Ultrathin Metal–Organic Framework Nanosheet-Derived Ultrathin Co3O4 Nanomeshes with Robust Oxygen-Evolving Performance and Asymmetric Supercapacitors

2018 ◽  
Vol 10 (28) ◽  
pp. 23721-23730 ◽  
Author(s):  
Guijuan Wei ◽  
Zhen Zhou ◽  
Xixia Zhao ◽  
Weiqing Zhang ◽  
Changhua An
Nanoscale ◽  
2018 ◽  
Vol 10 (33) ◽  
pp. 15454-15461 ◽  
Author(s):  
Simeng Dai ◽  
Yan Yuan ◽  
Jiangsheng Yu ◽  
Jian Tang ◽  
Jie Zhou ◽  
...  

MOFs are adopted for facile synthesizing hierarchical hollow architectures for energy storage.


2017 ◽  
Vol 201 ◽  
pp. 71-86 ◽  
Author(s):  
J. G. Santaclara ◽  
A. I. Olivos-Suarez ◽  
I. du Fossé ◽  
A. Houtepen ◽  
J. Hunger ◽  
...  

The highly porous titanium based metal–organic framework NH2-MIL-125(Ti) has recently attracted significant attention in the field of photocatalysis as a promising material for H+ reduction. This work reveals charge transfer upon visible light illumination from this MOF to two different charge acceptors, as an alternative to sacrificial electron donors. Charge transfer is demonstrated through a combined spectroscopic study between this MOF and: (1) 2-(1H-pyrazol-3-yl)phenol, a molecule that functionally mimics the tyrosine–histidine pair, responsible for shuttling the holes to the oxygen evolving centre in natural photosynthesis, and (2) TEMPO, a well known and stable radical. Charge transfer of the holes from the MOF to these occluded molecules takes place on the picosecond time scale. This work suggests that, by coupling a stable and recyclable charge acceptor to the photogenerated holes, the charges can be utilised for oxidation reactions and, thus, link the reduction to the oxidation reactions in water splitting.


2019 ◽  
Vol 3 (8) ◽  
pp. 1653-1660 ◽  
Author(s):  
Di Tian ◽  
Sihui Chen ◽  
Wendong Zhu ◽  
Ce Wang ◽  
Xiaofeng Lu

Metal–organic framework derived hierarchical Ni/Ni3S2 decorated carbon nanofibers were designed for high-performance asymmetric supercapacitors.


2021 ◽  
Vol 4 (9) ◽  
pp. 9034-9043
Author(s):  
Guosheng Wang ◽  
Zhaoxiong Yan ◽  
Nenghuan Wang ◽  
Ming Xiang ◽  
Zhihua Xu

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