MWCNTs were well dispersed into the epoxy resin without using any additives. The transverse mechanical properties of epoxy/MWCNT/CF hybrid nanocomposites were evaluated by the tensile test in the vertical direction to the CFs (90º tensile) and flexural tests. The fracture surfaces of composites were studied by scanning electron microscopy (SEM). The SEM observations showed that the bridging of the MWCNTs is one of the mechanisms of transverse mechanical properties enhancement in the epoxy/MWCNT/CF composites. The results of the 90º tensile test proved that the tensile strength and elongation at break of nanocomposite with 1.0 Wt.% MWCNTs improved up to 53% and 50% in comparison with epoxy/CF laminate composite, respectively. Furthermore, the flexural strength, secant modulus, and elongation of epoxy/1.0 Wt.% MWCNT/CF hybrid nanocomposite increased 15%, 7%, and 9% compared to epoxy/CF laminate composite, respectively.


2021 ◽  
Vol 881 ◽  
pp. 149-156
Author(s):  
Mochamad Teguh ◽  
Novi Rahmayanti ◽  
Zakki Rizal

Building material innovations in various interlocking concrete block masonry from local materials to withstand lateral earthquake forces is an exciting issue in masonry wall research. The block hook has an advantage in the interlocking system's invention to withstand loads in the in-plane and out-of-plane orientations commonly required by the masonry walls against earthquake forces. Reviews of the investigation of in-plane and out-of-plane masonry walls have rarely been found in previous studies. In this paper, the results of a series of experimental tests with different interlocking models in resisting the simultaneous in-plane shear and out-of-plane bending actions on concrete blocks are presented. This paper presents a research investigation of various interlocking concrete blocks' mechanical properties with different hook thicknesses. Discussion of the trends mentioned above and their implications towards interlocking concrete block mechanical properties is provided.


Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2421 ◽  
Author(s):  
Angelos Filippatos ◽  
Maik Gude

Fibre-reinforced composite structures subjected to complex loads exhibit gradual damage behaviour with the degradation of the effective mechanical properties and changes in their structural dynamic behaviour. Damage manifests itself as a spatial increase in inter-fibre failure and delamination growth, resulting in local changes in stiffness. These changes affect not only the residual strength but, more importantly, the structural dynamic behaviour. In the case of composite rotors, this can lead to catastrophic failure if an eigenfrequency coincides with the rotational speed. The description and analysis of the gradual damage behaviour of composite rotors, therefore, provide the fundamentals for a better understanding of unpredicted structural phenomena. The gradual damage behaviour of the example composite rotors and the resulting damage-dependent dynamic behaviour were experimentally investigated under propagating damage caused by a combination of out-of-plane and in-plane loads. A novel observation is the finding that a monotonic increase in damage results in a non-monotonic frequency shift of a significant number of eigenfrequencies.


2018 ◽  
Vol 774 ◽  
pp. 410-415 ◽  
Author(s):  
Kazuto Tanaka ◽  
Ken Uzumasa ◽  
Tsutao Katayama

Carbon fiber reinforced thermoplastics (CFRTP) are expected to be used as a structural material for aircraft and automobiles not only for their mechanical properties such as high specific strength and high specific rigidity but also for their high recyclability and short molding time. Generally, in a composite material having a laminated structure, interlaminar delamination is often caused by an out-of-plane impact, so the interlayer property plays an important role in the mechanical properties. It has been reported that the fiber/matrix interfacial strength increases by grafting carbon nanotubes (CNT) on the carbon fiber surface. In this study, CNT grafted carbon fibers were used for reinforcement of CFRTP laminate for the improvement of impact properties of CFRTP laminates. The impact absorbed energy of the CFRTP laminate using CNT grafted carbon fibers as reinforcing fiber was higher than that using untreated CF.


2007 ◽  
Vol 02 (03n04) ◽  
pp. 207-219 ◽  
Author(s):  
ANSUMAN LAHIRI ◽  
SOUMALEE BASU

We have studied the collective dynamics of leucine-rich repeat (LRR) proteins using an elastic network approximation. The slowest mode of the porcine ribonuclease inhibitor (pRI) protein could be visualized as bending fluctuations of a curved elastic strip leading to a planar opening–closing motion of the horseshoe which largely corresponded to the deformation of the protein on ligand binding. The second slowest mode however exhibited a significant out of plane splaying. The distribution of the lowest eigenvalues of different LRR proteins as a function of their repeat number was found to be close to the dispersion curve obtained from pRI whereas that of the leucine-rich variant (LRV) protein showed considerable deviation. The differing mechanical properties of these structurally similar solenoid proteins may have relevance to their function.


Sign in / Sign up

Export Citation Format

Share Document